http://www.sciencedirect.com/science/article/pii/S1674987111000594

A new model is suggested for the history of the Baikal Rift,in deviation from the classic two-stage evolution scenario,based on a synthesis of the available data from the Baikal Basin and revised correlation between tectonic-lithological-stratigraphic complexes(TLSC) in sedimentary sections around Lake Baikal and seismic stratigraphic sequences(SSS) in the lake sediments.Unlike the previous models,the revised model places the onset of rifting during Late Cretaceous and comprises three major stages which are subdivided into several substages.The stages and the substages are separated by events of tectonic activity and stress reversal when additional compression produced folds and shear structures.The events that mark the stage boundaries show up as gaps,unconformities,and deformation features in the deposition patterns. The earliest Late Cretaceous-Oligocene stage began long before the India-Eurasia collision in a setting of diffuse extension that acted over a large territory of Asia.The NW-SE far-field pure extension produced an NE-striking half-graben oriented along an old zone of weakness at the edge of the Siberian craton.That was already the onset of rift evolution recorded in weathered lacustrine deposits on the Baikal shore and in a wedge-shaped acoustically transparent seismic unit in the lake sediments.The second stage spanning Late Oligocene-Early Pliocene time began with a stress change when the effect from the Eocene India-Eurasia collision had reached the region and became a major control of its geodynamics.The EW and NE transpression and shear from the collisional front transformed the Late Cretaceous half-graben into a U-shaped one which accumulated a deformed layered sequence of sediments.Rifting at the latest stage was driven by extension from a local source associated with hot mantle material rising to the base of the rifted crust.The asthenospheric upwarp first induced the growth of the Baikal dome and the related change from finer to coarser molasse deposition.With time,the upwarp became a more powerful stress source than the collision,and the stress vector returned to the previous NW-SE extension that changed the rift geometry back to a half-graben. The layered Late Pliocene-Quaternary subaerial tectonic-lithological-stratigraphic and the Quaternary submarine seismic stratigraphic units filling the latest half-graben remained almost undeformed.The rifting mechanisms were thus passive during two earlier stages and active during the third stage. The three-stage model of the rift history does not rule out the previous division into two major stages but rather extends its limits back into time as far as the Maastrichtian.Our model is consistent with geological, stratigraphic,structural,and geophysical data and provides further insights into the understanding of rifting in the Baikal region in particular and continental rifting in general.     

世界水溶气资源分布、现状及问题

针对世界水溶气资源及国内外勘探开发现状统计结果表明,全世界水溶气资源丰富,总量达33 837×1012m3,这比常规天然气资源量(293×1012m3)高两个数量级;中国主要的含油气盆地中水溶气资源也很丰富,43个盆地的水溶气资源量的估算结果达到19×1012m3。对水溶性气藏成藏条件的分析研究认为:丰富的气源、异常高地层压力、储集层和保存条件是形成该类气藏的主要条件。根据天然气溶解的Henry经验定律、分子间隙溶解机理分析,认为溶解和脱气过程中除了考虑温度和压力变化,还存在构造震荡脱气等脱气过程。由于对不同的地层水条件下,天然气的溶解度变化的认识尚不太清晰,且富集条件及静态气藏形成条件是否能够促成动态气藏的形成,以及其他因素对气藏有何影响亦需要深入研究,对国内水溶性气藏资源需要进行系统的评价,确定气藏的有效开发技术方法,以促进水溶性天然气的勘探和开发,增加我国天然气供给的途径。     

Reservoir Characteristics and Genetic Mechanisms of the Mesozoic Granite Buried Hills in the Deep‐water of the Qiongdongnan Basin,Northern South China Sea

Due to its structure,rock and mineral composition,fluid and other factors,the granite Buried Hill Reservoir is highly heterogeneous with a complex longitudinal structure and a reservoir space made up of a combination of dissolution pores and fractures.This paper is based on current understanding of tectonic evolution in the northern part of the South China Sea,in conjunction with the seismic phase characteristics.It is determined that the meshed fault system was formed by three stages of movement-tectonic compression orogeny during the Indochinese epoch,strike-slip compression-tension during the Yanshanian Period,early fracture extension activation during the Himalayan-which controlled the distribution of the Buried Hill Reservoir.Drilling revealed two types of buried hills,faulted anticline and fault horst,their longitudinal structure and the reservoir space type being significantly different.The mineral composition,reservoir space and diagenetic characteristics of the reservoir rocks and minerals were analyzed by lithogeochemistry,micro section and logging etc.,it thus being determined that the Mesozoic rocks of the Songnan Low Uplift in the Qiongdongnan Basin are mainly composed of syenogranite,granodiorite,monzogranite,which is the material basis for the development of the Buried Hill Reservoir.The content of felsic and other brittle minerals is more than 70%,making it easy for it to be transformed into fractures.At the same time,the weathering resistance of granodiorite and monzogranite is weaker than that of syenogranite,which is easily weathered and destroyed,forming a thick sand gravel weathering zone.With increasing depth of burial,weathering and dissolution gradually weaken,the deep acidic fluid improving the reservoir property of internal fractures and expanding the vertical distribution range of the reservoirs.The research results lay a foundation for the exploration of Buried Hill in the deep-water area of the Qiongdongnan Basin.     

