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91.
弯岛湖蛇绿混杂岩带是金沙江缝合带西段的重要组成部分。蛇绿岩混杂于上三叠统变质碎屑岩夹变质火山岩中,成份主要为镁铁质-超镁铁质杂岩,岩石类型有变质橄榄岩、变质堆晶质辉长岩及其伴生的岛弧型花岗岩系。岩石化学及地球化学特征表明:蛇绿岩主要为低Ti(岛弧-弧后)型、富集型洋中脊(E-MORB)拉斑玄武岩;与之共(伴)生的基性喷出岩、辉绿岩脉属板内洋岛型裂谷型碱性玄武岩及其过渡类型系列。在变质辉长岩获得全岩Sm-Nd等时线年龄值为232±11Ma,代表了镁铁质-超镁铁质杂岩的形成年龄,可能为洋壳初始俯冲变质的时间。在蛇绿岩上覆的硅质岩中发现有中三叠世拉丁晚期至晚三叠世卡宁早期的放射虫化石,表明弯岛湖镁铁质-超镁铁质杂岩可能形成于中三叠世多岛洋盆或弧后盆地构造环境。 相似文献
92.
西准噶尔巴尔雷克蛇绿混杂岩带中玄武岩地球化学特征及大地构造意义 总被引:6,自引:0,他引:6
西准噶尔地区巴尔雷克蛇绿混杂岩中的玄武岩与蛇纹岩、放射虫硅质岩和晚泥盆世铁列克提组的泥质粉砂岩与沉凝灰岩形成混杂堆积。对玄武岩进行详细的岩石地球化学研究表明,SiO2含量为42.15%~44.71%,高TiO2(3.17%~3.77%)、Na2O(1.73%~2.28%),低Al2O3(13.54%~14.31%)、K2O(1%~1.82%),MgO含量相对稳定(6.75%~8.14%),Mg#为43~46,属于碱性玄武岩系列。稀土总量∑REE=186×10-6~219.06×10-6,轻、重稀土分馏较为明显((La/Yb)N=11.37~12.62),无明显Eu异常(Eu/Eu*=0.96~1),稀土配分模式类似于OIB。相对富集LILE(如Rb、Ba、Th),亏损HFSE(如Zr、Hf),没有明显的Nb和Ta异常,具有高的Ti/Yb(7395~8724)和Zr/Yb(120~136)比值,为典型的OIB地球化学特征。综合研究认为玄武岩形成于弧后盆地的海山环境,其岩浆源区可能为EMI型富集地幔,即软流圈的上涌导致尖晶石相二辉橄榄岩地幔源区大比例部分熔融形成的玄武岩。在区域上,蛇绿混杂岩中的玄武岩所代表的泥盆纪古洋盆是西准噶尔古洋盆向北收缩的残余洋盆。 相似文献
93.
Developments at ISO/REMCO and its Impact on the Production and Use of Geological Reference Materials
Angelique Botha 《Geostandards and Geoanalytical Research》2010,34(3):237-244
During the past decade the work of ISO/REMCO, the International Organization for Standardization’s Technical Committee on Reference Materials, was dedicated to achieving global harmonisation, and true involvement of the member countries. The first major accomplishment was the clarification of the terminology in the definitions for reference material and certified reference material, which were published as an amendment to ISO Guide 30 in 2008. The next milestone was the recognition that ISO Guide 34 (‘General requirements for the competence of reference material producers’) be used in conjunction with ISO/IEC 17025 for the accreditation of reference material producers. The third edition of ISO Guide 34 published in November 2009, clarifies the acceptable procedures for the certification of reference materials. This paper will discuss the role of ISO/REMCO in formalising the procedures for the accreditation of reference material producers and the evolution of the terms reference material and certified reference material. The paper will conclude with a case study, where a primary method in a single laboratory – one of the recognised acceptable metrologically valid procedures according to ISO Guide 34 – was used for the certification of reference materials. The reference materials are South African Reference Material SARM 2 (Syenite), SARM 3 (Lujavrite) and SARM 4 (Norite) from the suite of six NIMROCs that were originally certified by the Council for Mineral Technology (MINTEK) in South Africa in the 1970s. 相似文献
94.
