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991.
992.
993.
伊朗Y油田主力产层F油层属于典型的高温、高压、高产、有腐蚀性流体产出的油田。为了保障该油田的长效、高效、安全生产,需要对完井工艺及管柱保护进行防腐研究。采取完井时下入带封隔器的完井管柱,并在封隔器之上的油套环空注入防腐封隔液;室内对引进的2种环空封隔液体系进行了互溶性、高温稳定性、杀菌性等基础理化性能及对井下管材的腐蚀性的实验及评价。评价结果表明,CaCl2型环空封隔液高温稳定性较差,浸泡腐蚀速率值高值为0.062 mm/a,电偶腐蚀速率值高值为0.078 mm/a,均大于设定的腐蚀速率值0.05 mm/a。而引进的NaCl KCl型环空封隔液高温稳定性较好,浸泡腐蚀速率值高值为0.014 mm/a,电偶腐蚀速率值高值为0.037 mm/a,均低于设定的腐蚀速率值0.05 mm/a。鉴于此情况,对引进的CaCl2型环空封隔液进行改进并优化设计,确定合适的CaCl2型环空封隔液体系。优化设计后的CaCl2型环空封隔液高温稳定性良好,浸泡腐蚀和电偶腐蚀速率值均低于设定的腐蚀速率值,综合性能达到了现场应用要求。 相似文献
994.
谢家沟金矿床位于胶东隆起西北缘的焦家断裂带和招平断裂带之间。矿床赋存在中生代玲珑花岗岩体中,矿体主要受NNE向和NNW向断裂构造控制,主要呈脉状或透镜状产出。矿石矿物主要有黄铁矿、黄铜矿、方铅矿、闪锌矿、自然金、银金矿以及少量的碲银矿和辉银矿。围岩蚀变主要有钾长石化、硅化、黄铁绢英岩化、绿泥石化和碳酸盐化等。成矿作用从早到晚可划分为4个阶段:石英-黄铁矿阶段(Ⅰ)、石英-绢云母-黄铁矿阶段(Ⅱ)、石英-多金属硫化物阶段(Ⅲ)、碳酸盐-萤石阶段(Ⅳ)。流体包裹体显微测温和激光拉曼成分分析表明,成矿早期流体温度为308~377℃,盐度为6.29%~8.55%,压力为350 MPa,属于H_2O-CO_2-NaCl流体体系;主成矿期的流体温度为226~331℃,盐度为4.87%~10.29%,压力为280~300 MPa,属于H_2O-CO_2-NaCl±CH_4流体体系。包裹体显微测温及岩相学观察发现,主成矿期的成矿流体发生了不混溶作用,这可能是导致金矿化的主要原因之一。硫同位素研究表明,谢家沟金矿床主成矿期黄铁矿的δ34S值接近或略低于胶东典型金矿床成矿期黄铁矿的δ34S值,暗示这些金矿床的成矿物质可能来自相同的源区;氢、氧同位素对比研究表明,谢家沟金矿床成矿流体表现出较明显的岩浆水特征,可能有大气降水的参与,但参与程度较弱。大气降水与岩浆水混合引起的温度降低、挥发分含量的降低可能是导致金矿化的另一原因。 相似文献
995.
仑山金矿床位于宁镇矿集区东端。成矿期分为沉积成矿期和热液成矿期,后者可进一步划分为热液Ⅰ阶段和热液Ⅱ阶段。流体包裹体研究表明,热液Ⅰ阶段石英中的气液两相流体包裹体均一温度多集中在330~366℃之间,盐度w(Na Cl_(eq))变化于4.96%~6.74%之间,热液Ⅰ阶段方解石中气液两相流体包裹体均一温度多集中在150~240℃之间,w(Na Cl_(eq))变化于0.71%~9.80%之间,成矿流体为中高温低盐度流体;热液Ⅱ阶段石英、方解石和萤石的流体包裹体均一温度变化于124~260℃,盐度w(Na Cl_(eq))变化于1%~8%之间,成矿流体为中温低盐度流体。氢、氧同位素研究表明,热液Ⅰ阶段成矿流体为岩浆流体,热液Ⅱ阶段成矿流体以大气降水占主导,但仍有少量岩浆流体。硫同位素研究表明,仑山金矿床沉积成矿期硫除来源于三叠系青龙群膏盐层外,有机质也参与了沉积成矿期中金矿的形成。热液Ⅰ阶段硫来源于沉积成岩阶段黄铁矿的活化迁移和富集,岩浆硫也提供了成矿物质。萤石Sm-Nd测年分析表明,仑山金矿床热液Ⅱ阶段成矿年龄为(93.7±3.1)Ma,推断主成矿阶段形成于晚白垩世。仑山金矿床的形成代表着长江中下游成矿带最晚期的成矿作用。 相似文献
996.
