A three end-member model for petrologic analysis of lunar prospector gamma-ray spectrometer data

We analyze preliminary Lunar Prospector gamma-ray spectrometer data. Al-Mg and Fe-Mg petrologic maps of the Moon show that Mg-rich rocks are located in Mare Frigoris, the South Pole Aitken basin, and in some cryptomaria. Analysis of distances of Lunar Prospector pixels from three end-member plane in Mg-Al-Fe space reveals existence of Ca-rich, Al-low small-area anomalies in the farside highlands. An Mg-Th-Fe petrologic technique can be used for estimation of abundances of ferroan anorthosites, mare basalts, KREEP basalts, and Mg-rich rocks.     

A tale of two isotopes: differences in hydrograph separation for a runoff event when using δD versus δ18O

It is often assumed that stable water isotopes (δD and δ¹⁸O) provide redundant information for a given sample of water. In this note we illustrate that the choice of isotope used may influence the resultant hydrograph separation. This is especially true in light of the spatial and temporal variability in the isotopic composition of rainfall water at the catchment scale. We present several possible hydrograph separations based on both δD and δ¹⁸O observed in rainfall for a single runoff event occurring in the southwest USA. This study demonstrates the potential of using both stable water isotopes by showing that δD and δ¹⁸O may provide unique information for catchment hydrologists. We also report on the utility of new technology capable of simultaneous measurements of both δD and δ¹⁸O using off‐axis integrated cavity output spectroscopy (OA‐ICOS) methods. This may be of interest to catchment hydrologists seeking to incorporate this type of equipment into their laboratory. Copyright © 2009 John Wiley & Sons, Ltd.     

Experimental Research on Quantitative Inversion Models of Suspended Sediment Concentration Using Remote Sensing Technology

Research on quantitative models of suspended sediment concentration(SSC)using remote sensing technology is very important to understand the scouring and siltation variation in harbors and water channels.Based on laboratory study of the relationship between different suspended sediment concentrations and reflectance spectra measured synchronously,quantitative inversion models of SSC based on single factor,band ratio and sediment parameter were developed,which provides an effective method to retrieve the SSC from satellite images.Results show that the b1(430-500nm)and b3(670-735nm)are the optimal wavelengths for the estimation of lower SSC and the b4(780-835nm)is the optimal wavelength to estimate the higher SSC.Furthermore the band ratio B2/B3 can be used to simulate the variation of lower SSC better and the B4/B1 to estimate the higher SSC accurately.Also the inversion models developed by sediment parameters of higher and lower SSCs can get a relatively higher accuracy than the sin-gle factor and band ratio models.     

Infrared reflectance spectroscopy on thin films: Interference effects

Laboratory simulations of processes on astronomical surfaces that use infrared reflectance spectroscopy of thin films to analyze their composition and structure often ignore important optical interference effects which often lead to erroneous measurements of absorption band strengths and give an apparent dependence of this quantity on film thickness, index of refraction and wavelength. We demonstrate these interference effects experimentally and show that the optical depths of several absorption bands of thin water ice films on a gold mirror are not proportional to film thickness. We describe the method to calculate accurately band strengths from measured absorbance spectra using the Fresnel equations for two different experimental cases, and propose a way to remove interference effects by performing measurements with P-polarized light incident at Brewster's angle.     

Spectroscopic studies of solar corona VI: Trend in line-width variation of coronal emission lines with height independent of the structure of coronal loops

