An Air‐Cooled,High‐Yield,Compact and Inexpensive Teflon Still for High‐Purity Reagents

Mattinson’s (1972) well‐known simple design of a sub‐boiling still for the preparation of ultra high‐purity reagents consists of two Teflon bottles connected at right angles with one acting as the feed bottle and heated on its upper surface by infrared radiation and the other kept in a cold water bath serving both as the condenser and receiver. Connection of the two bottles in a vertical configuration and replacement of radiative surface heating with conductive bulk heating result in an equally simple and inexpensive still but with a smaller footprint, much larger yield and higher energy efficiency using only ambient air cooling. It can be easily configured for tandem distillation, supply of continuously purified reagent and fractional distillation. Ease and very low cost of fabrication of this still may be of particular interest to many geochemical laboratories requiring up to 500 ml of mineral acids and other common reagents per day.     

Non‐Matrix‐Matched Calibration for the Multi‐Element Analysis of Geological and Environmental Samples Using 200 nm Femtosecond LA‐ICP‐MS: A Comparison with Nanosecond Lasers

LA‐ICP‐MS is one of the most promising techniques for in situ analysis of geological and environmental samples. However, there are some limitations with respect to measurement accuracy, in particular for volatile and siderophile/chalcophile elements, when using non‐matrix‐matched calibration. We therefore investigated matrix‐related effects with a new 200 nm femtosecond (fs) laser ablation system (NWRFemto200) using reference materials with different matrices and spot sizes from 10 to 55 μm. We also performed similar experiments with two nanosecond (ns) lasers, a 193 nm excimer (ESI NWR 193) and a 213 nm Nd:YAG (NWR UP‐213) laser. The ion intensity of the 200 nm fs laser ablation was much lower than that of the 213 nm Nd:YAG laser, because the ablation rate was a factor of about 30 lower. Our experiments did not show significant matrix dependency with the 200 nm fs laser. Therefore, a non‐matrix‐matched calibration for the multi‐element analysis of quite different matrices could be performed. This is demonstrated with analytical results from twenty‐two international synthetic silicate glass, geological glass, mineral, phosphate and carbonate reference materials. Calibration was performed with the certified NIST SRM 610 glass, exclusively. Within overall analytical uncertainties, the 200 nm fs LA‐ICP‐MS data agreed with available reference values.     

Forty‐Nine Major and Trace Element Concentrations Measured in Soil Reference Materials NIST SRM 2586, 2587, 2709a, 2710a and 2711a Using ICP‐MS and Wavelength Dispersive‐XRF

Excellent agreement was noted in the concentration of major and trace elements in five NIST (National Institute for Science and Technology) soil reference materials (NIST SRM 2586, 2587, 2709a, 2710a and 2711a) between measurement results from wavelength dispersive‐XRF and ICP‐MS from two independent laboratories, and NIST certificate of analysis and literature data. We describe the variability in concentrations of up to forty‐nine elements (plus loss on ignition) and provide values for up to twenty‐one elements previously uncharacterised by NIST in these soil RMs. The additional characterisation provided in this investigation can be utilised to reduce the measurement bias of custom calibration routines and improve the quality of control checks developed using these NIST RMs.     

Proposal for an International Molybdenum Isotope Measurement Standard and Data Representation

Molybdenum isotopes are increasingly widely applied in Earth Sciences. They are primarily used to investigate the oxygenation of Earth's ocean and atmosphere. However, more and more fields of application are being developed, such as magmatic and hydrothermal processes, planetary sciences or the tracking of environmental pollution. Here, we present a proposal for a unifying presentation of Mo isotope ratios in the studies of mass‐dependent isotope fractionation. We suggest that the δ^98/95Mo of the NIST SRM 3134 be defined as +0.25‰. The rationale is that the vast majority of published data are presented relative to reference materials that are similar, but not identical, and that are all slightly lighter than NIST SRM 3134. Our proposed data presentation allows a direct first‐order comparison of almost all old data with future work while referring to an international measurement standard. In particular, canonical δ^98/95Mo values such as +2.3‰ for seawater and ?0.7‰ for marine Fe–Mn precipitates can be kept for discussion. As recent publications show that the ocean molybdenum isotope signature is homogeneous, the IAPSO ocean water standard or any other open ocean water sample is suggested as a secondary measurement standard, with a defined δ^98/95Mo value of +2.34 ± 0.10‰ (2s).     

