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61.
钽钼杂多酸—碱性染料多元缔合物体系的研究 总被引:1,自引:0,他引:1
在PVA、OP或Tween-60存在下,采用平衡移动法确定了碱性染料亚甲基蓝、耐尔蓝(NB)、罗丹明B(RB)、丁基罗丹明B(BRB)、结晶紫(CV)、乙基紫(EV)与Ta的摩尔比是1:1至7:1;考察了NB(或BRB)-钽钼杂多酸缔合物的红外光谱,初步探讨了反应机理:比较了几个碱性染料-钽钼杂多酸缔合物体系的光度特性,筛选出两个摩尔吸光系数>2×10~6的分析体系,并用于合金钢和地质标样中痕量Ta的测定,方法可行。 相似文献
62.
本文综述指出:深部过程,可能导致放射性元素在地幔或下地壳的某些部位聚结而产生强烈的核反应,致使下地壳加热和上地壳的快速抬升和伸展垮塌,产生地震、火山作用、岩浆作用,形成山脉。通过对来自地球内部的α─粒子辐射监测,有可能对毁灭性地震作出预报。 相似文献
63.
非接触极化曲线视反应电位差区分矿体矿物成分及确定其边界的实验研究 总被引:2,自引:0,他引:2
本文用非接触极化曲线视反应电位差区分矿体矿物成分和确定矿体边界的基本原理,着重阐述矿物非接触极化曲线视反应电位差特征的实验研究方法和结果,并指出非接触极化曲线视反应电位差区分矿体矿物成分和确定矿体边界是有可能的。 相似文献
64.
Numerical study of the oxidation process of dimethylsulfide in the marine atmosphere 总被引:1,自引:0,他引:1
A box model, involving simple heterogeneous reaction processes associated with the production of non-sea-salt sulfate (nss-SO
4
2–
) particles, is used to investigate the oxidation processes of dimethylsulfide (DMS or CH3SCH3) in the marine atmosphere. The model is applied to chemical reactions in the atmospheric surface mixing layer, at intervals of 15 degrees latitude between 60° N and 60° S. Given that the addition reaction of the hydroxyl radical (OH) to the sulfur atom in the DMS molecule is faster at lower temperature than at higher temperature and that it is the predominant pathway for the production of methanesulfonic acid (MSA or CH3SO3H), the results can well explain both the increasing tendency of the molar ratio of MSA to nss-SO
4
2–
toward higher latitudes and the uniform distribution with latitude of sulfur dioxide (SO2). The predicted production rate of MSA increases with increasing latitude due to the elevated rate constant of the addition reaction at lower temperature. Since latitudinal distributions of OH concentration and DMS reaction rate with OH are opposite, a uniform production rate of SO2 is realized over the globe. The primary sink of DMS in unpolluted air is caused by the reaction with OH. Reaction of DMS with the nitrate radical (NO3) also reduces DMS concentration but it is less important compared with that of OH. Concentrations of SO2, MSA, and nss-SO
4
2–
are almost independent of NO
x
concentration and radiation field. If dimethylsulfoxide (DMSO or CH3S(O)CH3) is produced by the addition reaction and further converted to sulfuric acid (H2SO4) in an aqueous solution of cloud droplets, the oxidation process of DMSO might be important for the production of aerosol particles containing nss-SO
4
2–
at high latitudes. 相似文献
65.
66.
新疆黄山杂岩体矿物学特征及其意义 总被引:1,自引:0,他引:1
黄山杂岩体造岩矿物有橄榄石、斜方辉石、单斜辉石、斜长石、角闪石和黑云母。其中斜方辉石的多色性不是由Fe~(2+)引起,而是由Ti~(4+)引起。单斜辉石结晶后常与岩浆继续发生化学反应,形成一种岩浆岩结构——角闪反应补丁结构。橄榄石中镍含量的亏损程度反映杂岩体曾经历过硫化物熔离作用。单斜辉石Si,Al~Ⅳ,Ti的变化表明杂岩体属于拉斑玄武岩系列。超镁铁岩中K,Ba,Th,Hf等元素反常的地球化学行为是由该岩石中黑云母矿物引起。 相似文献
67.
The Palghat Gap region is located near the centre of the large southern Indian granulite terrane. at the northern edge of the Kodaikanal charnockite massif. The dominant rock types in the region are hornblende-biotite ± orthopyroxene gneisses and charnockites along with minor amounts of intercalated mafic granulite, metapelite and calc-silicate. The P-T estimates from garnetiferous mafic granulites and metapelite samples are generally in the range 9-10 kbar and 800-900 C using both conventional thermobarometric methods and the TWEEQU thermobarometry program. These P-T estimates, which should be taken as minimum values, are among the highest yet reported for South Indian and Sri Lankan granulites. The occurrence of orthopyroxene + plagioclase symplectites around embayed garnet grains in the mafic granulites and cordierite rims around garnet grains in metapelite suggest an isothermal decompression-type path. Similarly, a core-rim P-T trajectory indicates c. 3 and 7 kbar decompression at high temperature in the mafic granulites and metapelite, respectively. In both rock types, the key to the determination of the retrograde P-T path was the recognition of small amounts of second generation plagioclase with a more anorthitic composition than the matrix plagioclase. The preservation of high garnet-pyroxene temperatures in the mafic granulites (despite small garnet grain size) suggests rapid cooling of the terrane. Calculated minimum cooling rates range from 8 to 80 C Ma-1 . Such cooling rates are more rapid than those associated with normal isostatic processes and suggest that the terrane was tectonically exhumed at high temperature. 相似文献
68.
69.
A statistically relevant correlation between the reaction rate coefficient, k
OH, for the OH radical reaction with 161 organic compounds in the gas phase at 300 K, and the corresponding vertical ionisation energies E
i,v, reveals two classes of compounds: aromatics where –log(k
OH/cm3s-1)3/2E
i,v(eV)–2 and aliphatics where –log(k
OH/cm3s-1)4/5E
i,v(eV)+3. The prediction of the rate coefficient, k
OH, for the reaction of OH with organic molecules from the above equations has a probability of about 90%. Assuming a global diurnal mean of the OH radical concentration of 5×105 cm3, the upper limit of the tropospheric half-life of organic compounds and their persistence can be estimated. 相似文献
70.
The chemistry of glycolaldehyde (hydroxyacetaldehyde) relevant to the troposphere has been investigated using UV absorption spectrometry and FTIR absorption spectrometry in an environmental chamber. Quantitative UV absorption spectra have been obtained for the first time. The UV spectrum peaks at 277 nm with a maximum cross section of (5.5± 0.7)×10–20 cm2 molecule–1. Studies of the ultraviolet photolysis of glycolaldehyde ( = 285 ± 25 nm) indicated that the overall quantum yield is > 0.5 in one bar of air, with the major products being CH2OH and HCO radicals. Rate coefficients for the reactions of Cl atoms and OH radicals with glycolaldehyde have been determined to be (7.6± 1.5)×10–11 and (1.1± 0.3)×10–11 cm3 molecule–1 s–1, respectively, in good agreement with the only previous study. The lifetime of glycolaldehyde in the atmosphere is about 1.0 day for reaction with OH, and > 2.5 days for photolysis, although both wet and dry deposition should also be considered in future modeling studies. 相似文献