Nodular monazite from placers in the Kular Ridge (Arctic Siberia,Russia): Composition and age

Nodular monazite occurs in metamorphic rocks worldwide and has zonal REE patterns. This paper focuses on the composition of nodular monazite hosted by Permian black shales of the Kular Ridge in the Kular-Nera terrane. This monazite variety (called kularite in the Russian literature) reaches commercial amounts in placers of the area. The contents of Ce, Nd, and La in the analyzed monazite nodules show correlations at Ce/Nd = 14.39La + 0.0919 (in apfu) and Ce/Nd = 0.2318La + 0.1135 (in wt.%) and vary regularly from core to rim. All monazite compositions fall on this trend, but specific grains may plot in its different parts. Thermodynamic calculations indicate that monazite forms via an intermediate precursor (LnPO₄·2H₂O). The Ce:La:Nd changes in different grains record Eh-pH variations during nucleation and a gradual temperature increase during subsequent growth. The Ce:La:Nd ratio changes partly in grain rims as a result of oxidative dissolution. Judging by the tectonic setting, REE came to the Kular-Nera rocks from the weathered Tomtor Nb-REE deposit, being transported by the Paleo-Khatanga River with monazite nanoparticles bound to the surface of clay minerals.     

Rutile R632 – A New Natural Reference Material for U‐Pb and Zr Determination

A new natural rutile reference material is presented, suitable for U‐Pb dating and Zr‐in‐rutile thermometry by microbeam methods. U‐Pb dating of rutile R632 using laser ablation ICP‐MS with both magnetic sector field and quadrupole instruments as well as isotope dilution‐thermal ionisation mass spectrometry yielded a concordia age of 496 ± 2 Ma. The high U content (> 300 μg g^?1) enabled measurement of high‐precision U‐Pb ages despite its young age. The sample was found to have a Zr content of 4294 ± 196 μg g^?1, which makes it an excellent complementary reference material for Zr‐in‐rutile thermometry. Individual rutile grains have homogeneous compositions of a number of other trace elements including V, Cr, Fe, Nb, Mo, Sn, Sb, Hf, Ta and W. This newly characterised material significantly expands the range of available rutile reference materials relevant for age and temperature determinations.     

辽西北票(金-羊)盆地北票组层序地层及沉积体系特征

为揭示北票(金-羊)盆地内北票组层序地层特征及沉积体系分布规律,应用层序地层学及沉积学理论和方法,综合利用野外露头、剖面等资料,建立了北票(金-羊)盆地北票组的层序地层格架,确定研究区的沉积相类型及分布规律。研究结果表明,北票(金-羊)盆地北票组可划分为2个三级层序,其内部可进一步划分为7个准层序组。在层序内识别出冲积扇、辫状河三角洲、湖泊3个沉积相。明确了沉积相的分布规律,向上形成由冲积扇到辫状河三角洲,再到湖相,最后是辫状河三角洲的沉积体系;平面上呈近北西—南东向展布的沉积体系,整体构成2个水进、水退的沉积体系。古地貌影响了底部冲积扇相沉积物的沉积特征。气候不仅影响了沉积物类型,且和湖平面变化共同控制了沉积物的演化规律。     

Effect of 2D spatial variability on slope reliability: A simplified FORM analysis

To meet the high demand for reliability based design of slopes, we present in this paper a simplified HLRF(Hasofere Linde Rackwitze Fiessler) iterative algorithm for first-order reliability method(FORM). It is simply formulated in x-space and requires neither transformation of correlated random variables nor optimization tools. The solution can be easily improved by iteratively adjusting the step length. The algorithm is particularly useful to practicing engineers for geotechnical reliability analysis where standalone(deterministic) numerical packages are used. Based on the proposed algorithm and through direct perturbation analysis of random variables, we conducted a case study of earth slope reliability with complete consideration of soil uncertainty and spatial variability.     

