甘肃省龙首山芨岭铀矿床成矿热液流体特征研究

芨岭铀矿是中国北方最典型的钠交代型铀矿床之一,文章通过对芨岭矿床ZKJ9-4钻孔深部所见含矿蚀变闪长岩、近矿蚀变闪长岩、远矿蚀变闪长岩、闪长岩原岩地球化学特征和组分迁移计算及矿体中心部位的淡粉红色方解石脉流体包裹体特征、均一温度、盐度和激光拉曼光谱研究,认为芨岭钠交代型铀矿床的成矿流体含有大量碳酸铀酰络合物[UO_2(CO_3)_2]~(2–)和[UO_2(CO_3)_2]~(4–)的同时还含有丰富的SiO_2、Na~+、Ca~(2+)、Mg~(2+)、Fe~(2+)、Mn~(2+)、∑REE、U、Th、Ga、Sr、Zr、Ba、Rb、Nb、Mo、Cd、Sn、Hf、Ti、Ta、CO_2、H_2S和CH_4等组分,成矿流体具有较强的还原性,并对MnO、K_2O、Cr和Co具有较强的交代溶蚀作用。成矿流体是起源于岩浆演化晚期的再平衡岩浆水,热液温度为(300±20)℃,盐度为2.99 wt%~4.57 wt%NaCl,密度为0.75~0.77 g/cm~3。流体沸腾是芨岭钠交代型铀矿成矿物质的早期卸载机制,晚期成矿流体中加入了大量的大气降水,流体混合作用进一步促进了成矿物质的卸载。     

特提斯喜马拉雅铅锌锑金成矿带含炭质岩石中热液脉型矿床的综合电法勘探——以西藏扎西康铅锌锑多金属矿为例

扎西康铅锌锑多金属矿床产出于特提斯喜马拉雅炭质板岩的断裂带内,是特提斯喜马拉雅铅锌锑金成矿带内典型的热液脉型矿床。由于含炭质岩石和金属硫化物都呈现出相似的低阻高极化电性特征,加之热液脉型矿床的矿体普遍较小,使得在含炭质岩石中对金属硫化物矿体进行电法勘探存在较大困难。本文通过对扎西康矿床已知矿体的音频大地电磁测深和激电中梯测量,发现矿区的炭质板岩呈现低电阻率(10^-0.4~10⁰Ω·m)和高极化率(9%~20%)特征,而矿体呈现出高电阻率(10²~10³Ω·m)和低极化率(1%~5%)的特征。经研究分析,认为造成这种现象的原因有两方面：(1)扎西康炭质板岩中的炭质物质量分数平均为0.79%,变质温度约在300±25℃~340±25℃,炭质物电阻率为6.1×10^-5~6.8×10^-4Ω·m,显示极好的导电性;此外,炭质板岩中存在大量黏土矿物,黏土矿物的吸水性促进了炭质物的连通性,因此炭质物高导电性与连通性的耦合使得炭质板岩呈现低阻高极化电性特征;(2)扎西康矿床的脉型矿体除包含金属硫化物外,还产出大量的脉石矿物,脉石矿物普遍具有高阻低极化电性特征,是造成整个矿体在炭质板岩中呈现高阻低极化异常的根本原因。据此,本文提出在炭质板岩中通过识别脉石矿物引起的高阻低极化异常带间接找矿的新思路,相应的技术方法组合为：利用激电中梯测量定位高阻低极化带的平面位置,再利用音频大地电磁测深探测其深部产状。     

北京市怀柔区北干沟金矿床与韧性剪切带的关系

北干沟金矿床是韧性剪切带含金石英脉型金矿床。韧性剪切带以发育糜棱岩和片理化带为特征,应变强度和退化变质作用从边缘到中心逐渐增强,并形成鞘褶皱;韧性构造岩具有分带性;产于韧性剪切带中心部位的石英脉是主要的含金脉体;韧性剪切带的形态、活动阶段及韧性剪切变质岩的分带性对金矿具有明显的控制作用。     

栖霞市马家窑金矿床成矿流体地球化学特征

马家窑金矿床是胶东地区比较典型的石英脉型金矿床代表,属中低温热液矿床,成矿流体盐度较低,气相成分以H2O,CO2为主,其次是Na^＋,Ca^＋和Cl^-,K^＋和F^-较贫,流体的成分与大气降水热液相类似。成矿流体的H,O同位素值则反映大气降水在不同温度和不同水／岩值条件下与栖霞超单元回龙夼单元交换后的分布特征,认为马家窑金矿床的成矿热液属大气降水成因。     

赣中聚源大型石英脉型白钨矿床含铀富钨矿物初步研究

聚源钨矿是华南地区为数不多的大型石英脉型白钨矿矿床之一.在详细的野外地质调查基础上,本文利用α径迹蚀刻、电子显微镜、扫描电镜以及电子探针等实验手段,对该矿床含钨和含铀矿物开展了精细矿物学的研究工作,探讨了成矿过程中钨和铀的富集规律.研究显示,该矿床钨铀矿物的形成可分为四个阶段:第一阶段,钨铀主要进入富含Nb、Ti的氧化...     

