High-resolution shallow seismic identification of gas escape features in the sediments of Loch Tay, Scotland: tectonic and microbiological associations

High-resolution seismic reflection profiles (3·5 kHz) have revealed the presence of extensive interstitial gas accumulation within the sedimentary sequences of Loch Tay, Scotland, as identified by acoustic turbidity masking the seismic stratigraphy. Within the central section of the loch, in the deepest water area directly above the zone of the seismically active Loch Tay Fault, focused flows of gas through the sediment pile to the loch bed via chimneys and pockmarks, together with gas seeps within the water column, have been identified. Microbiological observations indicate that the gas is biogenic CH₄, produced by both chemoautotrophic (which use CO₂ as a source of carbon and H₂ as a source of energy) and aceticlastic species (which use acetate as a source of carbon and energy) of methanogens in the fine-grained, organic rich deposits that have been focused into the zone of accumulation in the deep central part of the loch. The spatial distribution of the gas escape features suggests that earthquake movements along the Loch Tay Fault are responsible for facilitating focused gas escape in this part of the loch, by the creation of new pathways and conduits through the sediment pile, along which gas can migrate upwards and exit into the water column. Relict pockmarks and associated chimneys identified in the seismic records indicate that gas escape has been taking place since Pleistocene times though the precise timings cannot be ascertained. This is the first time that such features have been reported from a lake in the UK.     

Tracking recorded fires using charcoal morphology from the sedimentary sequence of Prosser Lake, British Columbia (Canada)

Quantitative analyses of variations in morphological features of charcoal were undertaken in a ²¹⁰Pb-dated sediment core from Prosser Lake (British Columbia, Canada). Seven morphological types of charcoal were defined by particle shape, major-minor axis ratio, apparent porosity and progradation to unburned material. The distribution of morphotypes and total charcoal abundances were assessed as a proxy for fire events recorded between 1919 and 2000 and to subsequent mechanisms of transportation-sedimentation to lake sediments. Charcoal morphotypes showed distinct relationships to recorded area burned by fires. Fragile charcoal fragments with highly irregular porosity (termed Type M) displayed the strongest correlation to burned area (r² = 0.51; P = 0.0001) and did not produce any false-positive signal for fires recorded within a radius of 20 km around the lake. We infer that high porosity and low density Type M fragments are aerially transported and directly deposited on the lake, and that the fragility of Type M charcoal prevents significant quantities from being secondarily transported and incorporated into the sedimentary record. We propose that charcoal morphology is an important but underutilized technique that can yield important insights into fire type, proximity and transportation-sedimentation processes.     

Hydrogen isotope of individual n-alkanes from modern sediments and their application to environments

Hydrogen isotopes are commonly fractionated to a much greater extent and as a result display larger variations in δ values, In terms of the hydrogen isotope ratios of individual n-alkanes of 16 samples of modern sediments selected from four different locations in the southern part of Gansu, China, the δD values for most of the n-alkanes varied from -150‰-300‰, Variations in δD also occurred between different ranges of n-alkanes, effects of environmental changes on the hydrogen isotopic compositions of individual n-alkanes have been detected. Besides the δD values of n-alkanes, the δD values of lipids including pristane （Pr）, phytane （Ph） were also examined, by the combination of D/H ratios with molecular fingerprinting, Our results further support the notion that hydrogen isotopes of n-alkanes from modern sediments can act as paleoclimatic and paleoenvironmental proxies and provide invaluable new sources of information in the research of paleoenvironment reconstruction.     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.     

Sources of Sediment in Lake Pepin on the Upper Mississippi River in Response to Holocene Climatic Changes

Sediments from Lake Pepin on the Mississippi River, southeastern Minnesota, are used as provenance tracers to assess variations in hydrology and sediment-transport during the middle Holocene. Three rivers contribute sediment to Lake Pepin, and each catchment is characterized by a distinctly different geologic terrain. The geochemical fingerprint for each drainage basin was determined from the elemental composition of heavy minerals in the silt-sized fraction of modern sediment samples. Down-core elemental abundances were compared with these fingerprints by use of a chemical-mass-balance model that apportions sediment to the source areas. We observed a decreased contribution from the Minnesota River during the interval ~6700–5500 ¹⁴C yr BP, which we attribute to decreased discharge of the Minnesota River, likely controlled by a combination of precipitation, snow melt, and groundwater input to the river. This hydrologic condition coincides with the mid-Holocene prairie period recorded by fossil pollen data. The occurrence of this feature in a proxy record for hydrologic variations supports the hypothesis that the mid-Holocene prairie period reflects drier conditions than before or after in midwestern North America.     