LCT型伟晶岩及其锂矿床成因概述

花岗伟晶岩具有与低共熔花岗岩相似的矿物和化学组成,通常与高分异花岗岩具有成因联系。花岗伟晶岩划分为富Li-Cs-Ta (LCT)、富Nb-Y-F (NYF)和混合的LCT+NYF型,其中LCT型伟晶岩以过铝质,富集助熔组分(H₂O、F、P、B)、稀有元素(Li、Rb、Cs、Nb、Ta、Be、Sn),极其低的Nb/Ta比值(<5)为特征。通常LCT型伟晶岩显示内部分带,主要包括边界带、壁带、中间带和核部带;此外,可能还发育交代体、层状细晶岩和晶洞。大多数LCT型伟晶岩形成与(同造山)-晚造山的过铝质S型、I型或混合的S+I型花岗岩具有成因联系。对于壳源沉积岩小比例部分熔融直接形成的伟晶岩,通常形成于伸展背景下的晚造山和造山后阶段,侵入于典型的低压角闪岩-高绿片岩相的变沉积岩中。伟晶岩外带(包括边缘带、壁带、细晶岩)中的细粒和细晶岩结构、UST (单向固结结构)是液相线过冷所致,而伟晶岩内带(中间带、核部带)中粗大矿物形成、矿物分带以及稀有金属矿物的饱和结晶是助熔组分(H₂O、B、P、F)、稀有金属(Li、Rb、Cs、Be、Nb、Ta)通过...     

再论煤中大分子基本结构单元演化的拼叠作用

芳构化作用和环缩合作用的传统煤化作用理论具有一定局限性,煤中基本结构单元拼叠作用是高煤级煤演化的特有机理。拼叠作用显著发生的起点位于镜质组最大反射率Ro,max为6．0％附近,大分子化学键的均裂提供了拼叠作用得以实现的微化学环境条件,其实质是一种“动力化学”过程,与氧接芳碳等有关的大量“均裂”是在短暂的煤化阶段中突然出现的,导致“拼叠作用”的显著发生具有“阶跃式”特征,是造成高煤级煤中期到后期阶段大分子基本结构单元急剧增大的根本原因和主要地球化学机理。     

含铁绿柱石的改色机制研究

含铁绿柱石经γ射线辐照或特定温度热处理,可因铁价态的改变引起颜色发生相应变化。处理前后的吸收光谱和顺磁共振谱研究表明,辐作用使隧道位的Ｆｅ＾２＋氧化Ｆｅ％３＋,八一位上的Ｆｅ＾３＋还原为Ｆｅ＾２＋,热处理使隧道位及八面体位Ｆｅ＾３＋均还原为Ｆｅ＾２＋。     

安徽大别山团岭花岗岩体岩石学特征及成因

团岭花岗岩体侵位于大别山南部超高压变质带变质表壳岩中, 由细粒少斑二长花岗岩和中粒少斑二长花岗岩组成。通过岩石学、岩石化学、地球化学的研究, 确定其为Ｓ 型花岗岩, 源岩可能来自大别山变质杂岩。结合同位素资料, 认为其属燕山期花岗岩, 侵位机制为底辟式强力就位。     

辽东湾凝析气田超压成因及侧向传递机制初探

位于辽东湾西部低凸起北端的JZ20-2超压凝析气田,离供烃中心较远,压力系数却达到1.56~1.7,这在我国东部裂谷盆地比较少见。经过综合分析,作者认为JZ20-2凝析气田异常高压的形成与其所处的特殊地质背景紧密相关,辽中凹陷沙河街组三段超压凝析油气沿不整合面、砂体输导通道向辽东湾西部低凸起的运移、充注和能量的侧向传递是JZ20-2凝析气田异常高压形成的根本原因,而上覆东营组二段下亚段-东营组三段巨厚的强超压泥岩封盖和辽西3号边界断层侧向遮挡共同构成的优越封闭环境是超压保存的必要条件。本文分析了该气田超压特征及其远距离超压侧向传递的成因机制,不仅有助于揭示辽东湾西部低凸起超压流体运移聚集的规律和成藏作用,而且可能提供了一个超压远距离侧向传递的典型实例。     

