Preparation and Certification of Biogeochemical Reference Materials

The Institute of Geophysical and Geochemical Exploration in China recently prepared ten biogeochemical certified reference samples GSB1‐10 (CRMs). The samples are primary agricultural products such as rice, wheat, corn, soybean, cabbage, spinach, tea, powder, chicken and apple. Lyophilisation technology and a high‐alumina ball mill were used to process the samples. Fourteen laboratories and hundreds analysts in China participated in the certification analysis. Over ten reliable analytical methods, predominately ICP‐MS, ICP‐AES and INAA, were used for analysing the samples for fifty‐nine elements. A total of 22477 determinations led to 5136 average data sets. Certified values of fifty‐four elements were assigned.     

Role of Lithology and Subsurface structures detected by potential field data in controlling the radioactive mineral accumulation at Natash area,Eastern Desert,Egypt

Wadi Natash area is located in the southern part of the Eastern desert of Egypt. It has a great importance for containing accumulations from the radioactive minerals of Uranium, Thorium and Potassium. An integrated potential study was carried out on the study area with the aim of locating depths to causative bodies with sufficient magnetic susceptibility that may represent magmatic intrusions with relation to the radioactivity location and delineate the subsurface structures affecting the area. Both magnetic and Bouguer data as well as radiometric data were interpreted rapidly for source positions and depths using Euler deconvolution, Werner deconvolution and 3D modeling techniques. The results deduced from the trend analyses show that the major fault trend affecting the area have NNW-SSE (Red Sea–Gulf of Suez trend) direction intersected by the less predominant NNE-SSW(The Gulf of Aqaba–Dead Sea trend) and WNW-ESE (Najd Fault System) fault trends. The causative bodies were imaged at depths ranging from 0.3 km to about 1.5 km. The depths along the interpreted profiles display discontinuities in potential field markers due to presence of the NNW-SSE fault trends act as pass channels for the hydrothermal solutions.It can be stated that the radioactive mineral accumulations were caused by the hydrothermal solutions rich with radioactive minerals as a result of intruding Natash volcanic to the granitic rocks. The Qouseir clastics and the Nudian sand stone were affected by these solutions and show a positive response for the radioactive minerals.     

汶川M_S8.0地震绵竹县汉旺镇周边地表破裂带展布方式及其震害意义

2008年5月12日汶川MS8.0地震的震中烈度为Ⅺ度,但位于地震烈度为Ⅹ度区边缘的绵竹县汉旺镇,无论是房屋毁坏情况还是遇难和失踪人员的数目,均高出周边地震烈度Ⅰ度,接近极震区的破坏程度。文中从汉旺镇周边地表地震破裂带展布方式的角度讨论了这种震害加重现象的原因,介绍了位于汉旺镇北面和南面出现的2条相距1.5km呈左阶斜列展布的地表破裂带。其中,位于汉旺镇北侧的地表破裂带,垂直位移1.4m,水平右旋位移0.44m;位于汉旺镇南侧的地表破裂带,垂直位移量由西向东递减,为3.0～0.2m。尽管这2条地表破裂带没有从汉旺镇中心通过,但汉旺镇正位于这2条地表破裂带夹持的左阶阶区,致使阶区内建筑物除遭受来自震源的振动外,又受到阶区内的挤压,由此加重了汉旺镇建筑物的破坏,也显示出地表破裂带对建筑物破坏形式的多样性。汉旺镇汶川MS8.0地震震害实例表明,地表破裂带的阶区,也是遭受地震时破坏加重的特殊构造部位     

An experimental study on variation of b value during deformation of rock samples with different structural models

Introduction Analyses of the b value in the frequency-magnitude relation (Gutenberg & Richter curve, G-R curve), lgN=a?bM, is one of important methods for earthquake prediction. It is often used to study the state of tectonic deformation and regional stress field. Many studies on the b value have been made in aspects of seismicity, experimental modeling (acoustic emission) and theory (Mogi, 1962; Scholz, 1968; LI et al, 1978; MA, 1978; CHEN, 1977; GENG, 1986; DU and MA, 1986; CAI et…     

Origine des eaux des émergences karstiques chlorurées du Languedoc-Roussillon

The origin of chloride-rich karstic spring waters representative of the Languedoc-Roussillon region has been investigated with a hydrochemical approach. To this end, the major and trace elements most often used in the study of saline environments have been considered (Cl, SO₄, Br, B, Li). This study allowed distinguishing the different end-members of the various chloride-rich karstic spring waters (evaporitic, marine, geothermal). Associated with the Cl, Br and B contents, the Li/SO₄ ratio appeared as a relevant tracer for the determination of the origin of lithium and by extension of the considered waters. To cite this article: O. Hébrard et al., C. R. Geoscience 338 (2006).     