早涝碱咸综合治理与生态环境良性循环

华北平原东部淡水资源短缺，旱涝碱成灾害限制了农业生产的可持续发展。海河的治理，解决了排洪排涝排咸出路。春季开发利用地下水包括微咸水和半咸水抗旱灌溉。夏季利用伏雨洗盐排咸，增大降雨入渗，减少径流流失，防治渍涝灾害，把降雨转化为地下水资源。秋冬引蓄河水，回灌地下水补源。以土壤与潜水的地层空间作为调节大气降水、土壤水、地下水、地表水的地下水库，以调控地下水埋深在临界动态为指标，最大限度地把时空分布不均的天然降雨转化为可持续利用的水资源。地表水地下水联合运用，促使水资源采补平衡，降雨灌溉淋洗脱盐强于干旱蒸发积盐过程，地下水淡化强于矿化过程。实现旱涝碱咸综合治理，水土资源可持续利用，经济社会可持续发展，生态环境良性循环。     

黑龙江省中部森林沼泽区 超低密度深穿透地球化学调查采样介质的确定

通过对王水溶矿法与四酸溶矿法的对比,元素在泛滥平原A层、B层沉积物及水系沉积物中的分配,以及这3种介质圈定的异常对比等综合因素的研究,确定了泛滥平原A层沉积物是黑龙江省中部森林沼泽区开展超低密度深穿透地球化学调查的有效采样介质。     

舞阳、襄城盐湖盆地未熟-低熟油成藏模式

舞阳、襄城凹陷下第三生活费为膏、盐岩相盐湖沉积。半咸水-咸水湖相、盐湖相是形成未熟-低熟油的良好环境，沉积旋回中期断坳式沉积形成了主要油源层系，其高丰度未熟烃类推岩体是形成未熟-低熟油藏的物质基础，中-高孔、中-高渗碎屑岩层构成了未熟-低熟油藏的重要储集层，并发育了较好的生储盖组合，这些有利条件为舞阳、襄城凹陷形成未熟-低熟油藏提供了重要保证。指出凹陷陡坡带为背斜、断鼻型油藏分布区，还可能有混合型油藏；中部洼陷带为岩性油藏、裂隙型油藏发育区；斜坡带主要发育断鼻型油藏。     

Temporal patterns of suspended sediment yield following moderate to extreme hydrological events recorded in varved lacustrine sediments

A 487‐year annually laminated (varved) sediment record from Nicolay Lake, Cornwall Island, in the Canadian High Arctic was evaluated to determine the impact that years with high sediment yields had on sediment yields in subsequent years. All of the 40 largest years showed evidence for increased sediment yield in the subsequent 10–30 years. The positive anomalies in lagging years were approximately scaled according to the size of the initiating year, although many intermediate years (25‐ to 100‐year recurrence) showed weak or variable responses. The smallest events considered (10‐ to 25‐year recurrence) showed a consistent, but low‐amplitude response. Additionally the 10‐year events revealed frequent negative sediment yield anomalies in the preceding decade. This behaviour was interpreted as a frequent sediment activation cycle initiated by the modest year, and leading to sediment yield hysteresis lasting 15–25 years. The largest years (greater than 50‐year recurrence) showed consistently above‐average sediment yields in the preceding decade, in part due to the frequent occurrence of moderate (Q₁₀) years. It is hypothesized that temporary storage of sediment and previous initiation of erosion sites resulted in extraordinary sediment yields during intense summer rainfall events. This study demonstrates the potential use of varved lake sediment records to improve our understanding of long‐term sediment dynamics. These records present an opportunity to further develop and test sediment dynamic and routing models to gain insight into the interaction of time and space in fluvial and sediment delivery processes. Copyright © 2002 John Wiley & Sons, Ltd.