Landfill site selection based on reliability concepts using the DRASTIC method and AHP integrated with GIS – a case study of Bengaluru city,India

The selection of landfill sites for municipal solid waste (MSW) disposal involves consideration of geological, hydrological and environmental parameters which exhibit large spatial variability. Therefore, it is necessary to define, to what extent the chosen sites are reliable such that the probability of environmental pollution and health risks to population is minimal. In the present study, groundwater vulnerability to contamination has been assessed using the standard DRASTIC method. The results showed that the study region has 9.45% of very less, 32.94% of less, 25.47% of moderate, 22.79% of high and 9.35% of very high vulnerable zones. The study also revealed that none of the landfills are located in safe zones. This suggests that it requires proper remedial measures to avoid environmental pollution. A landfill site selection process has been carried out using the Analytical Hierarchy Process integrated with Geographical Information System tools. The obtained results showed that only 3.59?km² (0.08%) of the total area is suitable for landfills. The reliability analysis of the site suitability revealed that landfills are located at unreliable locations where the probability of risk to environmental pollution is high. The presented approach assists decision-makers in selecting reliable locations for the safe disposal of MSW.     

西秦岭温泉—中川一带金属矿床的成矿规律及找矿预测

西秦岭温泉—中川一带实施的1:5万矿产地质调查项目,共圈定1:5万局部高磁异常33处,1:5万地球化学综合异常11处,发现矿点2处,矿化点5处,矿种有金、钼、铁、铜、铷等。通过分析研究区成矿地质条件、1:5万地球物理和地球化学综合异常特征、矿(化)点特征及分布规律等,阐明了该区成矿时空分布规律和矿产共生组合规律,划分成矿远景区9处,提交找矿靶区6处。对其中2处找矿靶区进行槽探验证的结果为: 关子镇幅玉杨观找矿靶区圈定了4条含铷矿化伟晶岩脉和多处铁矿化破碎蚀变带,具有形成伟晶岩型铷矿的潜力; 礼县幅李坝金矿床南侧百叶沟—河西沟找矿靶区圈定了14条蚀变破碎带,在矿化蚀变带内圈定了11条金矿(化)体,具有形成构造蚀变岩(微细粒浸染状)型金矿床的潜力。     

Multi-factor sensitivity analysis on the stability of submarine hydrate-bearing slope

There are many factors affecting the instability of the submarine hydrate-bearing slope (SHBS), and the interaction with hydrate is very complicated. In this paper, the mechanical mechanism of the static liquefaction and instability of submarine slope caused by the dissociation of natural gas hydrate (NGH) resulting in the rapid increase of pore pressure of gas hydrate-bearing sediments (GHBS) and the decrease of effective stress are analyzed based on the time series and type of SHBS. Then, taking the typical submarine slope in the northern South China Sea as an example, four important factors affecting the stability of SHBS are selected, such as the degree of hydrate dissociation, the depth of hydrate burial, the thickness of hydrate, and the depth of seawater. According to the principle of orthogonal method, 25 orthogonal test schemes with 4 factors and 5 levels are designed and the safety factors of submarine slope stability of each scheme are calculated by using the strength reduction finite element method. By means of the orthogonal design range analysis and the variance analysis, sensitivity of influential factors on stability of SHBS are obtained. The results show that the degree of hydrate dissociation is the most sensitive, followed by hydrate burial depth, the thickness of hydrate and the depth of seawater. Finally, the concept of gas hydrate critical burial depth is put forward according to the influence law of gas hydrate burial depth, and the numerical simulation for specific submarine slope is carried out, which indicates the existence of critical burial depth.     

Petrogenesis of the microcrystalline-dioritic enclaves from Jiuling granitoids in the eastern segment of Jiangnan Orogen and constraints on magma source materials

Numerous dark enclaves with different shapes are found in Jiuling Neoproterozoic granitoids. Precise LA-ICP-MS U-Pb dating was conducted on zircons extracted from two microcrystalline enclave samples, yielding crystallization ages of 822.6±5.8 Ma and 822.2±6.2 Ma, respectively. The consistent ages within analytical errors with the host granitoids suggested that they were the products of the same magmatism. The microcrystalline-dioritic enclaves commonly show plastic forms and contain similar plagioclase megacrysts to the host rocks, and both of the enclaves and host granitoids showed a complex composition and structural imbalance in plagioclases. Furthermore, the apatites with a euhedral acicular shape occurred widely in the microcrystalline-dioritic enclaves. All of these petrographic features above imply magma mixing is involved in their diagenesis. The enclaves and host granitoids show a marked zircon trace element difference and Hf isotopic signatures without correlation in zircon trace element pairs but form their own system between enclaves and host granitoids. Additionally, most of the zircons show extremely high ε_Hf (t) with ε_Hf (t) =3.54–11.94 from the southern samples, and ε_Hf (t) =1.0–9.09 from the central region. Some zircons with the higher ε_Hf (t) are similar to the zircons from the juvenile island arc in the eastern segment of Jiangnan Orogen. Integrated geological and Hf isotopic characteristics suggest microcrystalline-dioritic enclaves were derived from the partial melting process of the Mesoproterozoic crust which enriched juvenile island arc materials and mixed with the granitic magma that remelted from the Mesoproterozoic continental crust which relatively enriched ancient sediments and mixed with the host granitoid in diagenesis.     

