微细浸染型金矿深源矿质和流体地球化学示踪研究

在宏观和微观地质特征研究基础上,运用硅同位素动力学分馏原理,结合硅质阴极发光分析,论证了微细浸染型金矿的成矿硅质、矿质和流体主要直接来源于上地幔分异或深部循环的超临界流体,并认为这种深部因素可能对形成大型和超大型矿床发挥了重要作用.这对该类型金矿的成因研究及找矿开辟了新的思路.     

硅肥对水稻镉吸收影响初探

试验表明：用炼铁水淬渣为主要原料生产的硅肥,能够抑制水稻对镉吸收。在本试验条件下,施硅肥后糙米镉含量相对下降９２％以上,稻草镉含量下降９４％。随着硅肥施用量的增加,抑制作用有增强的趋势,作者认为在镉污染不太严重的地区,施用硅肥可以防止重金属污染。     

A semianalytical approach for solving first-order perturbation equations of dissolution-timescale reactive infiltration instability problems in fluid-saturated rocks

This paper presents a semianalytical approach for solving first-order perturbation (FOP) equations, which are used to describe dissolution-timescale reactive infiltration instability (RII) problems in fluid-saturated rocks. The proposed approach contains two parts because the chemical dissolution reaction divides the whole problem domain into two subdomains. In the first part, the interface-condition substitution strategy is used to derive the analytical expressions of purely mathematical solutions for the FOP equations in the upstream subdomain, where the dissolution chemical reaction is ceased and the FOP equations are weakly coupled. In the second part, the finite element method (FEM) is used to derive the analytical expressions of numerical solutions for the FOP equations in the downstream subdomain, where the dissolution chemical reaction needs to be considered and the FOP equations are strongly coupled so that it is impossible to derive purely mathematical solutions for them. Particular attention is paid to the development of the element-by-element forward marching strategy, which is associated with the use of the FEM for solving this new kind of scientific problem. The related analytical results demonstrated that (1) both the dynamic characteristic of a reactive infiltration system and the dimensionless wavenumber can have pronounced influences on the distribution of the FOP dimensionless acid concentration within the entire domain of the dissolution-timescale RII problems in fluid-saturated rocks and (2) the FOP dimensionless acid concentration distribution exhibits two significantly different patterns in the upstream and downstream subdomains of the dissolution-timescale RII system.     

Sources and variability of CO2 in a prealpine stream gravel bar

Gravel bars (GBs) contribute to carbon dioxide (CO₂) emissions from stream corridors, with CO₂ concentrations and emissions dependent on prevailing hydraulic, biochemical, and physicochemical conditions. We investigated CO₂ concentrations and fluxes across a GB in a prealpine stream over three different discharge‐temperature conditions. By combining field data with a reactive transport groundwater model, we were able to differentiate the most relevant hydrological and biogeochemical processes contributing to CO₂ dynamics. GB CO₂ concentrations showed significant spatial and temporal variability and were highest under the lowest flow and highest temperature conditions. Further, observed GB surface CO₂ evasion fluxes, measured CO₂ concentrations, and modelled aerobic respiration were highest at the tail of the GB over all conditions. Modelled CO₂ transport via streamwater downwelling contributed the largest fraction of the measured GB CO₂ concentrations (31% to 48%). This contribution increased its relative share at higher discharges as a result of a decrease in other sources. Also, it decreased from the GB head to tail across all discharge‐temperature conditions. Aerobic respiration accounted for 17% to 36% of measured surface CO₂ concentrations. Zoobenthic respiration was estimated to contribute between 4% and 8%, and direct groundwater CO₂ inputs 1% to 23%. Unexplained residuals accounted for 6% to 37% of the observed CO₂ concentrations at the GB surface. Overall, we highlight the dynamic role of subsurface aerobic respiration as a driver of spatial and temporal variability of CO₂ concentrations and evasion fluxes from a GB. As hydrological regimes in prealpine streams are predicted to change following climatic change, we propose that warming temperatures combined with extended periods of low flow will lead to increased CO₂ release via enhanced aerobic respiration in newly exposed GBs in prealpine stream corridors.     

