Hydrologic and geochemical properties of the San Andreas fault at the Stone Canyon well

The Stone Canyon well penetrates 600 m of highly fractured and severely altered quartz diorite intimately associated with the creeping segment of the San Andreas fault of central California. Geophysical logs reveal a complex hydrology dominated by major fractures. Fluid pressure in some fractures is sufficient to prevent invasion of the formation by heavy drilling mud, implying pore pressures at least 10% higher than hydrostatic ones. At least three chemically distinct waters are encountered, including a chloride brine clearly segregated from the shallow, potable groundwater. Chemical alteration of the quartz diorite persists throughout the well, far below the depth where the water-rock reactions responsible for the ubiquitous chlorite and mixed-layer clays can be considered weathering. Whole-rock ¹⁸O analyses indicate significant interaction of the rocks with a low ¹⁸O fluid within some of the fractured and altered zones, whereas a deeper sample shows¹⁸O enrichment. High pore pressures encountered in Stone Canyon may be due to tectonic compression. Measurements of temporal variations in the pore pressure at the well may provide a means of predicting earthquakes along this segment of the San Andreas fault.     

Frost weathering and the saturation of coastal rocks

Measurements were made of the water content in coastal rocks, by simulating tidal oscillations in the laboratory, and by field measurement in eastern Canada. If rapid freezing takes place upon exposure to the air, saturation levels may be high enough to permit frost weathering in fine grained rocks in the lower portions of the intertidal zone. Near the high tidal level, however, it may be dependent upon a supply of water from the ice foot and from melting snow. If freezing is slow, frost action may be inhibited by desorption of the rocks while they are exposed by the ebb tide. There was no evidence of a level of permanent sea water saturation within the intertidal zone. Ambient temperature and humidity may affect the rate of rock desorption.     

Roof bolting in underground mining: a state-of-the-art review

Conclusions With continuing investigations and developments, roof bolting today can in most cases successfully reinforce the mine roof in underground mining. In order to cope with the increasing use of roof bolts, efforts should be made to maximize the safety and minimize the cost. With regard to mechanical bolting, two important parameters need more advanced improvements and study, namely, optimum design of the shape and type of expansion shell and optimum bolt tension for a specific bolt pattern. For the fully grouted resin bolt, the most critical requirement is to develop a fast-setting, low-cost, intoxic, inflammable grouting material that can be used in the high speed mining cycle. It should be noted that geological conditions such as the strata type, rock properties,in situ stress, and planes of weakness play an important role in the successful application of any roof bolting system. These factors should be specified as accurately and quantitatively as possible in the design of any roof bolting system. Finally, proper and careful installation and continuous monitoring are imperative for the success of any roof bolting system.     

Importance of the oxidation/maturation pair in the evolution of humic coals

The natural thermal evolution of type III coals (Humic origin) is expressed during diagenesis by a loss of oxygen as CO₂ and H₂O. Other phenomena such as oxidation can cause extensive geochemical modifications and may complicate the effects of simple maturation.Humic coals from the Jurassic in southeastern Utah were studied by elemental analysis, Rock-Eval pyrolysis and infrared spectroscopy. In a van Krevelen diagram (atomic H/C vs atomic O/C), the samples fall within the envelope defined by 860 reference humic coals covering the entire range of diagenesis. Nevertheless, various criteria (geochemical, petrographic, geological and microscopic) cast doubt upon the interpretation that such a distribution of coal composition results from thermal maturation.The same criteria indicate the intervention of redox phenomena. Comparison of our results with those from artificial and natural oxidation shows that these coals were subjected to an oxidation process different from ordinary late alteration. This process was probably due to circulation of highly oxidizing saline water causing oxygen fixation and the transformation of carboxyls into carboxylate anions. The cations that were fixed are oxygenated and certainly contain calcium, but also uranium and perhaps several other cations (V, Mo, Fe...). Emphasis is placed on possible mechanisms that cause such phenomena.     

内蒙甲生盘层控硫铅锌矿床汞的岩石地球化学特征

本文以526个岩石样品的Hg、Zn测定及闪锌矿单矿物Hg的热释温度测定为基础,探讨了甲生盘层控硫铅锌矿床Hg的岩石地球化学异常特征,提出了以Hg×100/Zn为指标研究成矿后侵入体的热力对Hg的驱赶作用的可能性。从岩体向外250m的距离内,该比值逐渐从2升高到7。原生Hg异常的研究有利于解释该地壤中汞气异常的形成。已经证实,壤中汞气测量对寻找这类矿床是有效的。     

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.     

Biomarker distributions in asphaltenes and kerogens analysed by flash pyrolysis-gas chromatography-mass spectrometry

Biomarker distributions in a suite of asphaltenes and kerogens have been analysed by flash pyrolysis directly coupled to a GCMS system. Attention has been focussed on biomarkers of the sterane and triterpane types. The sample suite under investigation consists of sediments with different kerogen types and some crude oils. Biomarker distributions in the pyrolysates have been compared with the “free” biomarkers in the corresponding saturated hydrocarbon fractions.The analyses show significant differences between the distributions of the free biomarkers and those in the pyrolysates. The latter have lower amounts of steranes while diasteranes are absent or present at low concentrations only. In the triterpane traces a shift of maximum intensity from C₃₀ (free compounds) to C₂₇/C₂₉ is observed. Furthermore, the pyrolysates contain a set of triterpenes (not present among the free compounds), and there is a selective loss of “non-regular” triterpanes that are present in the saturated hydrocarbon fractions. The observed differences between pyrolysates and free hydrocarbons can be explained partly by the processes occurring during pyrolysis such as bond rupture and subsequent stabilisation of primary pyrolysis products. To a certain extent these differences also show that maturation processes occurring in sediments have effects on free biomarker molecules different from those on molecules that are enclosed in a macromolecular matrix (kerogen or asphaltenes).Differences between biomarker distributions of asphaltene and kerogen pyrolysates are relatively small. A comparison with the pyrolysates from extracted whole sediments suggests that these differences are mainly caused by interactions between the organic material and the mineral matrix during pyrolysis.Oil asphaltenes behave differently from sediment asphaltenes as their pyrolysates are more similar to the corresponding saturated hydrocarbon fractions, i.e. the differences described above are observed to a much smaller extent. This different behaviour appears to be the result of coprecipitation of a part of the maltene fraction with the oil asphaltenes.     

Complex behaviour of a coal sample in a large scalein situ compression test

Summary A large scalein situ compression test of a laminated coal cube is described. The cube was uniformly loaded by a system of hydraulic jacks supplied simultaneously from one pump. At the same time both load and deformations were controlled. Deformations were measured by 60 longitudinal gauges located at the side surface of the cube in the regular net. Due to the heterogeneity of the rock the readings showed scatter. As a first approximation, the scattered data were fitted to the plane using the least square method. Orientations of the planes were analysed and show permanent relative movement between adjacent lamina indicating complex behaviour of the cube under loading. Detailed analysis of this behaviour indicated that the cube was subjected to both bending and twisting.     

东海陆架盆地岩石密度与磁性

本文在东海陆架盆地２０口钻井１６０块岩心标本物测定和１７口钻井密度测井的基础上，通过整理、分析、统计，给出了东海陆架盆地的岩石密度和磁性特征。