冲绳海槽中部Jade热液活动区中海底热液沉积物的硫同位素组成及其地质意义

测定了冲绳海槽中部Jade热液活动区中18个热液沉积物样品的硫同位素组式,其中10个硫化物样品的δ34S值为5.2×10-3～7.2×10-3,7个硫酸盐样品的34S值为16.3×10-3～22.3×10-3,1个自然硫样品的δ34S值为8.2×10-3热液沉积物的硫主要来自中、酸性火山岩和海水,并且在流体与沉积物相互作用过程中海底沉积物也可能为热液沉积物的形成提供部分的硫.导致本区热液沉积物中硫化物与其他热液活动区的硫同位素组成不同的原因,主要是各热液活动区的硫源以及有关岩浆活动和构造演变的不同.海底热液体系中硫的演化是一个复杂的过程,涉及被加热海水的上升、流体与火山岩的相互作用、海水硫酸盐和中、酸性火山岩中流的混合作用以及流体与沉积物相互作周等一系列海底热液活动,其中海水和中、酸性火山岩的相互作用是本区硫演化的一个重要机制.     

冲绳海槽Jade热液活动区块状硫化物的铅同位素组成及其地质意义

新测行Ｊａｄｅ热液活动区中５件块状硫化物样品的铅同位素组成,具有较小的变化范围,表现出较均一的铅同位素组成特征。在Ｐｂ－Ｐｂ图解上,块状硫化物的铅同位素数据构成线形排列,与该区沉积物和蚀变火山岩的铅同位素组成一致,而与该区新鲜火山岩相比具较高的放射成因铅,证实了该区海底块状硫化物中的铅是由沉积物长英质火山岩来源铅共同构成的混合铅。不同热液活动区铅同位素组成对比研究表明,地质－构造环境的不同是导致各     

南海晚渐新世滑塌沉积指示的地质构造事件

南海北部ODP1148站晚渐新世至早中新世沉积以滑塌堆积和长时间沉积缺失为主要特征.由构造活动引起的沉积间断始于渐新世中期28.5 Ma至早中新世23 Ma左右结束.主间断面位于25 Ma, 亦即滑塌沉积层的底界.4次沉积间断总共造成至少3 Ma沉积记录的缺失.综合岩性、古生物年代测定、地球化学等分析结果, 表明南海晚渐新世的海底扩张模式呈多次跳跃式, 并以“25 Ma事件”为型变高峰.这一系列构造活动是欧亚、澳大利亚、菲律宾-太平洋板块相互作用的结果, 直接导致南海向前期裂谷更发育, 红河大断裂左擦拉张更强的南部扩张的转型.1148站的滑塌沉积为此次南海扩张转型提供了直接的证据.      

个旧锡矿区域地壳演化与成矿探讨

个旧锡多金属矿床是驰名中外的特大型矿床，过去认为是燕山晚期“花岗岩岩浆期后气液矿床”。但通过探讨区域上前震旦纪地壳演化、震旦纪-早古生代地壳演化、泥盆纪-三叠纪地壳演化以及侏罗纪-第四纪地壳演化，以及与成矿之间的关系，发现个旧矿区至少经历了印支中晚期海底基性火山-沉积成矿、印支中晚期海底喷流热水沉积成矿、燕山晚期花岗岩叠加改造成矿以及喜山期陆相表生沉积成矿作用，厘定了个旧锡矿区的印支中晚期海底基性火山．沉积Sn-Cu-Zn(Au)矿床系列、印支中晚期海底喷流-沉积Sn-Cu-Pb-Zn矿床系列、燕山晚期花岗岩叠加改造Sn-Cu-W-Be-Bi-Pb-Zn-Ag矿床系列、喜山期陆相表生沉积砂矿矿床系列等4大矿床系列及12种矿床类型。     

现代海底块状硫化物矿床储量估算方法探讨

海底块状硫化物矿床具有巨大的经济价值和良好的开发前景。但是由于勘探难度和技术手段的限制,在全球已经发现的600多个海底热液喷口和硫化物矿床中,不到5%的矿床进行了详细的勘探,进行资源量计算的矿床更是屈指可数。选择适当的方法估算储量对于深海资源开发意义重大。本文系统总结了前人估算海底硫化物储量的方法,并以勘探程度相对较高、数据资料相对丰富的Atlantis-II-Deep矿床和Solwara 1矿床为例,评析了前人采用不同储量计算方法得到的结果和各种方法计算的准确性;针对有一定钻孔数据的TAG硫化物堆丘,采用距离反比法重新计算了储量,并和块段法估算的结果进行对比。得到以下结论:(1)海底硫化物矿体形态是制约储量估算方法适用性的一个重要因素;(2)传统几何法可以在极低勘探条件下估算海底硫化物储量量级;(3)对于海底硫化物储量估算,地质统计学的精度高于传统几何法;(4)较高勘探条件下距离反比法可以与地质统计学相互对照、验证;(5)在一定钻孔数量的条件下,可以应用距离反比法进行海底硫化物储量估算。     