We have obtained spectroscopic observations in coronal emission lines by choosing two lines simultaneously, one [Fe x] 6374 Å and the other [Fe xi] 7892 Å or [Fe xiii] 10747 Å or [Fe xiv] 5303 Å. We found that in 95 per cent of the coronal loops observed in 6374 Å, the FWHM of the emission line increases with height above the limb irrespective of the size, shape and orientation of the loop and that in case of 5303 Å line decreases with height in about 89 per cent of the coronal loops. The FWHM of 7892 Å and 10747 Å emission lines show intermediate behavior. The increase in the FWHM of 6374 Å line with height is the steepest among these four lines. We have also studied the intensity ratio and ratio of FWHM of these lines with respect to those of 6374 Å as a function height above the limb. We found that the intensity ratio of 7892 Å and 10747 Å lines with respect to 6374 Å line increases with height and that of 5303 Å to 6374 Å decreases with height above the limb. This implies that temperature in coronal loops will appear to increase with height in the intensity ratio plots of 7892 Å and 6374 Å; and 10747 Å and 6374 Å whereas it will appear to decrease with height in intensity ratio of 5303 Å to 6374 Å lineversus height plot. These findings are up to a height of about 200 arcsec above the limb. The varying ratios with height indicate that relatively hotter and colder plasma in coronal loops interact with each other. Therefore, the observed increase in FWHM with height above the limb of coronal emission lines associated with plasma at about 1 MK may not be due to increase in non-thermal motions caused by coronal waves but due to interaction with the relatively hotter plasma. These findings also do not support the existing coronal loop models, which predict an increase in temperature of the loop with height above the limb.     

Anomalous lead isotope ratios and provenance of offshore sediments,Gulf of Carpentaria,northern Australia

Anomalous Pb isotope ratios measured by Inductively Coupled Plasma Mass Spectrometry in terrigenous marine sediments (<63 μm fraction) from the Gulf of Carpentaria originated from depositional mixing of clay/silt with average modern crustal Pb isotope ratios and detrital monazite with high ²⁰⁸Pb/²⁰⁶Pb and low ²⁰⁷Pb/²⁰⁶Pb. This interpretation is supported by strong correlations between Pb isotope ratio and Th, U and light rare‐earth element concentrations in the sediments as well as by monazite compositional data. A likely source of the detrital monazite is the western portion of the Georgetown Inlier of mainly Proterozoic S‐type granitic rocks. A clear distinction between Pb isotope ratios in sediments deposited from the Norman and Bynoe Rivers in the southeast Gulf of Carpentaria and the persistence of catchment‐specific Pb isotope ratios 45 km offshore suggest that Pb isotope data are useful in tracing the provenance of terrigenous offshore sediments when the source rocks of catchments show sufficient chemical and/or mineralogical variation.     

Millennial‐scale precipitation changes over Central Africa during the late Quaternary and Holocene: evidence in sediments from the Gulf of Guinea

We combine environmental magnetism, geochemical measurements and colour reflectance to study two late Quaternary sediment cores: GeoB 4905‐4 at 2° 30′ N off Cameroon and GeoB 4906‐3 at 0° 44′ N off Gabon. This area is suitable for investigating precipitation changes over Central and West Africa because of its potential to record input of aeolian and fluvial sediments. Three magnetozones representing low and high degree of alteration of the primary rock magnetic signals were identified. The magnetic signature is dominated by fine‐grained magnetite, while residual haematite prevails in the reduced intervals, showing increase in concentration and fine grain size at wet intervals. Our records also show millennial‐scale changes in climate during the last glacial and interglacial cycles. At the northern location, the past 5.5 ka are marked by high‐frequency oscillations of Ti and colour reflectance, which suggests aeolian input and hence aridity. The southern location remains under the influence of the Intertropical Convergence Zone and thus did not register aeolian signals. The millennial‐scale climatic signals indicate that drier and/or colder conditions persisted during the late Holocene and are synchronous with the 900 a climatic cycles observed in Northern Hemisphere ice core records. Copyright © 2009 John Wiley & Sons, Ltd.     

