菱刈矿床矿脉群形成的构造环境

本文主要介绍菱刈矿床矿脉的赋存状态、裂隙体系分析、矿脉群赋存的构造环境。菱刈矿床属脉状浅成热液型金银矿床。矿床成因与裂隙系统的形成关系密切。矿脉群大致位于基底岩石(四万十层群)隆起的中央部位。     

海洋平台隔水套管群桩性状的研究

海洋平台的隔水套管群桩与土共同作用研究是一个很复杂的课题,目前国内外研究资料甚少,因此在平台导管架设计中,一般不考虑隔水套管群桩承受水平力作用,这与实际不相符合。本文结合工程课题,在调查研究和模型试验的基础上,对隔水套管群桩在水平力作用下的工作性状与破坏机理、群桩的水平力及其主要影响因素、单桩与群桩情况下应力应变关系等方面进行较深入的研究;并提出砂土地基隔水套管群桩效应经验公式,弥补了现行计算方法的缺陷和不足。研究成果可供工程设计参考使用。     

Primary Product Distributions from the Reaction of OH with m-, p-Xylene, 1,2,4- and 1,3,5-Trimethylbenzene

A study was conducted to examine the OH-initiated degradation products of the four title compounds in the presence of sub-part-per-million levels of NO_x. The oxidation was conducted in a dynamic reactor to minimize the conversion of the aromatic compounds. The experiments were designed to represent reaction pathways that occur in the atmosphere at ambient NO₂ concentrations. A wide range of ring-retaining and ring-cleavage products having widely varying yields were measured during the study. For m-xylene, the major primary products observed (with molar yields) were methyl glyoxal (0.40), 4-oxo-2-pentenal (0.12), glyoxal (0.079), and m-tolualdehyde (0.049). For p-xylene, the major primary products were p-tolualdehyde (0.103), 2,5-dimethylphenol (0.13), cis-3-hexene-2,5-dione (0.176), trans-3-hexene-2,5-dione (0.045), 2-methyl-butenedial (0.071), glyoxal (0.394), and methylglyoxal (0.217). Several other reaction products were measured at yields less than 3%. The primary products for OH + 1,2,4-trimethylbenzene were found as follows: methylglyoxal (0.44), glyoxal (0.066), cis-3-hexene-2,5-dione (0.13), trans-3-hexene-2,5-dione (0.031), biacetyl (0.114), 3-methyl-3-hexene-2,5-dione (0.079), and 2-methyl-butenedial (0.045). Six other (ring retaining) products were measured at yields less than 3%. The primary products for OH + 1,3,5-trimethylbenzene were methylglyoxal (0.90), 3-methyl-5-methylidene-5(2H)-furanone (0.1), 3,5-dimethyl-3(2H)-2-furanone (0.1), 3,5-dimethyl-5(2H)-2-furanone biacetyl (0.08), and 2-methyl-4-oxo-2- pentenal (0.05). Three other products were detected at molar yields less than 5%. In some cases, the yields for the ring fragmentation products could only be based on calibrations from surrogate compounds. Yields for several of the unsaturated dicarbonyl compounds have not been reported previously while yields for methylglyoxal, glyoxal, and biacetyl are largely consistent with previous reports. Some of the primary furanone products are the identical to those reported as secondary products in aromatic systems.     

蒙皂石伊利石化反应机理和框架性行为模式

对珠江口盆地两口钻井95个泥质岩样粘土矿物X衍射分析资料的定量研究表明,若反应是以消耗蒙皂石为代价形成伊利石,则反应符合溶解-沉淀机理,但除此以外,蒙皂石还可以净溶解或新增伊利石层的方式加大I/S比。蒙皂石在渐进成岩过程中的框架性行为模式具有三级控制,按顺序分别由温度、基本离子成分和动力学因素控制特定温度段内蒙皂石行为过程的起始和终结、行为过程的方式和行为过程的速率和程度。渐进成岩过程中I/S比的变化主要与第三级控制有关,而游离状蒙皂石和伊-蒙混层粘土的含量变化则是第二三两级共同控制的结果。     

金属矿物的反应动力学与地球化学意义

概述了动力学实验的技术方法和金属矿物的反应动力学研究进展。动力学实验使用的三种基本化学反应装置是间歇反应器（ＢＲ）、活塞流反应器（ＰＦＲ）和混合流反应器（ＭＦＲ）,确定速率定律的数学方法包括积分法、微分法和混合法,以微分法中的初始速率法应用最广。目前主要研究了水溶液中黄铁矿氧化、黄铁矿和黄铜矿形成、晶质铀矿和磁铁矿溶解的速率定律和反应机理,发现：（１）酸性溶液中黄铁矿的氧化速率对Ｆｅ３＋和Ｏ２浓度呈分数依赖并受表面反应的控制;（２）低于３００℃时黄铁矿不能从溶液中直接成核,而需初始地通过ＦｅＳ先驱物的硫化生成,ＦｅＳ与Ｈ２Ｓ反应形成黄铁矿的速率方程为二级;（３）磁黄铁矿或黄铁矿与Ｃｕ２＋反应均可形成黄铜矿,前者经历了一系列准稳的Ｃｕ Ｆｅ硫化物的中间物,后者的速率方程为表观一级并受表面反应的控制;（４）酸性ｐＨ时磁铁矿的非线性溶解行为可采用表面反应扩散输运耦合的收缩核模型（ＳＣＭ）来描述。有关动力学实验成果完善和深化了对矿床中黄铁矿、黄铜矿的形成机理和风化壳中磁铁矿的稳定性等方面的认识。将来的实验研究将向更多的金属矿物和高温高压领域发展。     