赣南茅坪钨矿床黄玉单晶流体包裹体研究 总被引:2,自引:0,他引:2
文章以赣南茅坪大型钨矿床成矿早阶段形成的黄玉单晶为研究对象,对其中的流体包裹体开展了岩相学、显微测温以及激光拉曼光谱研究。结果显示,茅坪钨矿床黄玉单晶中的流体包裹体以富液两相包裹体为主,同时发育有单相包裹体、富二氧化碳的三相包裹体以及含子矿物包裹体。其中,含子矿物包裹体发育是本矿床黄玉中包裹体的重要特征,子矿物成分有方解石、石英、石盐等;流体包裹体的均一温度介于200~509℃之间,峰值位于420~500℃之间,盐度w(NaCl_(eq))为4.32%~19.22%,峰值介于17%~19%,较前人获得的石英脉型钨矿床成矿温度和盐度均高出许多,其峰值(420~500℃)在一定程度上衔接了石英脉型黑钨矿高温阶段的演化历史;黄玉单晶中包裹体还具有富含CO_2、CH_4、N_2等挥发分的特征。综上所述,笔者认为石英脉型钨矿的成矿流体在早阶段具有高温、中高盐度、富挥发分、富含多种离子的特征。 相似文献
997.
998.
Research on fluid inclusions of the Yinshan polymetallic deposit, Jiangxi Province, China 总被引:1,自引:0,他引:1
In this paper some new advances in the study of fluid inclusions of the Yinshan deposit in Jiangxi Province,China,are presented.The fluid inclusions of the deposit can be divided into four types:1) gas-rich inclusions;2)liquid-rich inclusions;3)salt-saturated H2O inclusions;and 4)single-phase or multiphase CO2-rich inclusions.Homogenization temperatures of the fluid inclusions range from 100 to 520℃,aminly in the range 120-400℃.The daughter crystal-bearing multiphase inclusions present in quartz porphyries(including Nos.13 and 4 dikes)have been observed.In ore veins,some daughter crystal-bearing multiphase inclusions have been observed.too.On the basis of the results of fluid inclusion research,the authors suggest that the ore-forming fluid must have a close genetic relation to magmatic hydrothermal solution.The ore-forming fluid was dominantly originated from the depth and the mixing of magmatic solution with meteoric water was enhanced during ascending of the fluid,accompanying immiscibility and boiling of fluid.Teher may be a conceales igneous body at the depth of the Yinshan deposity,which furnishes the scientific basis for metallogenic prognosis at th depth of the Yinshan deposit. 相似文献
999.
S.‐J. Wang L. Wang M. Brown P. M. Piccoli T. E. Johnson P. Feng H. Deng K. Kitajima Y. Huang 《Journal of Metamorphic Geology》2017,35(6):601-629
Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The εHf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ18O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H2O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H2O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H2O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel. 相似文献
1000.
Alexandre Peillod Uwe Ring Johannes Glodny Alasdair Skelton 《Journal of Metamorphic Geology》2017,35(7):805-830
Geothermobarometric and geochronological work indicates a complete Eocene/early Oligocene blueschist/greenschist facies metamorphic cycle of the Cycladic Blueschist Unit on Naxos Island in the Aegean Sea region. Using the average pressure–temperature (P–T) method of thermocalc coupled with detailed textural work, we separate an early blueschist facies event at 576 ± 16 to 619 ± 32°C and 15.5 ± 0.5 to 16.3 ± 0.9 kbar from a subsequent greenschist facies overprint at 384 ± 30°C and 3.8 ± 1.1 kbar. Multi‐mineral Rb–Sr isochron dating yields crystallization ages for near peak‐pressure blueschist facies assemblages between 40.5 ± 1.0 and 38.3 ± 0.5 Ma. The greenschist facies overprint commonly did not result in complete resetting of age signatures. Maximum ages for the end of greenschist facies reworking, obtained from disequilibrium patterns, cluster near c. 32 Ma, with one sample showing rejuvenation at c. 27 Ma. We conclude that the high‐P rocks from south Naxos were exhumed to upper mid‐crustal levels in the late Eocene and early Oligocene at rates of 7.4 ± 4.6 km/Ma, completing a full blueschist‐/greenschist facies metamorphic cycle soon after subduction within c. 8 Ma. The greenschist facies overprint of the blueschist facies rocks from south Naxos resulted from rapid exhumation and associated deformation/fluid‐controlled metamorphic re‐equilibration, and is unrelated to the strong high‐T metamorphism associated with the Miocene formation of the Naxos migmatite dome. It follows that the Miocene thermal overprint had no impact on rock textures or Sr isotopic signatures, and that the rocks of south Naxos underwent three metamorphic events, one more than hitherto envisaged. 相似文献