Discovery of diamond in the Tromsø Nappe,Scandinavian Caledonides (N. Norway)

We report the first finding of diamond in crustal rocks from the Tromsø Nappe of the North Norwegian Caledonides. Diamond occurs in situ as inclusions in garnet from gneiss at Tønsvika near Tromsø. The rock is composed essentially of garnet, biotite, white mica, quartz and plagioclase, minor constituents include kyanite, zoisite, rutile, tourmaline, amphibole, zircon, apatite and carbonates (magnesite, dolomite, calcite). The microdiamond, identified by micro‐Raman spectroscopy, is cuboidal to octahedral in shape and ranges from 5 to 50 μm in diameter. The diamond occurs as single grains and as composite diamond + carbonate inclusions. Diamond vibration bands show a downshift from 1 332 to 1 325 cm^?1, the majority of Raman peaks are centred between 1 332 and 1 330 cm^?1 and all peaks exhibit a full width at half maximum between 3 and 5 cm^?1. Several spectra show Raman bands typical for disordered and ordered graphite (sp²‐bonded carbon) indicating partial transformation of diamond to graphite. The calculated peak P–T conditions for the diamond‐bearing sample are 3.5 ± 0.5 GPa and 770 ± 50 °C. Metamorphic diamond found in situ in crustal rocks of the Tromsø Nappe thus provides unequivocal evidence for ultrahigh pressure metamorphism in this allochthonous unit of the Scandinavian Caledonides. Deep continental subduction, most probably in the Late Ordovician and shortly before or during the initial collision between Baltica and Laurentia, was required to stabilize the diamond at UHP conditions.     

Minor Constituent Concentrations Measured from a High Altitude Aircraft Using High Resolution Far-Infrared Fourier Transform Spectroscopy

Far-infrared emission spectroscopy has beendemonstrated to be a valuable method for remotesensing of trace species in the stratosphere, with theability to simultaneously detect a number of keychemical species. SAFIRE-A is a new far-infraredFourier Transform (FT) spectrometer which has beenspecifically designed to operate on board of a highaltitude aircraft in the lower stratosphere and uppertroposphere regions where relatively few remotesensing measurements have been made. Using newtechnology, the sensitivity of the FT spectrometermethod has been substantially improved for the longwavelength region. Results are reported formeasurements of O₃, HNO₃ and N₂O at 17and 19 km using a detection window near 23 cm^-1.Geographical and altitude variability of the volumemixing ratio of these constituents and their relativecorrelation are discussed. Ozone measurements agreewell with in situ measurements, except in regions ofstrong stirring and mixing associated with deformationof the northern vortex edge. Whilst SAFIREmeasurements of trace gases do not capture all of thelocal variability seen by rapid in-situ techniques,they can indicate horizontal variability close to, butnot intercepted by, the aircraft's flight path. Apossible detection of ClO at the low background levelsexpected outside the polar vortex is also reported.     

The transmittance color index of amorphous organic matter: a thermal maturity indicator for petroleum source rocks

Since the mid-1980s, Texaco has used the transmittance color index (TCI) of amorphous kerogen as an indicator of kerogen thermal maturation. The technique simply involves the direct measurement of a white-light spectrum as it is transmitted through a particle of amorphous organic matter (AOM). In brief, TCI values are obtained by the analysis of white light originating from a 100-W 6-V tungsten lamp attached to a photometric microscope. The assignment of particular TCI values is based on the increasing curvature of spectra with increasing maturity. TCI curves shift from an average wavelength around 580 nm for samples of immature, amorphous kerogen (i.e., material with a mean, random vitrinite reflectance of about 0.20%) to about 660 nm for samples containing very dark brown to some black particulate material (i.e., kerogen with a mean, random vitrinite reflectance of about 2.15%). The range of TCI values covers all zones of petroleum generation and preservation. In our opinion, TCI can provide as accurate a basis for maturation interpretations as is available from vitrinite reflectance (or from the mean random reflectance of some zooclasts, such as graptolites and chitinozoans), or the widely used visual estimate the thermal alteration index (TAI) or the similarly determined conodont color index (CAI). TCI is probably most useful, however, in those situations where the rocks to be examined have not yet reached the semianthricite coalification stage (≈2.0% vitrinite reflectance).