Cartographie du potentiel en eau souterraine du bassin versant de la Lobo (Centre-Ouest,Côte d’Ivoire) : approche par analyse multicritère

RÉSUMÉ

Ce travail aborde le problème d’accessibilité en eau potable dans les zones fissurées de la Côte d’Ivoire notamment en saison sèche. Sur le bassin versant de la Lobo, le problème se pose avec plus d’acuité puisque les retenues aménagées pour l’alimentation en eau des populations ne sont pas correctement alimentées ces dernières années et sujettes à une très forte eutrophisation. L’approche pluridisciplinaire (télédétection, analyse multicritère et système d’information hydrogéologique à référence spatiale) a été adoptée. La cartographie des sites potentiels en eau montre que la quasi-totalité du bassin de la Lobo possède une bonne et excellente disponibilité en eau souterraine (93% de la superficie totale). Cette bonne disponibilité en eau souterraine est due à une faible pente et à une bonne densité de fracturation qui entrainent une bonne infiltration des eaux dans l’aquifère. L’identification des sites potentiels montre que près de 72% de la superficie du bassin est favorable à l’implantation d’ouvrages à gros débits. Dans l’ensemble, ces aquifères présentent une bonne accessibilité avec cependant, une exploitabilité médiocre.

Editeur Z. W. Kundzewicz; Edithur Associé M.D. Fidelibus     

A Method for Rapid Determination of Re and Os Isotope Compositions Using ID‐MC‐ICP‐MS Combined with the Sparging Method

A simple, rapid method for the determination of Re and Os concentrations and isotope compositions using isotope dilution multi‐collector inductively coupled plasma‐mass spectrometry (ID‐MC‐ICP‐MS) combined with Carius tube digestion and sparging introduction of Os was developed. For Os measurement, four channeltron ion counters to detect different Os isotopes were used simultaneously, which led to a drastic reduction in the measurement time. Rhenium isotopes were measured by means of eight Faraday cups with solution nebulisation and an ultrasonic membrane desolvator. The representative ¹⁸⁸Os count rate of an Os standard solution containing 50 pg of total Os was approximately 110000–120000 cps at the onset of measurement; the Re intensity of our in‐house 10 pg g^?1 standard solution reached 1820 V/μg g^?1 with a sample uptake rate of 95–99 μl min^?1. These values indicate that the sensitivity of the method was sufficient even for samples with low Re and Os concentrations, such as chert. As the temporal variations of the amplification efficiency of the ion counters differed from one another, we adopted a sample‐calibrator bracketing method to correct the measured Re and Os isotope ratios. The Re and Os concentrations via the isotope dilution method and the ¹⁸⁷Os/¹⁸⁸Os ratios of two sedimentary rock reference materials (JMS‐2 and JCh‐1) on the basis of the isotope ratios determined by the MC‐ICP‐MS and by negative thermal ionisation mass spectrometry (N‐TIMS) were comparable within their ranges. Based on Os isotope measurement of the IAG reference material [Durham Romil Os (DROsS)], the average difference from the recommended value and precision of Os isotope measurements by the sparging method in combination with multi‐ion‐counters were 0.72% and 0.76% [1RSD (%), n = 29], respectively. The precisions in the ¹⁸⁷Os/¹⁸⁸Os ratios [1RSD (%)] of JMS‐2, JCh‐1 and DROsS were 0.35–0.71, 1.56–3.31 and 0.99–1.28%, respectively, which depended on their Os ion intensities. No systematic difference was observed between the Re and Os geochemical compositions of JCh‐1 and JMS‐2 obtained by means of digestion with inverse aqua regia and CrO₃‐H₂SO₄ solutions, suggesting that either acid solution can be used for the sparging method of sedimentary rock samples. As CrO₃‐H₂SO₄ solution is believed to liberate predominantly the hydrogenous Re and Os fraction from organic‐rich sediment, the sparging method combined with CrO₃‐H₂SO₄ digestion and multi‐ion‐counters in the mass spectrometry is expected to be a powerful tool for reconstructing the secular change in marine Os isotope compositions with high sample throughput.     