赣南合龙钨矿矿床地质、成岩成矿时代与成矿模式

合龙钨矿床位于南岭东西向构造岩浆带与北-北东向于山构造带交汇部位,是南岭东段于都-赣县矿集区的重要组成.合龙钨矿床是赣南地区近年在石英脉型钨矿勘查取得最重要突破的矿区,新发现钨多金属矿体达48条,新探明黑钨矿资源量3.5万余吨,WO3平均品位2.189％,深部具有大型以上资源潜力.合龙钨矿床以外带石英大脉型矿体与岩体内...     

Antiangiogenic activity of low-temperature lysozyme from a marine bacterium <Emphasis Type="Italic">in vivo</Emphasis> and <Emphasis Type="Italic">in vitro</Emphasis>

We extracted marine low-temperature lysozyme (MLTL), a novel lysozyme, from a marine microorganism through fermentation. Our previous study suggested that a low molecular weight (16 kDa) may exert anti-tumor activity through antiangiogenesis. In this study, we extracted a high weight (39 kDa) and investigated its antiangiogenic activity in vivo and in vitro. Using zebrafish embryos as an in vivo study model, we found that treatment with MLTL significantly inhibited the growth of subintestinal vessels (SIVs) in a dose-dependent manner and that 400 μg/ml MLTL was sufficient to block the growth of SIVs. An in vitro study conducted using human umbilical vein endothelial cells (HUVECs) revealed that MLTL suppressed the proliferation, migration and tube formation of HUVECs in a dose-dependent manner. Interestingly, assays by flow cytometry and DNA electrophoresis indicated that MLTL was able to induce apoptosis of HUVECs. Moreover, further study demonstrated that the disruption of intracellular Ca²⁺ homeostasis may play an important role in MLTL induced apoptosis of HUVECs. Taken together, the results of this study demonstrate for the first time that MLTL inhibits angiogenesis through its pleiotropic effects on vascular endothelial cells and induces apoptosis through regulation of cellular Ca²⁺ levels. The results of this study also revealed a possible mechanism underlying the antiangiogenic effect of MLTL and suggested that MLTL may be a promising new antiangiogenic agent for use in cancer therapy.     

Nb–Ta fractionation induced by fluid‐rock interaction in subduction‐zones: constraints from UHP eclogite‐ and vein‐hosted rutile from the Dabie orogen,Central‐Eastern China

Niobium and Ta concentrations in ultrahigh‐pressure (UHP) eclogites and rutile from these eclogites and associated high pressure (HP) veins were used to study the behaviour of Nb–Ta during dehydration and fluid‐rock interaction. Samples were collected through a ～2 km profile at the Bixiling complex in the Dabie orogenic belt, Central‐Eastern China. All but one eclogite away from veins (EAVs) display nearly constant Nb/Ta ratios ranging from 16.1 to 19.2, with an average of 16.9 ± 0.8 (2 SE), similar to that of their gabbroic protolith from the Yangtze Block. Nb/Ta ratios of rutile from the EAVs range from 12.7 to 25.3 among different individual grains, with the average values close to those of the corresponding bulk rocks. These observations show that Nb and Ta were not significantly fractionated by prograde metamorphism up to eclogite facies when no significant fluid‐rock interaction occurs. In contrast, Nb/Ta ratios of rutile from eclogites close to veins (ECVs) are highly variable from 17.8 to 49.8, which are systematically higher (by up to 17) than those of rutile from the veins. These observations demonstrate that Nb and Ta were mobilized and fractionated during localized fluid flow and intensive fluid‐rock interaction. This is strongly supported by Nb/Ta zoning patterns in single rutile grains revealed by in situ LA‐ICP‐MS analysis. Ratios of Nb/Ta in the ECV‐hosted rutile decrease gradually from cores towards rims, whereas those in the EAV‐hosted rutile are nearly invariable. Furthermore, the vein rutile shows Nb/Ta zoning patterns that are complementary to those in rutile from their immediate hosts (ECVs), suggesting an internal origin for the vein‐forming fluids. The Nb/Ta ratios of such fluids evolved from low values at the early stage of subduction to higher values at later supercritical conditions with increased temperature and pressure. Quantitative modelling was conducted to constrain the compositional evolution of metamorphic fluids during dehydration and fluid‐rock interaction focusing on Nb–Ta distribution. The modelling results based on our proposed multistage fluid phase evolution path can essentially reproduce the natural observations reported in the present study.     

Element mobility during continental collision: insights from polymineralic metamorphic vein within UHP eclogite in the Dabie orogen

Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ¹⁸O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.