柴里煤矿二水平岩巷的工程地质问题探讨

论证了柴里矿区现代地应力场为大地静力场型，指出地应力研究的工程意义，通过层位，实践，经济效益几方面的对比，指出三灰是二水平主干岩层位选择的最佳层位。     

裂隙、离层及冒落带的声波成像识别方法

煤层采空形成的冒落带，裂隙带和沉降变形情况的查明对灾害防治及土地利用是非常重要的，在勘察钻孔中进行声波扫描成像测井能提供清晰直观的图像资料，给工程地质的评价分析提供了可靠的依据。     

Boron and Oxygen Isotope Composition of Certified Reference Materials NIST SRM 610/612 and Reference Materials JB-2 and JR-2

We present data on the concentration, the isotope composition and the homogeneity of boron in NIST silicate glass reference materials SRM 610 and SRM 612, and in powders and glasses of geological reference materials JB-2 (basalt) and JR-2 (rhyolite). Our data are intended to serve as references for both microanalytical and wet-chemical techniques. The δ¹¹ B compositions determined by N-TIMS and P-TIMS agree within 0.5% and compare with SIMS data within 2.5%. SIMS profiles demonstrate boron isotope homogeneity to better than δ¹¹ B = 2% for both NIST glasses, however a slight boron depletion was detected towards the outermost 200 μm of the rim of each sample wafer. The boron isotope compositions of SRM 610 and SRM 612 were indistinguishable. Glasses produced in this study by fusing JB-2 and JR-2 powder also showed good boron isotope homogeneity, both within and between different glass fragments. Their major element abundance as well as boron isotope compositions and concentrations were identical to those of the starting composition. Hence, reference materials (glasses) for the in situ measurement of boron isotopes can be produced from already well-studied volcanic samples without significant isotope fractionation. Oxygen isotope ratios, both within and between wafers, of NIST reference glasses SRM 610 and SRM 612 are uniform. In contrast to boron, significant differences in oxygen isotope compositions were found between the two glasses, which may be due to the different amounts of trace element oxides added at ten-fold different concentration levels to the silicate matrix.     

Recognition of the hydrogeological potential using electrical sounding in the Khemisset-Tiflet region,Morocco

The low recharge of reservoirs and the increasing demand for water limit the potential of mobilized resources, especially in arid to semi-arid areas like Morocco. Integrated management is essential to safeguard this resource. In respect with this perspective, this work provides the analysis of hydrogeological potential of Khemisset-Tiflet region, which falls within the action area of the Sebou Hydraulic Basin Agency. The basis of our studies was as follows:(1) The interpretation of the existing geoelectric data;(2) application of geophysical methods for non-destructive reconnaissance and their integration into a Geographic Information System(GIS). The analysis demonstrates that: The map of the isohypses and the geoelectric cross-section of the substratum of the superficial roof aquifer show clearly a plunge associated with development of the Paleozoic roof in the South and the direction of flow of the surface water is from south to north, from the upper zone to the north of the El Kansera dam. These conclusions constitute very useful contribution for any resource management projects in this area.     

Static compression of α-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>: linear incompressibility of lattice parameters and high-pressure transformations

The high-pressure behavior of -Fe₂O₃ has been studied under static compression up to 60 GPa, using a laser-heated diamond anvil cell. Synchrotron-based angular-dispersive X-ray diffraction shows that the sample remains in the corundum structure up to 50 GPa, but with the appearance of coexisting diffraction lines from a high-pressure phase at pressures above 45 GPa. A least-squares fit of low-pressure phase data to an Eulerian finite-strain equation of state yields linear incompressibilities of K _{a 0}=749.5 (± 18.4) GPa and K _{c 0}= 455.7 (± 21.4) GPa, differing by a factor of 1.6 along the two directions. The enhanced compressibility of the c axis may lead to breaking of vertex- or edge-sharing bonds between octahedra, inducing the high-pressure phase transformation at 50 GPa. Analysis of linear compressibilities suggests that the high-pressure phase above 50 GPa is of the Rh₂O₃ (II) structure. Continuous laser heating reveals a new structural phase transformation of -Fe₂O₃ at 22 GPa, to an orthorhombic structure with a=7.305(3) Å, b=7.850(3) Å, and c=12.877(14) Å, different from the Rh₂O₃ (II) structure.     

