硫酸盐渍土在多次冻融循环时的盐胀累加规律

通过室内模拟试验,研究了硫酸盐渍土在历经多次冻融循环时的盐胀累加规律,得出了盐胀累加的不同类型,给出了累加盐胀率与循环次烽之间的关系式,进一步揭示了盐胀累加的 和影响因素。     

多途径解决我国钾盐资源紧缺的对策探讨

探讨了钾盐矿产的应用,钾盐矿产在世界及我国的分布状况,提出了解决我国钾盐矿产资源紧缺问题的途径。     

四川盆地三叠系蒸发岩的变质作用与富钾卤水的成因

在四川盆地三叠系蒸发岩建造中已发现钾盐镁矾、无水钾镁矾、软钾镁矾、杂卤石、钾石膏、多钙钾石膏、钙芒硝等矿物,并在多处发现富钾卤水。已有的资料表明,这些矿物组合是已沉积的固体钾盐层在成岩期水溶变质作用过程中形成的变质矿物组合。在此过程中大量的钾质转入水溶液,形成了富钾卤水。这种富钾卤水是可综合利用的ＫＣｌ、ＮａＣｌ和Ｌｉ、Ｓｒ、Ｃｓ、Ｒｂ、Ｂ、Ｂｒ、Ｉ的优质盐化工业原料卤水。     

察尔汗盐湖盐田渗漏及其工程地质条件分析

１９８１年以来对察尔汗盐湖三次渗漏试验结果表明,盐田渗漏是盐田土层与外界条件综合作用的结果,在盐田建设和生产管理过程中,应结合不同地点的土层特性、工程地质条件和其它有关条件,采取不同的处理措施。     

Spatial and temporal variations in aboveground and belowground biomass of Spartina maritima (small cordgrass) in created and natural marshes

Spartina species are commonly used for salt marsh manipulative projects, where aboveground and belowground biomasses are functional traits that play important roles, showing high spatial and temporal variations. This work analyses variations in AGB and BGB of Spartina maritima and abiotic environmental parameters along a chronosequence of six marshes created from 1997 to 2003 with disparate sediment dynamics, and adjacent natural marshes and unvegetated tidal flats. S. maritima behaved as an autogenic engineer, as its colonization of bare sediments yielded abiotic environmental changes: specifically, bed level rise accompanied by higher oxygenation and salinity. These modifications of the environment were site-specific, depending mainly on sedimentary dynamics. At the same time, abiotic environmental changes determined biomass production rates of S. maritima that were higher in more-accreting marshes; however, AGB was kept constant from early in its development (2 years). The increase in BGB with elevation seemed to be related to the inhibition of subsurface tissue development in anoxic sediments. Biomass accumulation and production varied markedly, depending on the spatial scale, indicating the relevance of the plot size chosen for the analysis of biomass of cordgrasses. Our results show that managers of salt marshes should consider sedimentary dynamics carefully when setting realistic expectations for success criteria of created and restored wetlands.     

Comparison of Kuqa foreland basin with Persian Gulf Basin in salt tectonics

Compared Kuqa foreland basin with Persian Gulf Basin in development of salt layers, salt tectonics, and the relation between salt tectonics and hydrocarbon, it is concluded that the salt diapirs are relative to hydrocarbon. Searching salt diapirs and related traps in Kuqa foreland basin is important. The forming mechanism of salt tectonic in Kuqa foreland basin is different from that of Hormuz Series, but similar to that of Lower Fars Series/Gachsaran Formation. Inspired by the role of salt tectonics of Lower Fars Series/Gachsaran Formation in hydrocarbon accumulation, the authors considered that the exploration below salt layer should be enforced, and the traps below salt layer in the southern part of the Kuqa foreland basin would be found where salt layer is thicker. On the contrary, the traps should be found both above and below the salt layer in front of the northern mountain where salt layer is thin. The Triassic and Jurassic source rocks are rich in this area with great exploration prospective.     

