White mica K–Ar geochronology of Sanbagawa eclogites from Southwest Japan: implications for deformation-controlled K–Ar closure temperature

White mica (phengite and paragonite) K–Ar ages of eclogite-facies Sanbagawa metamorphic rocks (15 eclogitic rocks and eight associated pelitic schists) from four different localities yielded ages of 84–89 Ma (Seba, central Shikoku), 78–80 Ma (Nishi-Iratsu, central Shikoku), 123 and 136 Ma (Gongen, central Shikoku), and 82–88 Ma (Kotsu/Bizan, eastern Shikoku). With the exception of a quartz-rich kyanite-bearing eclogite from Gongen, white mica ages overlap with the previously known range of phengite K–Ar ages of pelitic schists of the Sanbagawa metamorphic belt and can be distinguished from those of the Shimanto metamorphic belt. The similarity of K–Ar ages between the eclogites and surrounding pelitic schists supports a geological setting wherein the eclogites experienced intense ductile deformation with pelitic schists during exhumation. In contrast, phengite extracted from the Gongen eclogite, which is less overprinted by a ductile shear deformation during exhumation, yielded significantly older ages. Given that the Gongen eclogite is enclosed by the Higashi-Akaishi meta-peridotite body, these K–Ar ages are attributed to excess ⁴⁰Ar gained during an interaction between the eclogite and host meta-peridotite with mantle-derived noble gas (very high ⁴⁰Ar/³⁶Ar ratio) at eclogite-facies depth. Fluid exchange between deep-subducted sediments and mantle material might have enhanced the gain of mantle-derived extreme ⁴⁰Ar in the meta-sediment. Although dynamic recrystallization of white mica can reset the Ar isotope system, limited-argon-depletion due to lesser degrees of ductile shear deformation of the Gongen eclogite might have prevented complete release of the trapped excess argon from phengites. This observation supports a model of deformation-controlled K–Ar closure temperature.     

Evolution of continental crust of the Aravalli craton,NW India,during the Neoarchaean–Palaeoproterozoic: evidence from geochemistry of granitoids

Neoarchaean–Palaeoproterozoic granitoids of the Aravalli craton, represented by four plutons with different ages, viz. Gingla (2.6–2.4 Ga), Ahar River (2562 Ma), Untala (2505 Ma), and Berach (2440 Ma) granitoids, are classified into three suites: TTG-like, Sanukitoid, and High-K Granitoid suite, all exhibiting negative Nb and Ti anomalies. The TTG-like suite is characterized by high contents of SiO₂, Na₂O, and LREEs, high (La/Yb)_N, low contents of K₂O, MgO, Cr, and Ni, and low (Dy/Yb)_N, suggesting that this suite formed by partial melting of a subducted basaltic slab without interacting with a mantle wedge. In contrast, the calc-alkaline Sanukitoid suite is marked by a high content of LILEs and mantle-compatible elements, which indicate that this suite formed by partial melting of a slab-fluid metasomatized mantle wedge in a subduction-related arc environment. On the other hand, the High-K Granitoid suite is characterized by high contents of SiO₂ and K₂O, and low contents of Na₂O, MgO, Cr, and Ni with variable Eu anomaly, along with high (La/Sm)_N and (La/Yb)_N, and low (Dy/Yb)_N and Nb/Th. Some high-K granitoids also exhibit A-type characteristics. These features indicate that the High-K Granitoid suite formed by melting of crustal rocks. Early Neoarchaean continental crust formation reflected a slab-melting-dominated magmatic process as evidenced by the TTG-like suite, whereas Palaeoproterozoic petrogenesis was governed by the interaction of slab melt with mantle wedge as demonstrated by the Sanukitoid suite. The High-K Granitoid suite formed during the waning stages of subduction. This study reveals that granitic rocks of the Aravalli craton evolved from slab melting in the Neoarchaean to melting of mantle wedge in the Palaeoproterozoic. Melting of older crust led to the formation of the High-K Granitoid suite.     