Caractérisation minéralogique et microtexturale du vieillissement anthropique du minerai de fer lorrainMineralogical and microtextural characterisation of the anthropic-origin ageing of iron ore in Lorraine (France)

The abandoned pillars in iron mines in Lorraine show that the oolitic ore underwent several chemical-mineralogical transformations. The first one is a rapid alteration of the diagenetic siderite and berthierine cement promoted by a bacterial flora. The oolites of goethite pack down and get loaded by deviatory-type stresses; they desquamate, get deformed and become powdery; the ore looses its cohesion. A second step, featuring recrystallisation–neoformation of berthierine in the previously formed micro-cavities, then the formation of a cavernous goethite–hematite crust, leads to a low cohesion to the crumbled ore; this anthropic-origin ageing may be one cause of mine collapsing. To cite this article: G. Dagallier et al., C. R. Geoscience 334 (2002) 455–462.     

Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

共轭伸展褶劈理夹角的定量解析

９０ 年代初以来,中国地质学者先后在浙、皖、赣、湘的“板溪群”及震旦系中发现了古生代的生物化石。因此,再次将“板溪群”是否是前震旦纪的一个变质地层单位、江南古陆是否存在以及华南大地构造格局是否需要重新厘定等问题提了出来。１９９３ 年笔者于赣东北蛇绿混杂岩带内的“双桥山群”岩块中,首次发现了含晚古生代的放射虫硅质岩。１９９６ 年又在该混杂岩带多处的“双桥山群”岩块和“下震旦统志棠组”中找到了含晚古生代的放射虫硅质岩,还首次在“登山群拔竹坑组”中发现了早古生代的几丁虫化石。经数年野外多次观察和对室内化石鉴定、岩石地球化学测试结果以及岩石学特征的综合分析表明,所发现的含晚古生代放射虫硅质岩及其岩石组合是一套洋盆深水相沉积;登山群拔竹坑组,是早古生代的一套浅水陆棚 深水陆棚 半深海相沉积。结合同行学者在邻区“板溪群”研究方面取得的新成果,笔者认为：“板溪群”不是前震旦纪的一个变质地层单位,而是一个复杂的构造岩带,江南古陆是不存在的,华南从早古生代到中生代早期还经历了一次洋盆演化过程,现在的构造格局是印支运动奠定的     

Usable Values of Nickel Ore and Nickel Concentrate Certified Reference Materials

The preparation and characterisation of three nickel ores and two nickel concentrate certified reference materials are described in this paper. The samples of nickel ore and nickel concentrate were collected from the Hongqiling nickel deposit in Jilin province. The raw materials were crushed and passed through a 2.0‐mm sieve. The rough samples were then ground for 48 hr in a high‐alumina ball mill to a final size of < 0.074 mm. Homogeneity of the samples was tested by X‐ray fluorescence spectrometry (WD‐XRF) and inductively coupled plasma‐atomic emission spectrometry (ICP‐AES). The relative standard deviations (RSD) of results on mass fraction measurements by WD‐XRF were < 1.0% m/m for eighteen components. F‐tests showed that all five samples were homogeneous. Nineteen laboratories contributed with measurement results (2127 in total) for the certification of mass fractions for twenty‐three elements and compounds. Twenty‐three components in the nickel ores and twenty components in the nickel concentrates were characterised as certified values, while the Ni mass fractions ranges from 0.1 to 9.02% m/m in these certified reference materials. These five samples were approved as national certified reference materials by the National Organisation of Reference Materials of China in 2012.