张家口高家庄多金属矿床成矿时代厘定及其地质意义

太行山北东向构造-岩浆岩带中发育有多个燕山期酸性岩体,目前已发现的多金属及贵金属矿床与燕山期岩体有着密切的成因联系。本文对分布于大河南岩体北西侧的高家庄多金属矿床采用硫化物Rb-Sr法进行了同位素定年,(144.5±1.4)Ma等时线测年结果与采用锆石U-Pb法确定的大河南岩体形成时代接近;此外,矿床硫化物的初始锶同位素比值为0.7122~0.7123,显示成矿物质来源以壳源为主。这与大河南岩体主要为陆壳物质部分熔融形成的认识相一致,即高家庄多金属矿床在成矿物质来源上与大河南岩体的形成与演化之间具有密切的成因联系。大河南岩体的形成时限与区内多金属矿床形成时限与中国东部第二次大规模成矿期一致,此时区内地球动力学环境正处于主应力场由近南北向转换到近东西向的构造体制大转折时期。在此独特的成矿背景下,深熔作用形成的花岗质岩浆沿NNE向与原EW向断裂交汇处侵位。花岗质岩浆高侵位但未发生喷发作用,使挥发组分和成矿元素得以保存,从而为大规模成矿作用提供了必须的热、流体、挥发组分和成矿元素。     

点苍山-哀牢山杂岩带中北段嘎洒地区变沉积岩的成因矿物学与变质演化特征

点苍山-哀牢山变质杂岩带中北段嘎洒地区出露了多种典型的变沉积岩,其中夕线石榴黑云二长片麻岩和二云母片岩保存多期/多阶段矿物相转变特征,本文通过岩相学和矿物化学的综合分析,并结合传统矿物对温压计的估算结果,限定上述典型变沉积岩峰期角闪-麻粒岩相(M1)阶段、近等温减压-高温剪切变形阶段(M2)和晚期退变质(M3)阶段的矿物组合及变质温压条件。峰期角闪-麻粒岩相(M1)阶段的矿物组合为:石榴石(Grt)+板柱状夕线石(Sil1)+黑云母(Bt1)+钾长石(Kfs)+斜长石(Pl)+石英(Qtz)+钛铁矿(Ilm),变质温度压力条件为t=690~750℃,p=690~810 MPa;近等温减压-高温剪切变形阶段(M2)阶段,稳定矿物组合为:Grt+Sil2+Bt2+Kfs+Pl+Qtz+Ilm,黑云母在强烈走滑剪切作用下发生脱水熔融反应:2 Bt→Sil+6(Mg,Fe)O+K_2O+5 Qtz+2 H_2O,石榴石、黑云母和夕线石等受到剪切变形影响而发生强烈定向,形成的温度压力条件为t=650~720℃,p=450~630 MPa;晚期退变质阶段(M_3)的稳定矿物组合为:Qtz+Bt+Ms+Pl,退变的温度压力条件为t=580~640℃,p=400~500MPa。其变质演化p-T轨迹样式具有近等温减压的顺时针型式,表明点苍山-哀牢山变质杂岩带曾经历了一次明显的俯冲-碰撞造山事件,峰期变质可达到角闪-麻粒岩相;在碰撞后的构造折返过程中,上述变质岩石发生强烈的高温剪切变形作用,并伴随着黑云母等含水矿物的脱水熔融。     

西天山巴音布鲁克地区早古生代成矿地质环境:岩浆岩及其时代和元素同位素约束

西天山位于中亚造山带(CAOB)西南部,是其重要组成部分。CAOB晚古生代金属成矿环境和过程尤为典型,但早古生代成矿地质环境还不甚清楚。新疆巴音布鲁克地区出露(原定时代晚志留世)巴音布鲁克组火山岩夹浅海相碎屑岩和灰岩,是认识西天山早古生代成矿地质环境的难得对象。巴音布鲁克组出露于Nikolaev-那拉提山北缘断裂与Atbash-Inylchek-那拉提山南缘断裂之间的中天山,在巴音布鲁克地区典型发育,火山岩包括玄武岩、玄武安山岩、英安岩、流纹岩及相应的火山碎屑岩,其中侵入岩有正长斑岩和花岗闪长岩。LA-ICP-MS测得玄武安山岩、英安岩、正长斑岩、花岗闪长岩、流纹岩锆石U-Pb年龄分别为455.6±8.1Ma、444.5±1.9Ma、441.4±1.6Ma、455.4±5.3Ma、424±1.9Ma,岩浆活动于晚奥陶-早志留世,喷出和侵入时代接近,原定巴音布鲁克组地层时代晚志留世应改为晚奥陶-早志留世。这些岩浆岩具有相似的稀土元素地球化学特征,微量元素相比原始地幔均亏损Nb、Ta、P、Ti。玄武岩正的ε(t)=+1.6~+6.7,低的(~(87)~Sr/~(86)NdSr)i=0.70377~0.70489,指示岩浆源区具有亏损地幔特征,弱的Zr-Hf负异常,低的Th/Nb比值,较窄的同位素变化范围暗示地壳混染并不显著,微量元素及铅同位素特征(~(206)Pb/~(204)Pb=18.26~18.77,~(207)Pb/~(204)Pb=15.63~15.69,~(208)Pb/~(204)Pb=38.21~38.34)表明岩浆源区可能是俯冲流体及洋底沉积物交代的地幔楔橄榄岩部分熔融成因。西天山巴音布鲁克地区早古生代岩浆岩应是南天山洋晚奥陶-早志留世向北向中天山陆块之下俯冲在中天山-伊犁板块南缘活动大陆边缘的岩浆产物,指示了陆缘岩浆弧环境。这种陆缘弧环境有利于斑岩铜金成矿系统发育,值得高度关注相关铜金矿的地质找矿。     