Developing markets for water reallocation: Revisiting the experience of Spanish water mercantilización

Economic instruments are being promoted as a desirable alternative to public sector action in the allocation and management of natural resources. A wide body of literature has developed that critically analyzes this phenomenon as part of a wider project of ‘neoliberalization of nature’, trying to uncover the underlying rationale and commonalities of geographically specific phenomena. The case of water is at the vanguard of these processes and is proving to be particularly contentious. In the European Union water policies are increasingly emphasizing the application of economic instruments to improve the allocative equity and economic efficiency in the use of scarce resources. However, there are few analyses of how these instruments are really working on the ground and whether they are meeting their objectives. This paper aims to contribute to this debate by critically analyzing the experience with water markets in Spain, the only country in the European Union where they are operative. It looks at water permit sales during the 2005–2008 drought period using the Tajo–Segura transfer infrastructure. The paper describes how the institutional process of mercantilización of water works in practice in Spain. It shows that the use of markets requires an intense process of institutional development to facilitate and encourage their operation. These institutions tend to favor the interests of clearly identifiable elites, instead of the public interest they supposedly promote.     

Arsenic accumulation in the roots of Helianthus annuus and Zea mays by irrigation with arsenic-rich groundwater: Insights from synchrotron X-ray fluorescence imaging

The aim of this study was to investigate the accumulation of arsenic (As) in and on roots of Zea mays (maize) and Helianthus annuus (sunflower) by means of synchrotron-based micro-focused X-ray fluorescence imaging (μ-XRF). Plant and soil samples were collected from two field sites in the Hetao Plain (Inner Mongolia, China) which have been regularly irrigated with As-rich groundwater. Detailed μ-XRF element distribution maps were generated at the Fluo-beamline of the Anka synchrotron facility (Karlsruhe Institute of Technology) to assess the spatial distribution of As in thin sections of plant roots and soil particles. The results showed that average As concentrations in the roots (14.5–27.4 mg kg⁻¹) covered a similar range as in the surrounding soil, but local maximum root As concentrations reached up to 424 mg kg⁻¹ (H. annuus) and 1280 mg kg⁻¹ (Z. mays), respectively. Importantly, the results revealed that As had mainly accumulated at the outer rhizodermis along with iron (Fe). We therefore conclude that thin crusts of Fe-(hydr)oxides cover the roots and act as an effective barrier to As, similar to the formation of Fe plaque in rice roots. In contrast to permanently flooded rice paddy fields, regular flood irrigation results in variable redox conditions within the silty and loamy soils at our study site and fosters the formation of Fe-(hydr)oxide plaque on the root surfaces.     

Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.     

The material conditions for research in France from 1600 to 1850: Physics,chemistry and astronomy

The income of the scientists in France during the 17th to the middle of the 19th century is reviewed and compared to the cost of their instruments. Only a small number of scientists received enough public money to be able to do full-time research; this number increased substantially after the Revolution. Most scientists had to have other sources of income, in particular to be able to purchase their instruments. Large research projects, generally decided and financed by the Academy of Sciences, took place during this period, requiring collaborative interdisciplinary efforts and a considerable logistics: they anticipate our present cooperative programs and giant research facilities.     

Hemispheric asymmetry of sunspot area in solar cycle 23 and rising phase of solar cycle 24: Comparison of three data sets

Analysis of long-term solar data from different observatories is required to compare and confirm the various level of solar activity in depth. In this paper, we study the north–south asymmetry of monthly mean sunspot area distribution during the cycle-23 and rising phase of cycle-24 using the data from Kodaikanal Observatory (KO), Michelson Doppler Imager (MDI) and Solar Optical Observing Network (SOON). Our analysis confirmed the double peak behavior of solar cycle-23 and the dominance of southern hemisphere in all the sunspot area data obtained from three different resources. The analysis also showed that there is a 5–6 months time delay in the activity levels of two hemispheres. Furthermore, the wavelet analysis carried on the same data sets showed several known periodicities (e.g., 170–180 days, 2.1 year) in the north–south difference of sunspot area data. The temporal occurrence of these periods is also the same in all the three data sets. These results could help in understanding the underlying mechanism of north–south asymmetry of solar activity.     