Most laboratories aim to produce data of the highest quality. Trying to lower uncertainties to infinitesimal figures and push detection limits even lower are valid goals. However, is it possible to overachieve? Are old data still of good enough quality to be usable? In a geochemical context, the main goal of producing analytical results is to answer geological or environmental questions. Not all scientific problems require the same data quality. What is really required are data of adequate quality – i.e., ‘fit-for-purpose’– to ensure that the geological problem at hand can be solved. Furthermore, it is doubtful that uncertainties and reproducibilities associated with field sampling are better than those from laboratories. It is thus proposed that, as geoanalysts, we encourage data users (students, colleagues or referees) to ensure that their analytical results are of sufficient quality to solve the problem. However, authors have to demonstrate, through the use of reproducibility testing, reference and quality control materials, that the quality of their results is sufficient to solve the problem. Uncertainties and detection limits in publications should not only be evaluated with respect to a set value, such as 10%, but also with regard to the geological problem to be solved. 相似文献
95.
Isotope Dilution Determinations of Lu,Hf, Zr,Ta and W,and Hf Isotope Compositions of NIST SRM 610 and 612 Glass Wafers 总被引:1,自引:0,他引:1
Oliver Nebel Melanie L.A. Morel Pieter Z. Vroon 《Geostandards and Geoanalytical Research》2009,33(4):487-499
Isotope dilution determinations of Lu, Hf, Zr, Ta and W are reported for nine test portions (five for W) of NIST SRM 610 and 612 glass wafers. Additionally, all test portions were analysed for their Hf isotope compositions. In general, high field strength elemental (HFSE) distributions in NIST SRM 610 and 612 were reproducible to ~± 1%, except for Zr (± 5%) in NIST SRM 612, and absolute reported concentrations agreed with previously published values, but with higher precision. The slightly worse reproducibility of Zr in NIST SRM 612 compared to other HFSE is interpreted to result from analytical scatter, rather than sample inhomogeneity. The analyses demonstrated elemental homogeneity for both glass wafers for samples of 1–2 mg with respect to the precision of the method, i.e., ± 1% or better. Average Hf isotope compositions for both glass wafers agreed within uncertainty and the weighted average of all determinations yielded a mean 176Hf/177Hf ratio of 0.282111 ± 0.000009 (95% confidence level). However, although mean values for NIST SRM 610 and 612 agreed within analytical limits, NIST SRM 610 test portions showed a tendency of systematically elevated isotope composition of ~ 0.5 ?Hf units when compared to NIST SRM 612, which may indicate a slightly more radiogenic Hf isotope composition of NIST SRM 610. The results of this study suggest that NIST SRM 610 and 612 are valuable calibrators for HFSE in situ analyses within the given uncertainties. 相似文献
96.
97.
Comprehensive Chemical and Isotopic Analyses of Basalt and Sediment Reference Materials 总被引:2,自引:0,他引:2
Catherine Chauvel Sarah Bureau Christèle Poggi 《Geostandards and Geoanalytical Research》2011,35(1):125-143
Geochemical studies of geological samples require the precise determination of their major and trace element contents and, when measured, of their isotopic compositions. It is now commonly accepted that the accuracy and precision of geochemical analyses are best estimated by the concomitant analysis of international reference materials run as unknown samples. Although the composition of a wide selection of basalts is relatively well constrained, this is far from being the case for sedimentary materials. We present here a comprehensive set of major and trace element data as well as Nd, Hf, Sr and Pb isotopic compositions for thirteen commonly used international reference materials – eight magmatic rocks (BHVO‐2, BR, BE‐N, BR 24, AGV‐1, BIR‐1, UB‐N, RGM‐1) and five sediments (JLk‐1, JSd‐1, JSd‐2, JSd‐3, LKSD‐1). We determined the concentrations of over forty elements in the magmatic rocks together with Sr, Nd, Hf and Pb isotopic compositions. Our trace element results were both accurate (difference ≤ 3%) and precise (reproducibility at 1s ≤ 3%) and the isotopic results were very similar to other published values. In contrast, we observed a significant chemical and isotopic variability in the sedimentary materials, which we attribute to mineral heterogeneities in the powders. Despite the limitation imposed by this heterogeneity, our work presents a complete set of data determined with a precision not yet achieved in the literature for sedimentary material. We also provide the first Nd, Hf and Pb isotopic measurements for the five sediments, which are commonly used by the geochemical community. Our study of both basalt and sediment reference materials represents a comprehensive and self‐consistent set of geochemical data and can therefore be considered as a reference database for the community. 相似文献
98.