Bulk-rock Major and Trace Element Compositions of Abyssal Peridotites: Implications for Mantle Melting, Melt Extraction and Post-melting Processes Beneath Mid-Ocean Ridges

This paper presents the first comprehensive major and traceelement data for 130 abyssal peridotite samples from the Pacificand Indian ocean ridge–transform systems. The data revealimportant features about the petrogenesis of these rocks, mantlemelting and melt extraction processes beneath ocean ridges,and elemental behaviours. Although abyssal peridotites are serpentinized,and have also experienced seafloor weathering, magmatic signaturesremain well preserved in the bulk-rock compositions. The betterinverse correlation of MgO with progressively heavier rare earthelements (REE) reflects varying amounts of melt depletion. Thismelt depletion may result from recent sub-ridge mantle melting,but could also be inherited from previous melt extraction eventsfrom the fertile mantle source. Light REE (LREE) in bulk-rocksamples are more enriched, not more depleted, than in the constituentclinopyroxenes (cpx) of the same sample suites. If the cpx LREErecord sub-ridge mantle melting processes, then the bulk-rockLREE must reflect post-melting refertilization. The significantcorrelations of LREE (e.g. La, Ce, Pr, Nd) with immobile highfield strength elements (HFSE, e.g. Nb and Zr) suggest thatenrichments of both LREE and HFSE resulted from a common magmaticprocess. The refertilization takes place in the ‘cold’thermal boundary layer (TBL) beneath ridges through which theascending melts migrate and interact with the advanced residues.The refertilization apparently did not affect the cpx relicsanalyzed for trace elements. This observation suggests grain-boundaryporous melt migration in the TBL. The ascending melts may notbe thermally ‘reactive’, and thus may have affectedonly cpx rims, which, together with precipitated olivine, entrappedmelt, and the rest of the rock, were subsequently serpentinized.Very large variations in bulk-rock Zr/Hf and Nb/Ta ratios areobserved, which are unexpected. The correlation between thetwo ratios is consistent with observations on basalts that D_Zr/D_Hf< 1 and D_Nb/D_Ta < 1. Given the identical charges (5⁺ forNb and Ta; 4⁺ for Zr and Hf) and essentially the same ionicradii (R_Nb/R_Ta = 1·000 and R_Zr/R_Hf = 1·006–1·026),yet a factor of 2 mass differences (M_Zr/M_Hf = 0·511 andM_Nb/M_Ta = 0·513), it is hypothesized that mass-dependentD values, or diffusion or mass-transfer rates may be importantin causing elemental fractionations during porous melt migrationin the TBL. It is also possible that some ‘exotic’phases with highly fractionated Zr/Hf and Nb/Ta ratios may existin these rocks, thus having ‘nugget’ effects onthe bulk-rock analyses. All these hypotheses need testing byconstraining the storage and distribution of all the incompatibletrace elements in mantle peridotite. As serpentine containsup to 13 wt % H₂O, and is stable up to 7 GPa before it is transformedto dense hydrous magnesium silicate phases that are stable atpressures of 5–50 GPa, it is possible that the serpentinizedperidotites may survive, at least partly, subduction-zone dehydration,and transport large amounts of H₂O (also Ba, Rb, Cs, K, U, Sr,Pb, etc. with elevated U/Pb ratios) into the deep mantle. Thelatter may contribute to the HIMU component in the source regionsof some oceanic basalts. KEY WORDS: abyssal peridotites; serpentinization; seafloor weathering; bulk-rock major and trace element compositions; mantle melting; melt extraction; melt–residue interaction; porous flows; Nb/Ta and Zr/Hf fractionations; HIMU mantle sources     

新世纪的大洋钻探

较为详细地介绍了大洋钻探计划（ODP）的科学目标，研究主题及其重要的科学意义，大洋钻探计划是当今举世瞩目的国际性海洋科学研究计划，其前身深海钻探计划（DSDP）孕育了20世纪70年代的地学革命,为“新全球构造理论”－－板块构造学说的发展提供了关键性的证据。自1985年开始的ODP成功地探查了地质历史演化中塑造我们这颗星球并决定了其现今环境状态的各种地质过程，揭示了控制地壳形成，海洋化学，海洋的深部和表面循环的各种地质以及生物圈和环境物理化学间相互作用的复杂性，DSDP和ODP的成功为实施新世纪海洋钻探－综合海洋钻探项目（IODP）的目标铺平了道路，IODP是在21世纪初即将实施的新的大洋钻探计划。     

