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101.
We consider adaptive discontinuous Galerkin (DG) methods for solving reactive transport problems in porous media. To guide
anisotropic and dynamic mesh adaptation, a posteriori error estimators based on solving local problems are established. These error estimators are efficient to compute and effective
to capture local phenomena, and they apply to all the four primal DG schemes, namely, symmetric interior penalty Galerkin,
nonsymmetric interior penalty Galerkin, incomplete interior penalty Galerkin, and the Oden–Babuška-Baumann version of DG.
Numerical results are provided to illustrate the effectiveness of the proposed error estimators. 相似文献
102.
Steve Holland 《Experimental Astronomy》2002,14(2):83-89
Fully depleted, back-illuminated charge-coupled devices fabricated at Lawrence Berkeley National Laboratory on high-resistivity
silicon are described. Device operation and technology are discussed, as well as the results on telescopes and future plans.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
103.
The behavior of dissolved and particulate iron and manganese and dissolved silicon has been studied as a function of chlorinity in the Peconic River estuary, New York. This study sought to identify important geochemical processes in a relatively pristine estuary facing increasing anthropogenic impact.Dissolved iron behaved in the classical non-conservative manner exhibiting removal of nearly 80% at very low chlorinities, while particulate iron increased by a corresponding amount over the same chlorinity range. Dissolved manganese was enriched by up to 200% over its predicted concentration at low and intermediate chlorinities by desorption from suspended particulates and by a probable benthic flux. Dissolved silicon was enriched by up to 100% at low and intermediate chlorinities also from a probable benthic flux. These fluxes were estimated to be 5 μg cm?2 day?1 for dissolved manganese and 70 μg cm?2 day?1 for dissolved silicon.The quantity of both particulate iron and manganese increased at high chlorinities due to an influx of suspended inorganic particulates. In the intermediate to high chlorinity region, oxidation of sediment-derived manganese is believed to contribute to the observed increase in particulate manganese.Total iron was essentially conservative throughout most of the estuary, while total manganese was non-conservative presumably due to extensive remobilization of dissolved manganese from the sediments. 相似文献
104.
Using a single drop experiment, the uptake of NO3 radicals on aqueous solutions of the dye Alizarin Red S and NaCl was measured at 293 K. Uptake coefficients in the range
(1.7–3.1) ⋅ 10− 3 were measured on Alizarin Red S solutions. The uptake coefficients measured on NaCl solutions were in the range of (1.1–2.0)
⋅ 10−3 depending on the salt concentration. Both experiments lead to a consistent result for the mass accommodation coefficient
of αNO3 = (4.2− 1.7+2.2)⋅ 10−3.
The product H(Dl kCl−II)0.5 for the NO3 radical was determined to be (1.9 ± 0.2) M atm− 1 cm s−0.5 M−0.5 s−0.5 by fitting the uptake data for the NaCl solutions to the so-called resistance model.
The yield of the chemical NO3 radical source was characterized using UV-VIS and FT-IR spectroscopy. The amount of gas-phase NO3 radicals measured at elevated humidities was less than expected. Instead, a rise of the gas-phase HNO3 concentration was found indicating a conversion of gas-phase NO3 radicals to gas-phase HNO3 on the moist reactor walls. 相似文献
105.
地下水中铀的反应运移模拟对地下水保护和铀矿区的恢复都很重要, 因为铀是一种化学毒害性很高的放射性元素.在地下水及水与固体之间都应考虑对流、弥散、稀释、吸附等化学相互作用.介绍了德国德累斯顿市附近的Koenigstein矿区淋滤条件的可行性研究结果.由于反应运移模拟需占用大量的CPU时间, 所有的运行在一天内完成, 但用简单的混合法进行了稀释.对于这种研究, PHREEQC 2.2证明是一个功能很强的工具.与PHREEQC相对应的数据库WATEQ4F涉及到48种元素、400多种物质、300多种矿物.根据铀和镭的特性, 对其作了一定的修改, 以使它更具相容性和可靠性. 相似文献
106.
In the water jet propulsion system with a positive displacement (PD) pump, the nozzle, which converts pressure energy into kinetic energy, is one of the key parts exerting great influence on the reactive thrust and the efficiency of the system due to its high working pressure and easily occurring cavitation characteristics. Based on the previous studies of the energy loss and the pressure distribution of different nozzles, a model of water jet reactive thrust, which fully takes the energy loss and the nozzle parameters into consideration, is developed to optimize the nozzle design. Experiments and simulations are carried out to investigate the reactive thrust and the conversion efficiency of cylindrical nozzles, conical nozzles and optimized nozzles. The results show that the optimized nozzles have the largest reactive thrust and the highest energy conversion efficiency under the same inlet conditions. The related methods and conclusions are extended to the study of other applications of the water jet, such as water jet cutting, water mist fire suppression, water injection molding. 相似文献
107.
Zygosaccharomyces rouxii is a salt-tolerant yeast species capable of removing cadmium(Cd) pollutant from aqueous solution. Presently, the physiological characteristics of Z. rouxii under the stress of sodium chloride(NaCl) and Cd are poorly understood. This study investigated the effects of NaCl and Cd on the growth, oxidative stress and antioxidant enzyme activities of Z. rouxii after stress treatment for 24 h. Results showed that NaCl or Cd alone negatively affected the growth of Z. rouxii, but the growth-inhibiting effect of Cd on Z. rouxii was reduced in the presence of NaCl. Flow cytometry assay showed that under Cd stress, NaCl significantly reduced the production of reactive oxygen species(ROS) and cell death of Z. rouxii compared with those in the absence of NaCl. The activities of superoxide dismutase(SOD), catalase(CAT), and peroxidase(POD) of Z. rouxii were significantly enhanced by 2%–6% NaCl, which likely contributed to the high salt tolerance of Z. rouxii. The POD activity was inhibited by 20 mg L-1Cd while the SOD and CAT activities were enhanced by 8 mg L-1 Cd and inhibited by 20 mg L-1 or 50 mg L-1 Cd. The inhibitory effect of high-level Cd on the antioxidant enzyme activities of Z. rouxii was counteracted by the combined use of NaCl, especially at 6%. This probably accounted for the decrease in Cd-induced ROS production and cell death of Z. rouxii after incubation with NaCl and Cd. Our work provided physiological clues as to the use of Z. rouxii as a biosorbent for Cd removal from seawater and liquid highly salty food. 相似文献
108.