Mercury,Trace Elements and Organic Constituents in Atmospheric Fine Particulate Matter,Shenandoah National Park,Virginia, USA: A Combined Approach to Sampling and Analysis

Compliance with U.S. air quality regulatory standards for atmospheric fine particulate matter (PM_2.5) is based on meeting average 24 hour (35 μ m^?3) and yearly (15 μg m^?3) mass‐per‐unit‐volume limits, regardless of PM_2.5 composition. Whereas this presents a workable regulatory framework, information on particle composition is needed to assess the fate and transport of PM_2.5 and determine potential environmental/human health impacts. To address these important non‐regulatory issues an integrated approach is generally used that includes (1) field sampling of atmospheric particulate matter on filter media, using a size‐limiting cyclone, or with no particle‐size limitation; and (2) chemical extraction of exposed filters and analysis of separate particulate‐bound fractions for total mercury, trace elements and organic constituents, utilising different USGS laboratories optimised for quantitative analysis of these substances. This combination of sampling and analysis allowed for a more detailed interpretation of PM_2.5 sources and potential effects, compared to measurements of PM_2.5 abundance alone. Results obtained using this combined approach are presented for a 2006 air sampling campaign in Shenandoah National Park (Virginia, USA) to assess sources of atmospheric contaminants and their potential impact on air quality in the Park. PM_2.5 was collected at two sampling sites (Big Meadows and Pinnacles) separated by 13.6 km. At both sites, element concentrations in PM₂₅ were low, consistent with remote or rural locations. However, element/Zr crustal abundance enrichment factors greater than 10, indicating anthropogenic input, were found for Hg, Se, S, Sb, Cd, Pb, Mo, Zn and Cu, listed in decreasing order of enrichment. Principal component analysis showed that four element associations accounted for 84% of the PM_2.5 trace element variation; these associations are interpreted to represent: (1) crustal sources (Al, REE); (2) coal combustion (Se, Sb), (3) metal production and/or mobile sources (Mo, Cd, Pb, Cu, Zn) and (4) a transient marine source (Sr, Mg). Concentrations of Hg in PM_2.5 at background levels in the single pg m^?3 were shown by collection and analysis of PM_2.5 on filters and by an automated speciation analyser set up at the Big Meadows air quality site. The speciation unit revealed periodic elevation of reactive gaseous mercury (RGM) that co‐occurred with peaks in SO₂, indicating an anthropogenic source. GC/MS total ion current chromatograms for the two sites were quite similar indicating that organic signatures were regional in extent and/or that the same compounds were present locally at each site. Calculated carbon preference index values for n‐alkanes indicated that plant waxes rather than anthropogenic sources, were the dominant alkane source. Polycyclic aromatic hydrocarbons (PAHs) were detected, with a predominance of non‐alkylated, and higher molecular weight PAHs in this fraction, suggestive of a combustion source (fossil fuel or forest fires).     

Developments at ISO/REMCO and its Impact on the Production and Use of Geological Reference Materials

During the past decade the work of ISO/REMCO, the International Organization for Standardization’s Technical Committee on Reference Materials, was dedicated to achieving global harmonisation, and true involvement of the member countries. The first major accomplishment was the clarification of the terminology in the definitions for reference material and certified reference material, which were published as an amendment to ISO Guide 30 in 2008. The next milestone was the recognition that ISO Guide 34 (‘General requirements for the competence of reference material producers’) be used in conjunction with ISO/IEC 17025 for the accreditation of reference material producers. The third edition of ISO Guide 34 published in November 2009, clarifies the acceptable procedures for the certification of reference materials. This paper will discuss the role of ISO/REMCO in formalising the procedures for the accreditation of reference material producers and the evolution of the terms reference material and certified reference material. The paper will conclude with a case study, where a primary method in a single laboratory – one of the recognised acceptable metrologically valid procedures according to ISO Guide 34 – was used for the certification of reference materials. The reference materials are South African Reference Material SARM 2 (Syenite), SARM 3 (Lujavrite) and SARM 4 (Norite) from the suite of six NIMROCs that were originally certified by the Council for Mineral Technology (MINTEK) in South Africa in the 1970s.     

雁列断层变形过程中的声发射特征

对拉张型、挤压型雁列断层变形过程中岩桥区和主断层上的声发射特征进行了对比研究，结果表明，雁列断层变形中的声发射对应着多种机制：拉张型雁列岩桥区的声发射为单一事件组成，波振幅小、持续时间短、主频高、震源机制为张裂型；挤压型雁列岩桥区的声发射也是单一事件，波振幅较大、持续时间短、主频较低、震源机制为双剪型；而雁列主干断层上的声发射由多事件组成，波振幅大、持续时间长、主频低、震源机制与挤压型雁列岩桥区的声发射机制不同。这些特点与各区域所处力学状态有关     

How Fit Are Your Data?