北京飞云瀑景点崩塌地质灾害分析及防治方法研究

近15年来,北京飞云瀑景点附近发生过2次大规模崩塌,崩塌堆积岩块体积累计达450 m3,崩塌岩块已滚落覆盖至景区小路。经勘查,确定了1处危岩体及1处危岩带,该危岩体及危岩带对本景点的正常观赏及过往游人构成极大威胁。本文对该景点的崩塌地质灾害地质特征进行了简要介绍;对地质灾害成因、自然发展趋势等进行了初步探讨;对危岩体(带)的稳定性进行了计算、分析及评价;对可能采用的治理方法进行了比选分析。为了最大程度地保护景观资源,最终选择了以避让为主的治理措施,并对选定的治理方案及计算进行了阐述。     

基岩水井压裂增水机理分析

基岩地层压裂增水与岩层性质密切相关,不同岩性其力学性质及其裂隙构造不同,压裂机理与工艺方法就不同。根据基岩地下水岩层特点,结合水力压裂增水试验,着重分析了水力压裂的形成机制,探寻了不同岩层及其力学性质与压裂的关系。     

辐射井技术在尾矿库降排水工程中的应用

尾矿库是我国重大危险源之一,而尾矿库内的浸润线又是坝体安全的重要指标之一,为有效排出尾矿中的水,降低尾矿库内浸润线,本文通过辐射井技术在尾矿库降排水工程中应用的多个成功工程实例,归纳、总结并提出该技术在尾矿库应用过程中的设计思路、施工要点及工艺方法等。     

Research of in-situ hydraulic test method by using double packer equipment

Double packer equipment for hydraulic test can be used to measure pressure of test zone directly, and it is frequently used to perform many kinds of hydraulic tests and take groundwater sample from borehole. The test method of this equipment mainly includes the test design, implementation, interpretation and synthetic analysis. By adopting the double packer equipment for hydraulic test, the parameter distribution of rock permeability along borehole can be acquired, as well as the connectivity, water conductivity and water bearing capacity of the disclosed structure and the chemical characteristics of the deep groundwater. It is a necessary method for the research and evaluation of the complex hypotonicity terrace site selection under geological conditions. This method is not only suitable for the geological disposal of high level radioactive waste, but also can be used in the site selection of underground facilities such as storage of petroleum and carbon dioxide. Meanwhile, it has a good application prospect in other hydrogeological investigation fields.     

Diagenesis and origin of calcite cement in the Flemish Pass Basin sandstone reservoir (Upper Jurassic): Implications for porosity development

The Flemish Pass Basin is a deep-water basin located offshore on the continental passive margin of the Grand Banks, eastern Newfoundland, which is currently a hydrocarbon exploration target. The current study investigates the petrographic characteristics and origin of carbonate cements in the Ti-3 Member, a primary clastic reservoir interval of the Bodhrán Formation (Upper Jurassic) in the Flemish Pass Basin.The Ti-3 sandstones with average Q_86.0F_3.1R_10.9 contain various diagenetic minerals, including calcite, pyrite, quartz overgrowth, dolomite and siderite. Based on the volume of calcite cement, the investigated sandstones can be classified into (1) calcite-cemented intervals (>20% calcite), and (2) poorly calcite-cemented intervals (porous). Petrographic analysis shows that the dominant cement is intergranular poikilotopic (300–500 μm) calcite, which stared to form extensively at early diagenesis. The precipitation of calcite occured after feldspar leaching and was followed by corrosion of quartz grains. Intergranular calcite cement hosts all-liquid inclusions mainly in the crystal core, but rare primary two-phase (liquid and vapor) fluid inclusions in the rims ((with mean homogenization temperature (T_h) of 70.2 ± 4.9 °C and salinity estimates of 8.8 ± 1.2 eq. wt.% NaCl). The mean δ¹⁸O and δ¹³C isotopic compositions of the intergranular calcite are −8.3 ± 1.2‰, VPDB and −3.0 ± 1.3‰, VPDB, respectively; whereas, fracture-filling calcite has more depleted δ¹⁸O but similar δ¹³C values. The shale normalized rare earth element (REE_SN) patterns of calcite are generally parallel and exhibit slightly negative Ce anomalies and positive Eu anomalies. Fluid-inclusion gas ratios (CO₂/CH₄ and N₂/Ar) of calcite cement further confirms that diagenetic fluids originated from modified seawater. Combined evidence from petrographic, microthermometric and geochemical analyses suggest that (1) the intergranular calcite cement precipitated from diagenetic fluids of mixed marine and meteoric (riverine) waters in suboxic conditions; (2)the cement was sourced from the oxidation of organic matters and the dissolution of biogenic marine carbonates within sandstone beds or adjacent silty mudstones; and (3) the late phases of the intergranular and fracture-filling calcite cements were deposited from hot circulated basinal fluids.Calcite cementation acts as a main controlling factor on the reservoir quality in the Flemish Pass reservoir sandstones. Over 75% of initial porosity was lost due to the early calcite cementation. The development of secondary porosity (mostly enlarged, moldic pores) and throats by later calcite dissolution due to maturation of organic matters (e.g., hydrocarbon and coals), was the key process in improving the reservoir quality.     