塔里木盆地凝析气田的地质特征及其形成机制

塔里木盆地凝析油气资源丰富,已发现了二十余个凝析气田,包括库车坳陷的陆相油气来源的凝析气田和台盆区海相烃源岩来源的凝析气田;储层有碎屑岩,也有碳酸盐岩;时代自奥陶系至新生代均有分布。这些凝析气田的气油比分布在600~19900m³/m³,凝析油含量40~750g/m³;储层温度在78~155℃;地层压力在37~111MPa。研究认为,塔里木盆地凝析气藏的成因类型可以分为原生凝析气藏和次生凝析气藏。其中,以库车坳陷迪那2凝析气田为代表的煤系烃源岩在高演化阶段(镜质体反射率Ro为1.2%~2.0%),即凝析油和湿气生成带所形成的原生腐植型凝析气藏或煤成型凝析气藏。次生凝析气藏包括两类:陆相油气来源的多期充注,晚期干气对早期油藏发生混合改造,形成了以牙哈为代表的陆相油气成因的次生凝析气藏;以海相油气来源,多期油气充注与晚期干气气侵,造成蒸发分馏,在运移、聚集和成藏过程中烃体系分异、富化,发生反凝析作用,从而导致次生凝析气藏的形成。随着塔里木盆地勘探向深层转化,地层的温度和压力逐渐增高,烃类演化程度的升高,不同生烃阶段的烃体系混合也将更为普遍,次生凝析气藏也将更为普遍,因此,以海相油气来源的次生成因型凝析气藏将成为勘探的主体。     

浙西北淳安银山地区银铅锌矿床矿石结构构造、矿石成分及成矿机制

浙西北与同处钦杭成矿带东段的赣东北和皖南相比,由于其地质研究程度较低,在该区尚未能找到大型多金属矿床。近年来,随着地质勘查程度的不断提高,淳安地区银山一带发现中型以上银铅锌矿床。本文选取银山矿区钻井岩芯中富含银、铅、锌矿石样品,利用显微镜观察和电子探针分析等方法,对其中的银等多金属的矿石结构构造、矿石成分及成矿机制等进行了较深入的研究。研究表明,银山地区多金属(银、铅、锌)矿体主要分布在蓝田组上段与上覆皮园村组之间的接触带中,另有部分处于蓝田组层内岩性变化的界面以及蓝田组底部白云质灰岩和下伏南沱组含砾泥岩之间,均呈似层状展布。矿石呈自形-半自形粒状结构、他形粒状结构和交代残余结构以及块状构造、浸染状构造和网脉状构造。金属矿物组合主要分为黄铁矿-黄铜矿-方铅矿-闪锌矿和磁黄铁矿-毒砂-闪锌矿两组,其中前者位于蓝田组顶部和皮园村组之间,属于中低温热液型的矿物组合,后者位于蓝田组下部和南沱组之间,属于中温热液型的矿物组合。通过对不同金属矿物中银含量的对比分析,得出银山地区银元素主要赋存在方铅矿中。脉石矿物有石英、方解石、白云母、绿泥石、单斜辉石等,尤其在矿石中多见的细粒单斜辉石按其成分上的差异分为透辉石和钙铁辉石两类,指示了热液作用对成矿的显著影响。综上所述,笔者认为浙西北银山多金属矿床成因很可能为早期层控-后期中低温热液改造的叠生型矿床。其形成机制是:震旦纪时期海相火山喷流沉积使得部分多金属成层聚集,蓝田组地层为银山多金属矿床的形成提供了部分的物质来源,加里东期的变质变形作用及其发育的断裂构造也具有一定的控制作用;随后,大规模的燕山期花岗质岩浆及其流体组分沿断裂带上侵,不仅使得原有地层中的多金属元素进一步富集,而且其本身也可能带入部分多金属流体,从而使得富含多金属元素热液流体在具有地球化学障的岩性界面上富集成矿。此项研究对该地区及邻区进一步找矿勘探具有重要的科学意义和应用价值。