西藏盐湖沉积物：一种潜在的铷、铯资源

铷、铯是我国战略性关键矿产资源。西藏盐湖卤水中赋存着丰富的铷、铯资源,但是品位普遍低于10 mg/L。根据热泉与盐湖锂、铷、铯等元素的补给关系和含量差异特征及铷、铯极易被黏土矿物吸附等特点,推测盐湖沉积物中赋存一定规模的铷、铯资源。为验证该推测,本文选取西藏拉果错、聂尔错、依布茶卡、当穹错、扎布耶茶卡等5个典型盐湖,采集卤水和沉积物样品各5件,开展水体中铷、铯含量和沉积物矿物成分分析,结合沉积物分相淋滤实验,得出如下结论：西藏拉果错、当穹错、聂尔错盐湖卤水铷、铯含量和资源量与其补给量差异显著,大量的铷、铯资源消耗于盐湖沉积物中;盐湖沉积物中的铷、铯含量远高于卤水。铷、铯在沉积物水溶相、碳酸盐相中含量较低,主要以吸附形式赋存于黏土矿物(主要为伊利石),吸附点位包括基面位置、难解吸的磨损边缘及层间位置。盐湖沉积物铷、铯资源量远超大型矿床规模,黏土矿物中铷、铯含量高达100 n×10-6,超过固体盐类矿产综合评价指标,相较于现有盐湖钾产品中的铷资源、含铯硅华中的铯资源开发,具有较好的开发利用性,是一种潜在的铷、铯资源。本研究成果有助于完善盐湖铷、铯富集成矿机制,并为高效开发盐湖中的铷、铯资源提供理论支撑。     

南京市降水化学特征及其来源研究

为了解南京江北地区降水化学特征,分析了2011年3—6月共25个降水日的109个降水样品中的主要水溶性离子,并利用后向轨迹模式探讨了降水气团来源.结果表明:1)南京地区3—6月降水主要受南、北2种气团影响,北方气团降水的主要离子浓度高于南方气团降水.2)海盐示踪法和相关性分析显示,降水中NO₃^-和SO₄^2-主要来自燃煤、工业排放和汽车尾气;Ca²⁺主要来自地壳源;Cl^-主要来自海洋;海洋源和陆源对Mg²⁺和K⁺都有贡献,Mg²⁺的陆源贡献大于海洋源贡献,K⁺受海洋源的影响程度要低于Mg²⁺.3)南、北气团初期降水的各离子浓度高于总降水的各离子浓度,且初期降水的主要离子的富集系数高于总降水.这说明在降水初始阶段,雨水对南京大气中污染物(气态污染物和颗粒物)的云下冲刷去除作用较强,降水的离子浓度最高,局地源对降水离子的贡献较明显.     

论四川盆地地下卤水资源开发利用的现状及对策

四川盆地地下卤水资源储量大,卤水浓度较高,并含有I、Br、K、Li等多种有用组分。地下卤水多沿构造隆起部位富集,并具有天然气和卤水同层的特点。指出目前对地下卤水开发利用发展不均的现状,以及多以制盐为主,开发利用单一等现象。提出深化对地下卤水资源量的评价,加强对地下卤水综合利用的研究,组成跨行业的开发实体等建议。     

Phase Chemistry Study of the Zabuye Salt Lake Brine: Isothermal Evaporation at 15°C and 25°C

Zabuye Salt Lake in Tibet, China is a carbonate-type salt lake, which has some unique characteristics that make it different from other types of salt lakes. The lake is at the latter period in its evolution and contains liquid and solid resources. Its brine is rich in Li, B, K and other useful minor elements that are of great economic value. We studied the concentration behavior of these elements and the crystallization paths of salts during isothermal evaporation of brine at 15°C and 25°C. The crystallization sequence of the primary salts from the brine at 25°C is halite (NaCl) → aphthitalite (3K2SO4·Na2SO4) → zabuyelite (Li2CO3)→ trona (Na2CO3·NaHCO3·2H2O) → thermonatrite (Na2CO3·H2O) → sylvite (KCl), while the sequence is halite (NaCl) → sylvite (KCl) → trona (Na2CO3·NaHCO3·2H2O) → zabuyelite (Li2CO3) → thermonatrite (Na2CO3·H2O) → aphthitalite (3K2SO4·Na2SO4) at 15°C. They are in accordance with the metastable phase diagram of the Na+, K+-Cl?, CO32?, SO42?-H2O quinary system at 25°C, except for Na2CO3·7H2O which is replaced by trona and thermonatrite. In the 25°C experiment, zabuyelite (Li2CO3) was precipitated in the early stage because Li2CO3 is supersaturated in the brine at 25°C, in contrast with that at 15°C, it precipitated in the later stage. Potash was precipitated in the middle and late stages in both experiments, while boron was concentrated in the early and middle stages and precipitated in the late stage.