Mosaic and gradient SiGe single crystals for gamma ray Laue lenses

Both Ge_1−x Si _x mosaic crystals and Si_1−x Ge _x crystals with gradient of composition could be grown using the modified Czochralski technique to produce the diffracting elements for the MAX gamma ray telescope. Although many elements cut from the mosaic crystal and used before for CLAIRE gamma ray telescope had an efficiency up to 20%, the overall efficiency of the lens was about 8.1 ± 0.7 %, which is more than twice lower than the theoretically predicted efficiency. Some causes of this behaviour are discussed. In addition to mosaic crystals, the growth of Si_1−x Ge _x crystals with a gradient of composition and their properties are analysed. Such composition-gradient crystals could be a promising way to improve the diffraction efficiency of Laue lens for MAX.     

X射线荧光光谱法测定锌铝硅合金中硅和铁

采用岛津MXF-2400型多道X荧光光谱仪测定锌铝硅合金中硅及铁的含量,对样品分析面进行了选择,考察了分析面光洁度、样品放置时间对测定的影响条件。方法样品前期处理简便,分析速度快,灵敏度高,硅和铁的相对标准偏差(RSD,n=11)分别为1.15%和0.44%。与其他方法对照,结果相符。     

利用高精度重磁法对“羊里磁异常”的解释探讨

"羊里磁异常"自1967年发现以来,由于所处地质环境为矽卡岩型铁矿成矿有利地段,且紧邻已知的温石埠铁矿,以及"羊里磁异常"规模较大且具备低缓磁异常的特点,一直受到地质界的广泛关注,地勘单位在该区做了大量的铁矿找矿工作,但对"羊里磁异常"勘查中一直未取得突破性进展,该文从高精度重磁角度对"羊里磁异常"进行了定量解释以及定量计算,并通过钻探验证等技术手段,进一步推断"羊里磁异常"是由古近纪含磁铁碎屑的砂砾岩以及闪长岩共同引起的,对该异常的认识更进了一步。     

可渗透反应墙对重金属离子Pb~(2+)、Cd~(2+)吸附效果的试验研究

以受尾矿库渗滤液重金属离子Pb2+、Cd2+污染的地下水为研究对象,用天然矿物材料红辉沸石与膨润土作为反应渗透墙(PRB)的活性介质填充材料,试验结果表明,膨润土∶红辉沸石=1∶7,PRB渗透系数处于10-4cm/s数量级且随时间下降最为缓慢;PRB对单一组分Pb2+和单一组分Cd2+去除率分别达99.95%和99.995%;但在双组分PRB体系中,重金属离子Pb2+的存在显著地抑制了PRB对Cd2+的吸附作用,优先选择性吸附顺序是Pb2+Cd2+。     

不同介质材料组合可渗透反应墙渗透性能试验研究

渗透系数是可渗透反应墙(PRB)正常运行的关键参数之一,与PRB活性填充材料的选择密切相关。本试验采用常水头渗透系数测试法,首先选用斜发沸石、红辉沸石为作为PRB的活性介质材料,考察了沸石矿物的类型和粒径对PRB渗透系数的影响,试验结果显示,同一粒径的斜发沸石PRB和红辉沸石PRB渗透系数相差一个数量级;处于同一数量级渗透系数沸石PRB,斜发沸石的粒径大于红辉沸石的粒径。在此基础上,以膨润土作为掺和活性介质材料,讨论了渗透系数处于同一数量级沸石PRB,掺和比例对渗透系数的影响,结果表明,膨润土的掺和能导致沸石PRB渗透系数量级上的差异,与斜发沸石相比,红辉沸石更有利于实现沸石PRB系统渗透系数的可调性。     

锯缘青蟹不同器官组织中ROS与ASAFR含里的研究

采用生化测定的方法,对锯缘青蟹(Scyllaserrata)鳃、肝胰腺和肌肉等不同器官组织中活性氧(ROS)与抗超氧阴离子自由基(ASAFR)含量进行了测定。　结果表明,　不同器官组织中活性氧与抗超氧阴离子自由基含量各异。　各器官组织中活性氧含量由高到低依次为:肝胰腺>肌肉>鳃,　分别为195.04U/mg±33.46U/mg, 64.03 U/mg±12.77 U/mg和44.84U/mg±10.44U/mg。而抗超氧阴离子自由基含量则是鳃>肝胰腺>肌肉,大小分别为439.62 U/g±64.73U/g,297.89 U/g±39.75 U/g和84.24 U/g±18.03 U/g。统计分析显示,锯缘青蟹各器官组织间的活性氧与抗超氧阴离子自由基含量均存在极显著性差异(P<0.01)。这是由于不同器官组织所执行的生理功能不同造成的。