Klaus Peter Jochum Brigitte Stoll Ulrike Weis Dorrit E. Jacob Regina Mertz‐Kraus Meinrat O. Andreae 《Geostandards and Geoanalytical Research》2014,38(3):265-292
LA‐ICP‐MS is one of the most promising techniques for in situ analysis of geological and environmental samples. However, there are some limitations with respect to measurement accuracy, in particular for volatile and siderophile/chalcophile elements, when using non‐matrix‐matched calibration. We therefore investigated matrix‐related effects with a new 200 nm femtosecond (fs) laser ablation system (NWRFemto200) using reference materials with different matrices and spot sizes from 10 to 55 μm. We also performed similar experiments with two nanosecond (ns) lasers, a 193 nm excimer (ESI NWR 193) and a 213 nm Nd:YAG (NWR UP‐213) laser. The ion intensity of the 200 nm fs laser ablation was much lower than that of the 213 nm Nd:YAG laser, because the ablation rate was a factor of about 30 lower. Our experiments did not show significant matrix dependency with the 200 nm fs laser. Therefore, a non‐matrix‐matched calibration for the multi‐element analysis of quite different matrices could be performed. This is demonstrated with analytical results from twenty‐two international synthetic silicate glass, geological glass, mineral, phosphate and carbonate reference materials. Calibration was performed with the certified NIST SRM 610 glass, exclusively. Within overall analytical uncertainties, the 200 nm fs LA‐ICP‐MS data agreed with available reference values. 相似文献
99.
High‐Precision Iron Isotope Analysis of Geological Reference Materials by High‐Resolution MC‐ICP‐MS
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Yongsheng He Shan Ke Fang‐Zhen Teng Tiantian Wang Hongjie Wu Yinhuai Lu Shuguang Li 《Geostandards and Geoanalytical Research》2015,39(3):341-356
We report high‐precision iron isotopic data for twenty‐two commercially available geological reference materials, including silicates, carbonatite, shale, carbonate and clay. Accuracy was checked by analyses of synthetic solutions with known Fe isotopic compositions but different matrices ranging from felsic to ultramafic igneous rocks, high Ca and low Fe limestone, to samples enriched in transition group elements (e.g., Cu, Co and Ni). Analyses over a 2‐year period of these synthetic samples and pure Fe solutions that were processed through the whole chemistry procedure yielded an average δ56Fe value of ?0.001 ± 0.025‰ (2s, n = 74), identical to the expected true value of 0. This demonstrates a long‐term reproducibility and accuracy of < 0.03‰ for determination of 56Fe/54Fe ratios. Reproducibility and accuracy were further confirmed by replicate measurements of the twenty‐two RMs, which yielded results that perfectly match the mean values of published data within quoted uncertainties. New recommended values and associated uncertainties are presented for interlaboratory calibration in the future. 相似文献
100.
Fang‐Zhen Teng Wang‐Ye Li Shan Ke Wei Yang Sheng‐Ao Liu Fatemeh Sedaghatpour Shui‐Jiong Wang Kang‐Jun Huang Yan Hu Ming‐Xing Ling Yan Xiao Xiao‐Ming Liu Xiao‐Wei Li Hai‐Ou Gu Corliss K. Sio Debra A. Wallace Ben‐Xun Su Li Zhao Johnnie Chamberlin Melissa Harrington Aaron Brewer 《Geostandards and Geoanalytical Research》2015,39(3):329-339
Magnesium isotopic compositions are reported for twenty‐four international geological reference materials including igneous, metamorphic and sedimentary rocks, as well as phlogopite and serpentine minerals. The long‐term reproducibility of Mg isotopic determination, based on 4‐year analyses of olivine and seawater samples, was ≤ 0.07‰ (2s) for δ26Mg and ≤ 0.05‰ (2s) for δ25Mg. Accuracy was tested by analysis of synthetic reference materials down to the quoted long‐term reproducibility. This comprehensive dataset, plus seawater data produced in the same laboratory, serves as a reference for quality assurance and inter‐laboratory comparison of high‐precision Mg isotopic data. 相似文献