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261.
262.
Neutron Activation Analysis, Atomic Absorption and X-Ray Fluorescence Spectrometry Review for 2003 总被引:1,自引:0,他引:1
This review for the year 2003 deals with three relatively well-established, mature, analytical techniques (neutron activation analysis, atomic absorption spectrometry and X-ray fluorescence spectrometry) that nevertheless remain very important for the characterisation of geological and environmental samples. Developments in neutron activation analysis included modification to the technique in relation to the determination of platinum-group elements, as well as consideration of sample size in ore grade estimation. A considerable body of literature was published on the application of atomic absorption spectrometry in the analysis of environmental samples. Many of these proposed technical and methodological improvements, notably in extraction procedures. X-ray fluorescence spectrometry saw developments in in situ analysis, synchrotron micro-XRF (μ-SRXRF) and a confocal X-ray set-up for 3D elemental imaging. XRF technologies were used in the analysis of geological samples, reference materials, glasses, solutes and environmental materials. 相似文献
263.
Lance P. Black 《Geostandards and Geoanalytical Research》2005,29(2):169-182
Data from a series of extended analytical sessions using a range of different zircon reference samples have been used to investigate the periodic derivation of abnormal 207 Pb/206 Pb ages during microbeam analysis%For the Canberra SHRIMP II, this phenomenon probably results from the presence of a signal at mass 204 that is alien to the Pb spectrum; isotopic fractionation is unlikely to be a significant contributor. In contrast, abnormal 207 Pb/206 Pb ages obtained from SHRIMP I at the same research centre require a different, but as yet unknown explanation. Assessment of the reasons for atypical 207Pb /206 Pb measurements and the means of correcting for them should therefore be independently assessed for individual analytical instruments. The use of reference samples with very different ages is an effective way of doing this, because older reference samples are more useful for documenting isotopic fractionation, whereas younger ones are more sensitive indicators of isobaric interference. 相似文献
264.
建立了一个在线氢化物发生原子荧光光谱法直接测定土壤和天然水中痕量锑的分析方法。设计了微型在线氢化物发生器及操作程序。选择了氢化物发生的各项最佳条件。方法检出限为0.084ng/mL,工作曲线在0~30ng/mL内呈良好的线性,经标准物质分析验证,测定结果与标准值吻合,水样中的回收率在92.8%~106.9%之间,相对标准偏差(RSD,n=5)<4.8%。 相似文献
265.
NK8310螯合树脂分离富集地质样品中痕量金银铂钯及其测定 总被引:14,自引:3,他引:14
研究了硫脲螯合树脂(NK8310)分类富集地质样品中痕量Au、Ag、Pt和Pd的实验条件。在φ=10%的王水介质中,[AuCI4]^-、[AgCI2]^-、[PtCI6]^2-和[PdCI4]^2-定量吸附于树脂上并与大量贱金属分离;用5g/L硫脲-0.12mol/L HCI溶液洗脱Au、Ag、Pt和Pd,回收率为97%-104%。用硫镍矿管理样以及国家一级标准物质进行分析验证,分析结果与推荐值及标准值吻合,表明NK8310螯合树脂适用于地质样品中Au、Ag、Pt和Pd的分离富集。 相似文献
266.
不同类型水样中同位素样品采集方法浅析 总被引:1,自引:0,他引:1
本文对不同类型水样中同住素样品野外采集方法进行了探讨。根据各种水样的同位素分布情况,进一步探索地下水的来源、补给和运移机理,为实现水资源的计划开发、统一管理服务。 相似文献
267.
Permeability of the samples collected from the surface and from the depths of 8–11 km in the Kola SG-3 and from the depth of 3.8 in the KTB boreholes was studied at temperatures up to 600 °C and pressures up to 150 MPa. These PT correspond to in situ conditions of the deep parts of the superdeep boreholes and to the conditions of progressive and regressive metamorphism of the Kola series rocks. The experiments were carried out with fluid filtration parallel and normal to rock foliation and parallel to core axis. The temperature–permeability trend behavior depends on effective pressure and depth of sample collection. At low effective pressure, a temperature increase leads first to a permeability decrease and then to its increase. At higher effective pressure, inversions appear on all the temperature trends of the samples collected from great depths. In contrast, permeability of the samples selected at shallow depth (3.8 km) and on the surface decreases within the entire temperature range. As a rule, with flow parallel to foliation, the values of permeability are higher than with flow normal to foliation. The results of microstructure studies allow to conclude that microcrack initiation and closure, due to a competitive influence of temperature and pressure cause such permeability behavior. In the samples, there are two families of microcracks: with low aspect ratio and those with high aspect ratio. Their effect on rock permeability changes with temperature. On sample heating, the low aspect ratio microcracks close and, on the contrary, high aspect ratio ones open. The total effect is expressed by minima in the temperature–permeability trends. Permeability anisotropy increases with temperature, reaches a maximum at 200 °C and then decreases. Sample permeability decreases with different gradients at simultaneous increase of temperature and pressure, simulating in situ depth increase. Hence, the deep seat rocks can vary greatly in permeability and against the common background of permeability decrease with depth, local deep aquifers may occur. At PT of progressive metamorphism the permeability values were high enough to permit the fluid flow to penetrate the whole volume of rock massif. At PT of regressive metamorphism, the permeability values were a few decimal orders lower, so fluid flow could be concentrated in large disjunctive zones only. 相似文献
268.
本文研究了黄原酯棉分离富集水中痕量铜的条件,结合催化极谱,可用水中3μg/L~200μg/L铜的测定,方法简便、快速,适用性强。 相似文献
269.
多母体p—范极大似然平差 总被引:2,自引:0,他引:2
本文提出了多母体p-范极大似然平差方法,建立了该方法的数学模型,并且导出了求解参数估值的基础方程,本文提出的方法溶测量平差,误差母体分布的估计、方差分量估计于一体,是对多元p-范极大似然平差的进一步推广。 相似文献
270.
Madeleine Sélo Jean Benkhelil Jean Mascle Dieter Storzer Neville Exon 《Comptes Rendus Geoscience》2002,334(1):59-66
We present and discuss a few fission track data, and microstructural observations, from rock samples dredged along the western and southwestern continental margin of Tasmania. The results allow assessing the thermal and tectonic regimes that were active prior to and during the margin creation. The different ages, as provided by fission tracks, and deformational styles, as evidenced from microstructures, are then tentatively correlated with the two main rifting episodes, in Late Jurassic–Cretaceous times and Eocene–Oligocene respectively, deduced from kinematical reconstructions, that have led to the present- day southern margin of Tasmania. To cite this article: M. Sélo et al., C. R. Geoscience 334 (2002) 59–66 相似文献