基于声波探测海底浅层沉积物特性的方法研究

利用声波在水中的传输特性进行海底浅层沉积物特性的探测。在实践应用中有实验室方法、现场测量方法和海底声学遥测方法,并研制出大量的仪器。由于海上和海底实际条件的限制,声波探测方法都存在一定的不足之处,由此提出了声衰减测试沉积物特性以及建立实验室模拟海底环境探测方法的设想。     

Diverse Range of Mineralization Induced by Phase Separation of Hydrothermal Fluid: Case Study of the Yonaguni Knoll IV Hydrothermal Field in the Okinawa Trough Back-Arc Basin

The Yonaguni Knoll IV hydrothermal vent field (24°51′N, 122°42′E) is located at water depths of 1370–1385 m near the western edge of the southern Okinawa Trough. During the YK03–05 and YK04–05 expeditions using the submersible Shinkai 6500, both hydrothermal precipitates (sulfide/sulfate/carbonate) and high temperature fluids (Tmax = 328°C) presently venting from chimney‐mound structures were extensively sampled. The collected venting fluids had a wide range of chemistry (Cl concentration 376–635 mmol kg^?1), which is considered as evidence for sub‐seafloor phase separation. While the Cl‐enriched smoky black fluids were venting from two adjacent chimney‐mound structures in the hydrothermal center, the clear transparent fluids sometimes containing CO₂ droplet were found in the peripheral area of the field. This distribution pattern could be explained by migration of the vapor‐rich hydrothermal fluid within a porous sediment layer after the sub‐seafloor phase separation. The collected hydrothermal precipitates demonstrated a diverse range of mineralization, which can be classified into five groups: (i) anhydrite‐rich chimneys, immature precipitates including sulfide disseminations in anhydrite; (ii) massive Zn‐Pb‐Cu sulfides, consisting of sphalerite, wurtzite, galena, chalcopyrite, pyrite, and marcasite; (iii) Ba‐As chimneys, composed of barite with sulfide disseminations, sometimes associated with realgar and orpiment overgrowth; (iv) Mn‐rich chimneys, consisting of carbonates (calcite and magnesite) and sulfides (sphalerite, galena, chalcopyrite, alabandite, and minor amount of tennantite and enargite); and (v) pavement, silicified sediment including abundant native sulfur or barite. Sulfide/sulfate mineralization (groups i–iii) was found in the chimney–mound structure associated with vapor‐loss (Cl‐enriched) fluid venting. In contrast, the sulfide/carbonate mineralization (group iv) was specifically found in the chimneys where vapor‐rich (Cl‐depleted) fluid venting is expected, and the pavement (group v) was associated with diffusive venting from the seafloor sediment. This correspondence strongly suggests that the subseafloor phase separation plays an important role in the diverse range of mineralization in the Yonaguni IV field. The observed sulfide mineral assemblage was consistent with the sulfur fugacity calculated from the FeS content in sphalerite/wurtzite and the fluid temperature for each site, which suggests that the shift of the sulfur fugacity due to participation of volatile species during phase separation is an important factor to induce diverse mineralization. In contrast, carbonate mineralization is attributed to the significant mixing of vapor‐rich hydrothermal fluid and seawater. A submarine hydrothermal system within a back‐arc basin in the continental margin may be considered as developed in a geologic setting favorable to a diverse range of mineralization, where relatively shallow water depth induces sub‐seafloor phase separation of hydrothermal fluid, and sediment accumulation could enhance migration of the vapor‐rich hydrothermal fluid.     

遥感影像地形校正物理模型的简化与改进

针对考虑太阳直接辐射、天空散射辐射以及来自于附近地表反射辐射的复杂地形EMT 遥感影像地形校正物理模型公式复杂、计算繁琐、不易实施的特点以及存在过度校正的缺陷,对该物理模型进行简化和改进。提出一套简化模型相关参数,即r值,Vt,Vd,T↓(λ,θ)等的计算方案,从而简化计算过程,提高计算效率。并针对该地形校正物理模型朗伯体假设的缺陷,引入Minnaert参数k时模型进行非朗伯体修正。简化和改进的地形校正物理模型的校正实验结果表明该模型很好地消除了复杂地形EMT 遥感影像的地形阴影,从而证明该地形校正物理模型的简化和改进方案可行。