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951.
M. N. Das 《Geotechnical and Geological Engineering》1986,4(1):79-87
Conclusions The post-failure slope immediately after strength failure decreases on the negative side with the increase inw/h ratio. Atw/h equal to around 10 or 11 this slope becomes almost zero and then again the slope increases but on the positive side with further increase inw/h ratio.At loww/h ratios, the post-failure characteristic touches the abscissa ultimately. Forw/h greater than 4 or 6 after an initial fall, the broken mass starts reconsolidation on further loading due to high lateral constraints provided at the centre and the curve starts rising again. Forw/h ratios greater than 10 or 11, there is no loss in the post-failure strength. 相似文献
952.
Hydrogenolysis with rhodium-on-charcoal was found to be an effective method for degrading different types of macromolecular material of geological origin. Between 6 and 70% of coals, kerogens and humic substances were transferred into low-molecular-weight soluble materials. The reaction products contained a series of monomeric and dimeric lignin-derived compounds which strongly suggest intact fossil lignin as their source. The substitutional patterns of the released phenols reflect the type and amount of terrestrial organic matter input and diagenetic alterations.In addition to the lignin constituents, a complete suite of hydrocarbons differing from those of the low-molecular-weight fraction was obtained after hydrogenolysis of the sample material. Hydrocarbons released by the hydrogenolytic degradation technique were attached to the polymeric matrix as monoor polyethers. Deuterium was used in the degradation experiment to evaluate the sites of chemical bonds by which 4-methylsteranes and hopanes are attached to the kerogen matrix. These experiments suggested a linkage of the released molecules with ring A and the side-chain, respectively. 相似文献
953.
Summary The objective of this study is to determine the parameters which influence coal's mechanical behaviour. The two coals examined (HBL, Simon, France and Barro Banco, Brazil) structurally originated from different deposits. The differences are readily explained by the contrasting composition of vitrain, clarain, durain and fusain. Their mechanical behaviour is linked to their petrographical composition. The Lorrainain coal behavioural pattern was evaluated. It is elastobrittle or elastoplastic with progressive failure. Brazilian coal behaves according to a pattern of elastoplastic with progressive failure or perfect elastoplastic. 相似文献
954.
The sources of reservoired liquid hydrocarbons in Australia differ substantially from their Northern Hemisphere counterparts. Not only are Australian source rocks largely of terrigenous origin but the concepts accepted as defining the hydrocarbon potential of source rocks have recently been challenged. Although isotopic measurements on Australian source rocks and liquid hydrocarbon products closely parallel those published from elsewhere, new interpretations of these data have been made, particularly with regard to D/H ratios in coals. As interesting as such results may be, the most important findings relate to the origins and histories of methane, the higher gaseous hydrocarbons and carbon dioxide, and the interpretation of these data in terms of hydrocarbon genesis. Simple Northern Hemisphere concepts which characterize gases as being biogenic, oil-associated, etc., on the bases of their isotopic and chemical compositions are clearly not applicable to the Australian scene. Indeed justification of such precise classifications in the Northern Hemisphere on the available evidence is also questioned.Isotopic and compositional data from gases from the Cooper, Bowen, Sydney and Gippsland Basins and from the North West Shelf (Australia) are reviewed, and assessed in terms of generation pathways. 相似文献
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燃煤过程中氯氟烃的产生和释放 总被引:6,自引:0,他引:6
用静态去除燃煤产生的CO2气体,经冷阱两步浓缩,气相色谱-质谱对燃煤产生的烟气样品进行了检测,近100种物质被检测出,其中,二氟二氯甲烷与当地大气背景相比呈显著异常.随着燃烧温度的变化,二氟二氯甲烷具规律性变化,当燃炉温度达到400℃左右时,氟里昂释放达到峰值.燃煤过程中,二氟二氯甲烷含量变化表现出与氯甲烷有明显的正相关关系,表明氟里昂的生成同氯甲烷有着密切的内在联系.除了氟里昂外,燃煤过程中产生的氯甲烷对大气环境的影响也不容忽视. 相似文献
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