Origin of natural sulfur-metal chimney in the Tangyin hydrothermal field,Okinawa Trough: constraints from rare earth element and sulfur isotopic compositions

For the first time, we present the rare earth element (REE) and sulfur isotopic composition of hydrothermal precipitates recovered from the Tangyin hydrothermal field (THF), Okinawa Trough at a water depth of 1206 m. The natural sulfur samples exhibit the lowest ΣREE concentrations (ΣREE= 0.65×10^–6–4.580×10^–6) followed by metal sulfides (ΣREE=1.71×10^–6–11.63×10^–6). By contrast, the natural sulfur-sediment samples have maximum ΣREE concentrations (ΣREE=11.54×10^–6–33.06×10^–6), significantly lower than those of the volcanic and sediment samples. Nevertheless, the δEu, δCe, (La/Yb)_N, La/Sm, (Gd/Yb)_N and normalized patterns of the natural sulfur and metal sulfide show the most similarity to the sediment. Most hydrothermal precipitate samples are characterized by enrichments of LREE (LREE/HREE=10.09–24.53) and slightly negative Eu anomalies or no anomaly (δEu=0.48–0.99), which are different from the hydrothermal fluid from sediment-free mid-oceanic ridges and back-arc basins, but identical to the sulfides from the Jade hydrothermal field. The lower temperature and more oxidizing conditions produced by the mixing between seawater and hydrothermal fluids further attenuate the leaching ability of hydrothermal fluid, inducing lower REE concentrations for natural sulfur compared with metal sulfide; meanwhile, the negative Eu anomaly is also weakened or almost absent. The sulfur isotopic compositions of the natural sulfur (δ³⁴S=3.20‰–5.01‰, mean 4.23‰) and metal sulfide samples (δ³⁴S=0.82‰–0.89‰, mean 0.85‰) reveal that the sulfur of the chimney is sourced from magmatic degassing.     

The geothermal formation mechanism in the Gonghe Basin: Discussion and analysis from the geological background

The Gonghe Basin, a Cenozoic down-warped basin, is located in the northeastern part of the Qinghai-Xizang (Tibetan) Plateau, and spread over important nodes of the transfer of multiple blocks in the central orogenic belt in the NWW direction. It is also called “Qin Kun Fork” and “Gonghe Gap”. The basin has a high heat flow value and obvious thermal anomaly. The geothermal resources are mainly hot dry rock and underground hot water. In recent years, the mechanism of geothermal formation within the basin has been controversial. On the basis of understanding the knowledge of predecessors, this paper proposes the geothermal formation mechanism of the “heat source–heat transfer–heat reservoir and caprock–thermal system” of the Gonghe Basin from the perspective of a geological background through data integration-integrated research-expert, discussion-graph, compilation-field verification and other processes: (1) Heat source: geophysical exploration and radioisotope calculations show that the heat source of heat in the basin has both the contribution of mantle and the participation of the earth’s crust, but mainly the contribution of the deep mantle. (2) Heat transfer: The petrological properties of the basin and the exposed structure position of the surface hot springs show that one transfer mode is the material of the mantle source upwells and invades from the bottom, directly injecting heat; the other is that the deep fault conducts the deep heat of the basin to the middle and lower parts of the earth’s crust, then the secondary fracture transfers the heat to the shallow part. (3) Heat reservoir and caprock: First, the convective strip-shaped heat reservoir exposed by the hot springs on the peripheral fault zone of the basin; second, the underlying hot dry rock layered heat reservoir and the upper new generation heat reservoir and caprock in the basin revealed by drilling data. (4) Thermal system: Based on the characteristics of the “heat source-heat transfer-heat reservoir and caprock”, it is preliminarily believed that the Gonghe Basin belongs to the non-magmatic heat source hydrothermal geothermal system (type II2₁) and the dry heat geothermal system (type II2₂). Its favorable structural position and special geological evolutionary history have given birth to a unique environment for the formation of the geothermal system. There may be a cumulative effect of heat accumulation in the eastern part of the basin, which is expected to become a favorable exploration area for hot dry rocks.