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11.
海洋沉积物中石英单矿物的化学分离 总被引:7,自引:1,他引:7
海洋沉积物中的石英作为陆源物质的标志性矿物,是古环境和古气候演化的信息载体,已成为古环境和古气候演化研究的重要替代指标.提供了改进了的化学分离海洋沉积物中石英单矿物的方法流程.在流程中的不同阶段可有效去掉全样中的生物组分、粘土矿物和长石等,取得海洋沉积物全样的总陆源矿物、石英+长石、石英的相对和绝对含量,通过计算可获得各种组分的通量,通过粒度分析可获得粒度数据.同一样品的17次重复实验表明,含量结果的平均相对误差仅为2.36%;显微镜和X射线衍射分析检查所分离出的石英纯度可达98%以上;激光粒度分析表明,化学试剂对石英的溶蚀作用不明显,不影响粒度分析结果. 相似文献
12.
Two distinct series of slumps deform the upper part of the sedimentary sequence along the continental margin of the Levant.
One series is found along the base of the continental slope, where it overlies the disrupted eastern edge of the Messinian
evaporites. The second series of slumps transects the continental margin from the shelf break to the Levant Basin. It seemed
that the two series were triggered by two unrelated, though contemporaneous, processes. The shore-parallel slumps were initiated
by basinwards flow of the Messinian salt, that carried along the overlying Plio-Quaternary sediments. Seawater that percolated
along the detachment faults dissolved the underlying salt to form distinctly disrupted structures. The slope-normal slumps
are located on top of large canyons that cut into the pre-Messinian sedimentary rocks. A layer of salt is found in the canyons,
and the Plio-Quaternary sediments were deposited on that layer. The slumps are bounded by large, NW-trending faults where
post-Messinian faulted offset was measured. We presume that the flow of the salt in the canyons also drives the slope-normal
slumps. Thus thin-skinned halokynetic processes generated the composite post-Tortonian structural patterns of the Levant margin.
The Phoenician Structures are a prime example of the collapse of a distal continental margin due to the dissolution of a massive
salt layer. 相似文献
13.
The seismic expression of a salt-filled channel which cuts across the Mid North Sea High in Quadrant 37 is described, with features interpreted as being produced by salt-edge dissolution forming both eastern and western margins of the channel. The apparent half-graben nature of the channel is shown to be only superficial, and due to complex faulting associated with, but not defining, its western margin. The shallower faulting here is a Mesozoic to early Tertiary growth fault related to local dissolution of Zechstein salt. The dissolution effect appears in turn to have been localized by the presence of a deeper fault that was already downthrown to the east in Zechstein times, when it seems to have limited the eastward progradation of Zechstein shelf carbonates and anhydrites, and had probably ceased to move significantly before the onset of the Late Cimmerian erosional phase. The origin of this arcuate fault is tentatively ascribed to subsidence around a granite batholith. Zechstein salt originally spread some distance to the east and west of the channel; it was dissolved from the edges inwards, mainly before the Late Cretaceous, giving rise to a thicker Mesozoic sequence on parts of the flanks of the channel than in the middle. Besides providing an interesting structural case history, the features described have implications regarding Zechstein sedimentation, reservoir potential, the tectonic history of the North Sea, and the nature of the Mid North Sea High itself. 相似文献
14.
15.
V.B. Vasilenko A.V. Tolstov V.A. Minin L.G. Kuznetsova N.V. Surkov 《Russian Geology and Geophysics》2008,49(12):894-907
The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO2–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds. 相似文献
16.
天然气溶解过程中组分分馏模型及其应用 总被引:1,自引:0,他引:1
天然气不同组分在水中溶解度的差异,导致溶解相与残留游离相天然气组分组成不同,即发生组分的溶解分馏效应。溶解分馏效应在天然气水溶运移、溶解散失等过程中均有发生。揭示天然气组分的溶解分馏规律、建立定量分馏模型,有助于天然气气源对比和成藏过程示踪。以Henry定律为依据,对不同组分溶解特征分析,提出了溶解度分数的概念,并建立了溶解分馏模型。根据该模型和各组分的溶解度分数和天然气溶解量,可计算各组分的溶解分馏量,恢复天然气初始组成特征。计算表明,威远震旦系气藏初期的天然气组成为:CH4为72.70%,C2H6为0.09%,CO2为22.41%,N2为4.07%,干燥系数(C1/C1-5)为99.876%。溶解作用使天然气中CO2含量显著降低,烃类气体含量增加,而天然气干燥系数降低。结果有助于天然气成因判识和气源对比等。 相似文献
17.
Rock magnetic record of Cenozoic lake sediments from the Linxia basin and aridification of the Asian inland 总被引:1,自引:0,他引:1
High resolution research of rock magnetic records and quartz sands from the Maogou Section in the Linxia basin reveals that
after a relatively stable environment between 13.07 Ma and 8.6 Ma, the basin was gradually influxed by eolian dusts at about
8.6 Ma, with two rapid increases at about 6.4 Ma and 5.3 Ma, respectively. The study suggests that drying of northwest China
began at 8.6 Ma and strengthened rapidly at about 6.4 Ma and 5.3 Ma.
__________
Translated from Marine geology & Quaternary geology, 2007, 27(4): 103–110 [译自: 海洋地质与第四纪地质] 相似文献
18.
The kinetics of conversion of iron(III) (hydr)oxides to ferrous iron mediated by fulvic acid have been investigated in order to improve the understanding of the redox cycling of iron at the oxic-anoxic boundary in natural waters. Under the conditions similar to natural waters, fulvic acid is able to reduce the iron(III) (hydr)oxide. The kinetics of the reaction depend on the reactivity of iron(III) (hydr)oxides and the reducing power of the fulvic acid. The rate of reaction is 60 nm/h obtained under following conditions: total concentration of Fe(III) 1.0 × 10–4 M, pH 7.5, fulvic acid 5 mg/L. The rate is considered as a net result of reduction and oxidation in the > FeIII-OH/Fe(II) wheel coupled with fulvic acid. In a real natural water system, reductants other than fulvic acid may be of importance. The results obtained in the laboratory, however, provide evidence that the Fe(OH)3(s)/Fe(II) redox couple is able to act as an electron-transfer mediator for the oxidation of natural organic substances, such as fulvic acid by molecular oxygen either in the absence of microorganisms or as a supplement to microbial activity. 相似文献
19.
The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO
–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge. 相似文献
20.