The diagenetic history of Oligocene-Miocene sandstones of the Austrian north Alpine foreland basin

Diagenesis is an essential tool to reconstruct the development of reservoir rocks. Diagenetic processes - precipitation and dissolution - have an influence on pore space. The present paper aims to study the diagenetic history of deep-marine sandstones of the Austrian Alpine Foreland Basin. To reach that goal, sediment petrology and diagenetic features of more than 110 sandstone samples from water- and gas-bearing sections from gas fields within the Oligocene-Miocene Puchkirchen Group and Hall Formation has been investigated. Special emphasis was put on samples in the vicinity of the gas-water contact (GWC). The sediment petrography of sandstones of Puchkirchen Group and Hall Formation is similar; hence their diagenesis proceeded the same way. In fact, primary mineralogy was controlled by paleo-geography with increasing transport distance and diverse detrital input.Sediment petrographically, investigated sandstones from the water-bearing horizon seemed quite comparable to the gas-bearing sediments. In general, they can be classified as feldspatic litharenites to litharenites and display porosities of up to 30% and permeabilities of up to 1300 mD. The carbon and oxygen isotopic composition of bulk carbonate cements from these sandstones range from−3.8 to +2.2 and from −7.5 to +0.2‰ [VPDB]. However, near the Gas-Water Contact (GWC) a horizon with low porosities (<3%) and permeabilities (<0.1 mD) is present. This zone is completely cemented with calcite, which has a blocky/homogenous morphology. A slight, but significant negative shift in δ18O isotopy (−2.5‰) is evident.During early diagenesis the first carbonate generations formed. First a fibrous calcite and afterwards a micritic calcite precipitated. Further siliciclastic minerals, such as quartz and feldspar (K-feldspar and minor plagioclase), exhibit corroded grains. Occasionally, clay minerals (illite; smectite, chlorite) formed as rims around detrital grains. Late diagenesis is indicated by the formation of a low permeable zone at the GWC.     

Geochemical characteristics of the Paleogene shales in the Dongying depression,eastern China

Fluctuations in lacustrine sedimentary environments significantly affect distributions of organic matter (OM), uranium, and other elements in shales. In this study a high-resolution geochemical record of fluctuations in the paleo-depositional environment of a terrestrial lake basin is provided on the basis of extensive samples collected from the Member 3 of the Paleogene Shahejie Formation (Es₃) of the Niu-38 well in the Dongying Depression, Eastern China. These samples were tested for total organic carbon (TOC), element concentrations, and biomarkers to study the evolution and fluctuation in the depositional environments of an ancient lake basin and associated geochemical response. The evolution and fluctuation of the sedimentary environment from a deep lake to a semi-deep lake and then to a shallow lake delta were indicated by geochemical response. During this evolution, the values of TOC, S₁, S₂, Sr, and Ts/(Ts + Tm) remarkably decreased, whereas those of Co, Ni, Rb, Na, Fe/Mn, Fe/(Ca + Mg), and C₂₉ mortane/C₂₉ hopane significantly increased. The deep lake basin shows depositional fluctuations, as indicated by rock lithofacies and their geochemical parameters. A close interrelationship was observed among U concentration, TOC content, and inorganic element content. Uranium concentrations are positively correlated with TOC contents, Ca and Sr concentrations, and Sr/Ba and Ca/Mg ratios but negatively with K, Na, Ba, and Rb contents and Fe/(Ca + Mg) and Fe/Mn ratios. The observed increase in U concentration in the lower Es₃ section is closely related to surface adsorption by clay minerals and OM, together with some replacements of Ca and Sr by U in the shales.