Most laboratories aim to produce data of the highest quality. Trying to lower uncertainties to infinitesimal figures and push detection limits even lower are valid goals. However, is it possible to overachieve? Are old data still of good enough quality to be usable? In a geochemical context, the main goal of producing analytical results is to answer geological or environmental questions. Not all scientific problems require the same data quality. What is really required are data of adequate quality – i.e., ‘fit-for-purpose’– to ensure that the geological problem at hand can be solved. Furthermore, it is doubtful that uncertainties and reproducibilities associated with field sampling are better than those from laboratories. It is thus proposed that, as geoanalysts, we encourage data users (students, colleagues or referees) to ensure that their analytical results are of sufficient quality to solve the problem. However, authors have to demonstrate, through the use of reproducibility testing, reference and quality control materials, that the quality of their results is sufficient to solve the problem. Uncertainties and detection limits in publications should not only be evaluated with respect to a set value, such as 10%, but also with regard to the geological problem to be solved.     

Structures spatiales de l'évapotranspiration de référence et des variables climatiques corrélées en Tunisie

Résumé

Nous étudions sur le territoire Tunisien, transition entre les climats sub-humide Méditerranéen et aride Saharien, l'organisation spatiale de l'évapotranspiration de référence décadaire interannuelle (1986–2003) et des variables climatiques utilisées pour son estimation: température de l'air, humidité relative de l'air, vitesse du vent et durée d'ensoleillement. L'étude est basée sur la modélisation du variogramme et la détermination de ses paramètres (pépite, pente ou palier et portée). Nous considérons également des indicateurs sur le comportement à l'origine du variogramme et sur la variation de la structure spatiale des variables étudiées. L'étude montre que les modèles des variogrammes changent d'une variable à une autre et d'une période de l'année à une autre. Cependant, ils sont de type linéaire dans la plupart des cas. Le variogramme de l'évapotranspiration de référence est sans pépite, quelle que soit la période de l'année. Pour les autres variables, notamment la température maximale de l'air, l'humidité relative de l'air et la durée d'ensoleillement, la pépite est plus importante pendant la période chaude de l'année. Le variogramme de la vitesse du vent est sphérique à grande portée sur toute l'année, et la structure de l'ensoleillement est pépitique pendant l'été et linéaire le reste de l'année. L'évapotranspiration de référence présente un gradient structural semblable à celui de l'humidité relative durant toute l'année, mais différent de ceux des autres variables climatiques.

Editeur Z.W. Kundzewicz; Editeur associé G. Mahé

Citation Baccour, H., Slimani, M. et Cudennec, C., 2012. Structures spatiales de l'évapotranspiration de référence et des variables climatiques corrélées en Tunisie. Hydrological Sciences Journal, 57 (4), 818–829.     

A synthesis: Late Cenozoic stress field distribution at northeastern corner of the Eastern Mediterranean,SE Turkey

Fault kinematic analysis and inversion of focal mechanisms of shallow earthquakes reveal significant evolution of the regional stress regime in the northeastern most corner of the Eastern Mediterranean region since the Mio-Pliocene to the present time. This study was carried out in the interaction area between the Arabian/African plates and the Anatolian block. The evolution of stress regimes consists of a change from older transpression to younger transtension. Both strike-slip stress regimes having a NNW- to northwest-trending σ_Hmax (σ₁) and ENE- to northeast-trending σ_Hmin (σ₃) axes induce a sinistral component of displacement on the major intra-continental Karatas–Osmaniye and Misis–Ceyhan faults elongated with the northeast-trending Misis Range between Adana and Osmaniye provinces (sub-area i) and by a NNE-trending plate boundary Amanos fault running along Amanos Range between Antakya and Kahramanmaras provinces (sub-area ii). The inversion results show that the transtensional stress regime is dominantly strike-slip to extension, with an ENE- to northeast-trending σ_Hmin (σ₃) axis for sub-areas (i) and (ii), respectively. The inversions of earthquake focal mechanisms indicate that the transtensional stress regime is still active in the whole study area since probably recent Quaternary time. To cite this article: S. Over et al., C. R. Geoscience 336 (2004).