Production and Certification of a Unique Set of Isotope and Delta Reference Materials for Boron Isotope Determination in Geochemical,Environmental and Industrial Materials

Isotopic reference materials are essential to enable reliable and comparable isotope data. In the case of boron only a very limited number of such materials is available, thus preventing adequate quality control of measurement results and validation of analytical procedures. To address this situation a unique set of two boron isotope reference materials (ERM‐AE102a and ‐AE104a) and three offset δ¹¹B reference materials (ERM‐AE120, ‐AE121 and ‐AE122) were produced and certified. The present article describes the production and certification procedure in detail. The isotopic composition of all the materials was adjusted by mixing boron parent solutions enriched in ¹⁰B or ¹¹B with a boron parent solution having a natural isotopic composition under full gravimetric control. All parent solutions were analysed for their boron concentration as well as their boron isotopic composition by thermal ionisation mass spectrometry (TIMS) using isotope dilution as the calibration technique. For all five reference materials the isotopic composition obtained on the basis of the gravimetric data agreed very well with the isotopic composition obtained from different TIMS techniques. Stability and homogeneity studies that were performed showed no significant influence on the isotopic composition or on the related uncertainties. The three reference materials ERM‐AE120, ERM‐AE121 and ERM‐AE122 are the first reference materials with natural δ¹¹B values not equal to 0‰. The certified δ¹¹B values are ?20.2‰ for ERM‐AE120, 19.9‰ for ERM‐AE121 and 39.7‰ for ERM‐AE122, each with an expanded uncertainty (k = 2) of 0.6‰. These materials were produced to cover about three‐quarters of the known natural boron isotope variation. The ¹⁰B enriched isotope reference materials ERM‐AE102a and ERM‐AE104a were produced for industrial applications utilising ¹⁰B for neutron shielding purposes. The certified ¹⁰B isotope abundances are 0.29995 for ERM‐AE102a and 0.31488 for ERM‐AE104a with expanded uncertainties (k = 2) of 0.00027 and 0.00028, respectively. Together with the formerly certified ERM‐AE101 and ERM‐AE103 a unique set of four isotope reference materials and three offset δ¹¹B reference materials for boron isotope determination are now available from European Reference Materials.     

Spatial Geochemistry: A Characterisation of Heterogeneity in Reference Materials

Geochemical reference materials (RMs) for microbeam techniques are typically characterised by averages and dispersion statistics (e.g., standard deviation, variance) that are calculated for a number of measurements (beam shots). It is proposed that the mapping of RMs will add spatial information that better characterises the grouping and magnitudes of the heterogeneities and provides the information necessary to define a minimum analytical mass. A simple mathematical solution is proposed, which can be easily computed and understood. The analogous notions to sill and range from geostatistics are applied to the minimum analytical mass versus the relative standard deviation. To assess grouping and magnitudes of the heterogeneities, a ‘proximity number’ is computed for each average value ± ‘n’ standard deviations (magnitude). Different chemical anomalies have been simulated to demonstrate the behaviour of the proximity number. To further test the proposed spatial geochemistry concept, sulfide‐ and oxide‐bearing RMs have been selected because many are crippled with nugget effect. They have been mapped with a micro‐XRF apparatus, and results are presented for CHR‐Bkg, CHR‐Pt+, MASS‐1, MASS‐3, WMS‐1 and WMS‐1a. MASS‐1 and MASS‐3 are the most suitable RMs for microbeam techniques. Spatial geochemistry offers a new approach to better characterise reference materials.     

Preparation and Characterisation of Two Geochemical Reference Materials: DG‐H (Granite) and AM‐H (Amphibolite) from the Himalayan Orogenic Belt

Two geochemical reference materials of Himalayan origin named DG‐H (a granite) and AM‐H (an amphibolite) prepared by the Wadia Institute of Himalayan Geology Dehradun are described. Both samples were collected from the NW Himachal Himalaya in India. With the participation of analysts from more than forty international laboratories, element determination data collected during the past 10 years for characterisation of the samples was processed to assign working values using statistical procedures in use for this purpose. Earlier work published on these samples is incorporated in the present communication making it an updated document. The typical chemical and petrological characteristics of these two samples may prove useful for method validation and calibration of analytical instruments used for analysing similar rock types, and for widening the analytical range of several analytical methods used for geochemical analysis.