A HF‐free sample preparation method was used to purify silicon in twelve geological RMs. Silicon isotope compositions were determined using a Neptune instrument multi‐collector‐ICP‐MS in high‐resolution mode, which allowed separation of the silicon isotope plateaus from their interferences. A 1 μg g‐1 Mg spike was added to each sample and standard solution for online mass bias drift correction. δ30Si and δ29Si values are expressed in per mil (‰), relative to the NIST SRM 8546 (NBS‐28) international isotopic RM. The total variation of δ30Si in the geological reference samples analysed in this study ranged from ‐0.13‰ to ‐0.29‰. Comparison with δ29Si values shows that these isotopic fractionations were mass dependent. IRMM‐17 yielded a δ30Si value of ‐1.41 ± 0.07‰ (2s, n = 12) in agreement with previous data. The long‐term reproducibility for natural samples obtained on BHVO‐2 yielded δ30Si = ‐0.27 ± 0.08‰ (2s, n = 42) on a 12 month time scale. An in‐house Si reference sample was produced to check for the long‐term reproducibility of a mono‐elemental sample solution; this yielded a comparable uncertainty of ± 0.07‰ (2s, n = 24) over 5 months. 相似文献
109.
Desertification has been notably expanding in China in the recent decade, especially in North China where dust/sand storm (DSS) frequently assaulted local communities. Analyses in marine ecology found that the earth ecosystem could be able to complement nutrient silicon for keeping sustain- able development of marine ecosystem, and decreasing CO2 concentration in the atmosphere; as a result, the area of desertification would be enlarged. Modern human being activities have resulted in constant changes in the amount of silicon transport from land into sea, leading to oversupply of nitrogen and phosphorus but silicon in seawater. The proportion of nitrogen, phosphorus and silicon was seriously im- balanced and the limitation of silicon for phytoplankton growth has become more serious. The silicon de- ficiency has damaged the marine ecosystem in coastal regions and slowed down the carbon sedimentation in the atmosphere of the world. The authors believe that the continual discharge of CO2 into the atmos- phere is the cause for the global warming including marine water temperature rise. Consequently, the earth ecosystem would have to trigger its complementary action to resume to the silicon balance by algae bloom in seawater for reducing air and water temperatures. In order to complement nutrient silicon into the sea, the ecosystem would transport silicon via the atmosphere; therefore, the desertification in the in- ner land is a natural reaction. As marine phytoplankton booming can reduce the CO2 concentration in the atmosphere and further ease the green-house effect, during this process, a large amount of silicon are de- manded by the ecosystem, which human being are unable to stop desertification from happening but slow down the progress and ease the risk. Therefore, as an important role in earth ecosystem, people should reduce the CO2 discharge into the atmosphere first; then, the normal function of river transporting silicon must be restored. In this way, the CO2 in the atmosphere can be kept in balance, the global warming slowed down, marine ecosystem development sustained, the drought in inner land eased, and the desert gradually under-controlled. 相似文献
110.
Dolmatova L.S. Eliseykina M.G. Timchenko N.F. Kovaleva A.L. Shitkova O.A. 《中国海洋湖沼学报》2003,21(4):293-304
Pure fraction (92% - 95%) of phagocytes (FP) and a mixture of amoebocytes (62%) and morula cells (38 % )-FPMC- of the holothurian Eupentacta fraudatrix ( Holothuroidea,Dendrochirota ) were obtained by using ficoll-verographine step gradient. Basal production of reactive oxygen species (ROS) in FP quantified by using reduction of nitroblue tetrazolium (NBT) was more than twice that in FPMC. Thermostable toxin of Yersinia pseudotuberculosis (TST) at differentconcentrations ( 0.2; 0.5; 2.5 μg/ml, but not 0.1 μg/ml) stimulated NBT reduction in FPMC after 24 h incubation. In FP, TST at concentrations of 0.1 and 0.2 μg/ml inhibited and at concentrations of 0.5 and 2.5 μg/ml stimulated NBT reduction after 24 h incubation. Maximal effect was observed in FP and FPMC at TST concentrations of 0.5 and 0.2 μg/ml, respectively. Addition of catalase (0.7 μg/ml) to the cells treated with TST (2.5 μg/ml) was followed by a decrease in NBT reduction compared to that under toxin treatment alone. TST stimulated superoxide dismutase activity in ccncentration-dependent manner (maximum at 0.5 μg/ml concentration in FP) after 24 htreatment, and this stimulation was prevented by a commercial catalase. Plant lectin concanavalin A stimulated NBT reduction more than 5-fold in FPMC compared to the control. With addition of TST, lectin stimulated ROS to lesser extent than that with lectin alone. When catalase, TST, and lectin were added into the FPMC simultaneously, ROS increase was similar to that under lectin treatment alone. On the whole, data obtained indicated that ROS generation in holothurian coelomocytes especially occurs in both stimulated and not stimulated phagocytes, and that changes in ROS production by these cells may be one of the mechanisms of antibacterial protection of holothurians. 相似文献