Multi-stage pseudomorphic replacement of garnet during polymetamorphism: 2. Algebraic analysis of mineral assemblages

Chemical relationships among four metapelites have been studied by investigation of mineral and bulk chemistry data and by singular value decomposition analysis of single and composite assemblage matrices. Bulk rock compositions cluster close together in an AFM diagram, all within the intersection space defined by the four sample assemblages. The similarity of bulk compositions normalized on a silica-free, anhydrous basis indicates that sample chemistries differ mainly as a result of inhomogeneous distribution of quartz layers. The existence of mass balance relationships among samples indicates that assemblages also overlap in the Si–Ti–Al–Fe–Mg–Mn–Ca–Na–K multisystem. Analysis of single and composite matrices helps in defining possible mass balances linking sample mineral facies to one another during progressive contact metamorphism. The assemblage in sample A can form as the result of the model reaction 5.000  Ky+0.269 Grt+0.965 Bt+0.314 Pl=0.049 Ilm+1.115 Ms+0.849 Chl+0.306 St and react to assemblage B via reaction 0.97 Chl+0.52 Grt+0.66 Ms+0.14 Ilm+1.26  Ky=0.42 St+0.63 Bt+0.22 Pl coupled with the Ky→And transition. Assemblage B can transform into C by initial progress of Ky+Ilm+Chl+Grt+Ms=And+St+Bt+Pl followed by 0.142 Ilm+0.175 St+1.089 Chl+1.533 Ms+0.003 Grt=5.000 And+1.266 Bt+0.551 Pl Matrix analysis cannot satisfactorily model the C–D transition, because it predicts a net production of staurolite, which is in disagreement with petrographic evidence. All mass balances in the C–D composite matrix indicate net consumption of muscovite; this is integrated with the contrasting evidence of prograde pseudomorphs of muscovite after staurolite, observed in the nodules of sample D, within a model involving the progress of ionic reaction cycles.     

M_(S(BB))、M、M_(S7)震级对比

选取2009—2015年内蒙古测震台网速报的46个M≥4.1地震,依据《地震震级的规定》(GB17740—2016)中关于量取地震宽频带面波震级M_(S(BB))的各项条款,重新量取M_(S(BB)),与中国地震台网中心编目结果产出的M震级和M_(S7)震级进行对比分析,结果显示:M_(S(BB))震级与M_(S7)震级的一致性较好。     

水下多路液压快速接头的夹头结构分析与优化

深海油气田水下生产系统装备之间的精准连接是国际公认的技术难题,对接一般通过深海连接器完成。弹性夹头是水下连接器的重要组成部分,其性能关系到海洋油气生产系统的安全性和可靠性。弹性夹头的主要作用是在水下机器人的辅助下连接和锁紧连接器的固定端和移动端。采用ABAQUS软件的显式动力学分析模块计算夹头夹紧心轴这一过程中的应力、反作用力状态。三维模型仿真结果表明,锁紧过程中弹性夹头的最大应力不超过430 MPa,小于所选取的材料屈服强度480 MPa。采用正交试验和方差分析的方法研究夹头的长度、夹头与心轴的间隙等几个关键尺寸从而分析影响夹头应力和连接所需推力的最显著因素。对夹头的结构进行优化设计,同时也为夹头心轴结构的设计提供了理论依据。最后,通过试验研究对样机进行测试,测试结果表明,夹紧动作所需的最大推力在700 N以下。     

吉林测震台网地震记录仿真前后震级对比分析

选取2013-2017年吉林测震台网记录的部分地震,按测震台网运行管理细则对地震编目的要求,需对地震波形进行WA仿真处理后测量震级。对比仿真前后震级,发现仿真后量取的震级普遍较大,偏差在0.3以内。因此,地震编目需严格按照细则执行,地震速报使用仿真震级更加准确,而且掌握震级偏差可为新旧震级资料的连续性提供参考依据。     

碱煮法:一种制备海洋浮游生物PCR模板DNA的实用方法

介绍了一种制备海洋浮游生物PCR模板DNA的方法——碱煮法。取少量海水样品(40μL)．直接经0．25mol／L艺机NaOH和99℃温育处理裂解细胞,从而得到环境样品总DNA。实验证明,该方法制备的模板DNA可用于细菌核糖体RNA、浮游植物叶绿体rbcL和浮游动物线粒体COI等基因的PCR扩增。但是,在使用通用引物扩增细菌基因时,假阳性很难避免。该法制备的模板DNA适用于扩增非细菌基因或者特异引物界定的细菌基因。该方法较传统制备方法快速、简便,样品需要量减少,适用于浮游生物分子遗传多样性研究。