基于图像法的多孔介质双分子反应溶质运移模拟

采用图像分析法确定溶质浓度,以硫酸铜和EDTA二钠作为双分子反应物,在多孔介质模型中开展了不同粒径(1.52.0,2.53.0,3.54.0 mm)和流量(1.0,1.5,2.0 mL/s)下反应性溶质运移实验,探讨了应用不完全混合的对流弥散模型(IM-ADRE)对双分子反应溶质运移的模拟和预测,并进行了参数敏感性分析。结果表明:图像分析法可准确获取多孔介质中显色反应性溶质的浓度,灰度值与浓度的决定系数R²大于0.96;用IM-ADRE模型能够准确预测双分子反应性溶质硫酸铜和EDTA二钠在3种不同多孔介质中的运移过程,误差低于3.71%;实验条件的改变对IM-ADRE模型参数D、m和β₀的影响显著,说明模型参数依赖于环境条件,其变化规律需要根据实际环境条件进一步率定,便于IM-ADRE模型的进一步推广应用。     

2016年冬季京津冀豫大气污染的时空分布及影响因子研究

利用2016年12月至2017年2月北京、天津、石家庄和郑州的PM2.5质量浓度、反应性气体质量浓度及其相对应的气象要素资料分析了大气污染的理化特征、传输和生消规律。结果表明:北京、石家庄、天津及郑州的PM2.5质量浓度分布频率均有两个较为明显的峰值,四个地区PM2.5质量浓度分布频率最高时均值分别为10.1、19.2、40.0和47.1μg·m^-3,大气的氧化程度为北京最低,其次为石家庄、天津,郑州最高。四个研究地区的交通源对环境大气污染均有重要贡献。PM2.5和CO的相关性在低相对湿度时高于高相对湿度时;而PM2.5和NO2的相关性在相对湿度较大时高于相对湿度较小时。四个研究地区的PM2.5质量浓度均随风速的增大呈快速降低后趋于平缓的趋势,其中北京、石家庄和郑州的风速阈值均为3m·s^-1,天津地区为4m·s^-1。受上游污染地区的影响,偏南风的输送作用滞后20~30h达到最大,而偏北风的影响作用在滞后8~12h达到最大。     

Predictive modelling of dump water impact on the surroundings of the lignite dump site Jänschwalde (Eastern Germany)

Open cast mining of lignite leads to dumps containing highly mineralised pore waters. To predict the impact of the dump waters on the undisturbed aquifers two steps are necessary. (1) The prediction of dump water quality at times when steady state flow conditions will be established. (2) The simulation of the dump ground water migration with a model that is able to handle the complexity of the homogeneous and heterogeneous interactions of the migration process.For the investigated site Jänschwalde, which is still dewatered, a chemical mass balance was performed. The predicted alkalinity potentials exceed acidity potentials for the dump as a whole. The distribution of these parameters show high alkalinity potentials for the northern part.In order to model the migration process the transport code PCGEOFIM^® [Anwenderdokumentaion, IBGW Leipzig, (in German)] was coupled with the geochemical equilibrium code PHREEQC [USGS, Water-Resources Investigations Report]. This was done to simulate redox reactions, mineral dissolution and precipitation, and cation exchange in the ground water zone. The model is verified by a column flow test. The results of the simulations show a small effect of the migrating dump waters on the quartenary aquifer with respect to acidity changes. This results from calcite buffering and cation exchange. The impact on the quartenary aquifer by sulphate is much higher.     

天然粉石英的开发利用及深加工

介绍了粉石英的基本性能，概括了粉石英在工业中的应用，研究了提高粉石英表面活性的方法，进一步揭示了粉石英作为填料的潜在应用价值。     

云南梅树村前寒武系-寒武系界线剖面硅同位素研究

云南梅树村前寒武系-寒武系界线剖面是研究前寒武系-寒武系界线层型最重要的国际候选剖面之一。本文首次系统地研究了硅同位素在剖面中的变化规律,指出“C”点附近“界线粘土层”为火山成因,“B”点至“C”点之间有海底喷气活动;“C”点附近的δ~(13)C,δ~(18)O负异常与生物大量活动有关,而非“灾变”所致。     

中国的天然硅铁矿

硅铁矿属于罕见的Ｓｉ和Ｆｅ的互化物类矿物，目前在自然界已发现并命名的此类矿物相的矿物有：古北矿（Ｆｅ＿３Ｓｉ）、喜峰矿（Ｆｅ＿５Ｓｉ＿３）、等轴硅铁矿（ＦｅＳｉ）、二磋铁矿（ＦｅＳｉ＿２）及苏硅铁矿（ａＦｅ＿３Ｓｉ）等５种。本文着重介绍我国自１９８０年以来在藏、甘、冀、苏、皖、新、辽、浙诸省区所发现的二硅铁矿及其连生矿物自然硅。     