The Euro-Atlantic Circulation Response to the Madden-Julian Oscillation Cycle of Tropical Heating: Coupled GCM Intervention Experiments

Abstract

Intervention experiments using the Coupled Forecast System model, version 2 (CFSv2), have been performed in which various Madden-Julian Oscillation (MJO) evolutions were added to the model’s internally generated heating: Slow Repeated Cycles, Slow Single Cycle, Fast Repeated Cycles, and Fast Single Cycle. In each experiment, one of these specified MJO evolutions of tropical diabatic heating was added in multiple ensemble reforecasts of boreal winter (1 November to 31 March for 31 winters: 1980–2010). Since in each experiment, multiple re-forecasts were made with the identical heating evolution added, predictable component analysis is used to identify modes with the highest signal-to-noise ratio. Traditional MJO-phase analysis of total model heating (dominated by internally generated heating) shows that the MJO-related heating structure compares well with heating estimated from observed fast and slow episodes; however, the model heating is larger by a factor of two. The evolution of Euro-Atlantic circulation regimes indicates a clear response due to the added heating, with a robust increase in the frequency of occurrence of the negative phase of the North Atlantic Oscillation (NAO?) after the heating crosses into the Pacific and a somewhat less robust increase in the positive phase of the NAO (NAO+) following Indian Ocean heating. In the Fast Cycle experiments, the model response is somewhat muted compared with the Slow Cycle experiments. The Scandinavian Blocking regime becomes more frequent prior to the NAO? regime. The two leading modes in the predictable component analysis of 300?hPa height (Z300), synoptic scale feedback (DZ300), and planetary wave diabatic heating in all experiments form an oscillatory pair with high statistical significance. The oscillatory pair represents the cyclic response to the particular MJO signal (Fast or Slow, Single, or Repeated Cycles) in each case. The period is about 64 days for the Slow Cycle and 36 days for the Fast Cycle, consistent with the imposed periods. The time series of one of the leading modes of Z300 is highly anti-correlated with the frequency of occurrence of the NAO– in the Repeated Cycle experiments. A clear cycle involving the Z300 and DZ300 leading modes is identified.     

Sediment cascades and the entangled relationship between human impact and natural dynamics at the pre-pottery Neolithic site of Göbekli Tepe,Anatolia

This study presents a meta-analysis of radiocarbon ages for the environs of Göbekli Tepe – one of the oldest monumental structures worldwide – using cumulative probability functions to diachronically assess phases of geomorphodynamic activity as controlled by natural or anthropogenic drivers. We employ sediment cascades as a heuristic framework to study the complex responses of the geomorphological system to various triggers at local to supra-regional scales. Possible triggers include climatic variability as documented by supra-regional hydroclimatic proxy data, regional demographic trends, and local to regional socioeconomic developments such as the emergence of sedentism or the introduction and dispersal of livestock herding. Our results show that phases of intensified geomorphodynamic activity occurred between ca. 7.4–7.0 and 5.8–3.3 ka BP. These phases roughly coincide with phases of population growth in southern Turkey and climatic variations in Turkey and the Levant. The phase between ca. 5.8–3.3 ka BP also corresponds to the time when organized agriculture and the seeder plough were introduced. Also, the identified phases are in agreement with the general trend of varying geomorphodynamic activity in the Eastern Mediterranean as driven by human impact and climatic change. However, neither the Younger Dryas–Holocene transition nor the development of herding during the Pre-Pottery Neolithic left a clear signature. We demonstrate how the different depositional environments in the studied landscape compartments vary with respect to their spatiotemporal coverage and discuss challenges when trying to understand processes that once shaped landscapes of past societies. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd