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41.
H. Tan D. Feng J.S.J. van Deventer G.C. Lukey 《International Journal of Mineral Processing》2006,80(2-4):153-168
The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness. 相似文献
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Lallan Prasad Gupta Hodaka Kawahata Mio Ltakeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2006,56(2):191-196
Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions. 相似文献
44.
M. Hamami 《Geotechnical and Geological Engineering》2006,24(5):1271-1292
The work presented in this paper comes as part of a research program dealing with the thermomechanical behaviour of rock salt.
It aims to study laboratory and in-situ long-term behaviour by means of creep tests with deviator and temperature changes. The laboratory results, using a triaxial
multi-stages creep tests, highlighted the strain hardening character of rock salt. Furthermore, the in-situ results, using a borehole dilatometer multi-step creep test, have shown that the drilling is carried out in a weakly stressed
pillar. The interpretation of the laboratory results, using the J.LEMAITRE law, did not indicate full agreement with all the
test results. As a result a ‘double’ J.LEMAITRE model, which takes into account a double strain hardening variable, has been
put forward. The validation of this model on the laboratory creep tests is very satisfactory. Furthermore, the activation
energy seems satisfactory to represent the influence of the temperature. The in-situ behaviour modelling is clearly more complex than the modelization based on laboratory tests. In fact, it seems that if the
rock salt behaviour is maintained by J.LEMAITRE law, it is necessary to vary with the stress, at least, one of the parameters
assumed constant in the basic law. 相似文献
45.
图像平滑算法比较研究及改进策略 总被引:9,自引:0,他引:9
图像平滑作为去除图像中含有噪声的图像增强处理技术,是各种与图像有关软件中必不可少的功能模块。文中在分析噪声模型的基础上,对均值平滑、中值平滑、边缘保持平滑等技术从图像处理空间域中的算法原理、实现方法及效率等方面进行了详细比较。针对图像中含有的不同噪声模型,通过多次试验,得出了值得从事图像处理研究者参考的结论。这将有助于提高图像处理软件开发的效率。 相似文献
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湘中锑(金)矿床成矿物质来源——Ⅰ.微量元素及其实验地球化学证据 总被引:9,自引:0,他引:9
为了查明湘中盆地中-低温梯(金)矿床的成矿物质来源,文章应用高分辨率ICP-MS、ICP-AES等方法对岩石与矿石进行了系统测定,并结合作者以往分析数据和实验地球化学结果,对该区盆地及周边基底地层与矿床中的微量元素分布特征及其水/岩反应效应进行了综合分析和系统研究。结果表明:Sb、Au等成矿元素在元古界基底碎屑岩中具有高的背景含量,在近似成矿条件下的水/岩反应实验中,成矿元素的淋出率达20%~90%,元古界基底碎屑岩中的金(锑、钨)矿床的周围蚀变围岩中出现明显的金负异常区。而盆地内泥盆系统地层中的高锑含量仅局限于锑矿床(化)及其蚀变围岩中;湘中锑(金)矿床中的矿石与基底碎屑岩具有相似的稀土元素球粒陨石标准化配分曲线特征,以上微量元素地球化学特征充分证明该区锑(金)矿床锑、金等成矿物质主要来源于元古界底碎屑岩。 相似文献
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Based on the mineral and chemical compositions of spoils taken from the Shilu Cu-Mo deposit and Hetai gold deposit, the leaching and batch experiments were made on spoils taken from these two deposits using the leaching column designed by the authors. The experimental results showed that it is not always true that the mine drainage is acidic. Its acidity depends on acid-buffering capacity of gangue, host rock and its alteration mineral assemblage. The composition of the drainage water is related with the interaction between superficial or underground water and solid materials in the spoils, including minerals, hydroxides and amorphous substances. The leaching extent of the element is related with its occurrence form in the deposit. The preferential flow results in leaching-out of heavy metals in large amounts. So it is important to prevent the generating of preferential flow in the system. The results will provide very important grounds for the comprehensive management of land and ecological rehabilitation of the mine site. 相似文献
50.
An experiment on evapotranspiration from citrus trees under irrigation with saline waterwas carried out for 4 months. Two lysimeters planted with a citrus tree in the green house wereused. One lysimeter was irrigated with saline water (NaCl and CaCl2 of 2000 mg/L equivalence,EC = 3.8 dS/m, SAR = 5.9) and the other was irrigated with freshwater using drip irrigation. Theapplied irrigation water was 1.2 times that of the evapotranspiration on the previous day.Evapotranspiration was calculated as the change in lysimeter weight recorded every 30 minutes.The lysimeters were filled with soil with 95.8% sand. The results of the experiment were as follows.(i) The evapotranspiration from citrus tree was reduced after irrigation with saline water. Theevapotranspiration returns to normal after leaching. However it takes months to exhaust the saltfrom the tree. ( ii ) To estimate the impact of irrigation with saline water on the evapotranspirationfrom citrus trees, the reduction coefficient due to salt stress (Ks) was used in this experiment.Evapotranspiration under irrigation with saline water (ETs) can be calculated from evapotranspira-tion under irrigation with freshwater (ET) by the equation ETs = Ks× ET. Ks can be expressed as afunction of ECsw. (iii) The critical soil-water electrical conductivity (ECsw) is 9.5 dS/m, beyondwhich adverse effects on evapotranspiration begin to appear. If ECsw can be controlled at below9.5 dS/m, saline water can be safely used for irrigation. 相似文献