大厂锡矿床硅,氧同位素地球化学

本文对大厂锡矿床不同类型石英和岩石进行系统的硅、氧同位素研究表明，各类矿化体中石英的硅同位素组成几乎相同，而且它们又与直接容矿硅质岩的δ30Si值十分接近，但完全不同于矿区侵入岩的有关值。这说明层状矿体中的石英与直接窑矿硅质岩有相同的硅质来源，后期各类脉状矿化过程中的硅质来自容矿硅质岩，而不是花岗岩。层状矿体中荣带状岩石和含冰长石混合样的δ30Si值为-0．3‰±0．2‰，这组负值可能是由冰长石引起的。但冰长石中的硅是由海底热水活动系统还是火山灰尘提供尚待研究。对比发现，本矿区硅质岩δ30Si值与部分深海（洋壳区）、半深海（陆壳区）放射虫硅质岩有关资料相似，但其δ18O值低于全球各类硅质岩，它们可能是在海底热水活动与生物化学作用共同参与下形成的。     

我国首次发现原生—自然硅

本文对自然硅进行了矿相学，矿物学研究，该矿物产于福建某地矽卡岩型硫，多金属矿床中，自然硅呈亮灰银白色、强金属光泽。性脆。镜下呈浑圆粒状、乳滴状，均质。实测比重ｄ＝２．３６８。硬度ＨＭ＝６．７６。反射率Ｒ：４７０ｎｍ３７０８；５４６ｎｍ３１．２７；６５０ｎｍ２９．９６。经扫描电镜能谱分析、电子探针分析，Ｓｉ９９．８７％～９９．９４％。含少许Ａｌ，Ｃａ，Ｆｅ机械混入物，Ｘ射线粉晶分析，主要Ｘ射线粉晶谱     

Equation of state of iron–silicon alloys to megabar pressure

The stability and pressure–volume equation of state of iron–silicon alloys, Fe-8.7 wt% Si and Fe-17.8 wt% Si, have been investigated using diamond-anvil cell techniques up to 196 and 124 GPa, respectively. Angular–dispersive X-ray diffractions of iron–silicon alloys were measured at room temperature using monochromatic synchrotron radiation and an imaging plate (IP). A bcc–Fe-8.7 wt% Si transformed to hcp structure at around 1636 GPa. The high-pressure phase of Fe-8.7 wt% Si with hexagonal close-packed (hcp) structure was found to be stable up to 196 GPa and no phase transition of bcc–Fe-17.8 wt% Si was observed up to 124 GPa. The pressure–volume data were fitted to a third-order Birch–Murnaghan equation of state (BM EOS) with zero–pressure parameters: V₀=22.2(8) ų, K₀=198(9) GPa, and K₀=4.7(3) for hcp–Fe-8.7 wt% Si and V₀=179.41(45) ų, K₀=207(15) GPa and K₀=5.1(6) for Fe-17.8 wt% Si. The density and bulk sound velocity of hcp–Fe-8.7 wt% Si indicate that the inner core could contain 3–5 wt% Si.     

Availability of Bauxite Reserves

Based upon a large database, this paper analyzes the record of bauxite mine production, exploration success, and resource depletion and evaluates the availability of bauxite reserves in the near future. The record clearly shows that for the past 50 years world bauxite production rose by an annual increase of over 5% while per capita consumption rose during the same period by about 4%. Time trends of the world bauxite reserve life index (RLI); that is, known world reserves of a given year divided by world production of the same year, are episodic and seem to follow bauxite price cycles. The present-day RLI indicates adequate bauxite supply for about 180 years and is the same as it was in 1950. However, if an annual growth rate of 5% is considered, the currently known reserves will be exhausted within the next 20 years and the reserve base will be adequate for not more than 25 years. This scenario is based, of course, on the unrealistic assumption that future exploration efforts fail to discover additional reserves. Evaluation of the quality, in terms of bauxite signatures, and quantity of presently known bauxite prospects that may be mined in future suggests that there is sufficient potential for adequate bauxite supply for the next 20 to 25 years at least. Bauxite signatures cover a wide range of values that allows selection of the most favorable bauxite prospects for future mining, both in economic as well as environmental terms. Although, there is the general believe that the world abundance of bauxite resources will ensure sufficient supply to meet future demands significant additional reserves have to be discovered if exponential growth rates continue. As the question of future bauxite supply is subject to economic and geologic principles one has to take into consideration that increasing exploration maturity in many mineral provinces will make it difficult to locate additional bauxite reserves and that decreasing real commodity prices will influence the level of investment in bauxite exploration.