G-Probe-1 - An International Proficiency Test for Microprobe Laboratories - Report on Round 1 : February 2002 (TB-1 Basaltic Glass)

Results are presented for round one of a new international proficiency testing programme designed for microprobe laboratories involved in the routine analysis of silicate minerals. The sample used for this round was TB-1, a basaltic glass fused and prepared by the USGS. Thirty nine laboratories contributed data to this round, the majority of major element results being undertaken by EPMA and the majority of trace elements by LA-ICP-MS. Assigned values were derived from the median of results produced by nine selected laboratories that analysed powdered material by conventional ICP-MS, INAA and XRF techniques using bulk powders of the sample. Submitted microprobe results were evaluated using a target precision calculated using the Horwitz function, adopting the same criteria as those used for "applied" geochemistry laboratories in the companion GeoPT proficiency testing programme for laboratories involved in the routine bulk analysis of silicate rocks. An evaluation of results from participating microprobe laboratories indicated that overall, data were compatible with this precision function. A comparison between the performance of bulk and microprobe techniques used in the analysis of the basaltic glass showed remarkably good agreement, with significant bias only observed for the major oxide MgO.     

Caractérisation des paragenèses et des paléocirculations fluides dans l'indice d'or de Bleı̈da (Anti-Atlas,Maroc)Characterization of the paragenesis and the fluid palaeo-circulations in the gold showings of Bleida (Anti-Atlas,Morocco)

The gold showings at Bleida are hosted in Late Pan-African N50–80 °E quartz–hematite–chlorite 1 tension lenses that are related to the activity of major sinistral sub-east–west thrusts. Ores result from three superimposed stages of fluid migration. Gold occurs in microcracks offsetting the earlier minerals. Fluids evolved from COHN compositions with a saline component to boiling aqueous fluids. Pressure and temperature decreased from 50 MPa and 300 °C to less than 4 MPa and 150 °C. Thus, the gold showings at Bleida were formed in a typical geothermal (epithermal) setting, likely controlled by the Late Pan-African magmatism. To cite this article: A. Barakat et al., C. R. Geoscience 334 (2002) 35–41     

Determining gaseous composition of fluid inclusions with quadrupole mass spectrometer

Quadrupole mass spectrometer (QMS) is an instrument for effectively determining gaseous composition of fluid inclusion. The gaseous component is extracted from inclusions with thermal decrepitation method and then determined with the sensitive QMS instrument. The method is characterized by high sensitivity and high accuracy with the relative standard deviation (RSD,n=6) of less than 3%. It has been successfully used for analyzing fluid inclusions. The analytical results meet the requirement of geological study.     

新04号井、新10号井水位和新10号泉流量地震前兆特征的对比分析

通过分析认为乌鲁木齐地区的年降雨、年气温对新 0 4号井、新 1 0号井水位和新 1 0号泉流量没有明显干扰。新 0 4号井、新 1 0号井和新 1 0号泉的震兆特征是 0 4号井水位为负异常 ,1 0号井水位、1 0号泉流量为正异常 ,产生差异的原因可能与观测点所处的构造环境有关。预测了新疆及邻近地区未来一年或稍长一段时间内有发生 7级左右地震的可能。     

河流水质风险评价的灰色-随机风险率方法

提出了量化影响河流水质的随机不确定性与灰色不确定性的水质超标灰色－随机风险率概念，建立了水质超标灰色－随机风险率评价模型。在水质单项参数评价模型中，将河流污染物浓度变量的分布处理成灰色概率分布，将污染物浓度超过水质类别标准值的风险率处理成灰色概率，即水质超标灰色－随机风险率。在水质综合评价模型中，河流水环境系统被考虑为担任某一使用可能的可靠性系统，而任意一种水质参数超标意味着河流水体使用功能不能得到应有的保证，也即表明水体综合评价超标，最后借鉴系统可靠性分析的理论和方法计算水质综合超标率。该方法应用于黄河花园口断面重金属污染风险评价。     

中国东部地区耕地土壤肥力变化趋势研究

随着人口、资源和环境之间的矛盾日趋尖锐,中国耕地土壤肥力及其变化日益为世人所关注。本文利用最近20年东北地区的吉林和黑龙江省,华北地区的北京市和河北省以及长江下游地区的江苏和浙江省的15个县市180个样本点的土壤数据资料,分析了20世纪80年代以来东部地区农业土壤肥力的演变趋势。结果表明,从总体上看,东部地区除土壤速效钾下降和酸碱性有所退化外,农业土壤的有机质、全氮和速效磷平均含量都增加了。在空间分布上,土壤肥力的变化趋势存在明显差异。长江下游和华北地区的平均肥力提高,东北地区下降。另外,除华北地区的土壤酸碱性有改善外,长江下游和东北地区土壤都存在酸化倾向。     

从流体包裹体研究探讨金属矿床成矿条件

根据作者多年来对流体包裹体的研究成果，参考了国内外的研究结论，提出了一个新的成矿流体分类方案，并评述了我国若干典型金属矿床的研究状况，由此探讨了金属矿床的形成机制。     

云南兰坪北部铜多金属矿化区成矿流体流动与矿化分带——流体包裹体和稳定同位素依据

滇西兰坪盆地北部发育了一类受逆冲推覆构造控制的浅成热液Cu—Ag—Pb-Zn矿化，形成了白秧坪、富隆厂、吴底厂、麻栗坪及金满、科登涧等大-中型矿床和矿点，并存在矿化分带。文章利用这些矿化脉体的流体包裹体和热液方解石的碳氧同位素组成资料，研究成矿流体与矿化分带的关系。结果表明，成矿流体主要属于NaCl-H2O成分体系，盐度ω(NaCleq)为2％～11％，形成温度为170～300℃，形成于1．8～3．8km深度内，这些相似性说明这类矿化的发生具有相似的流体性质和沉淀机制。热液方解石在δ^13C-δ^18O图解中呈近水平线展布的型式，指示流体源自地壳浅部的地下水系统，与海相灰岩等围岩作用形成了溶解碳以[HCO3^]-为主的成矿流体，流体与岩石的相互作用可能是成矿流体沉淀的主要机理。从西到东，流体包裹体的盐度-温度由高到低变化与矿化分带和逆冲推覆构造的根带→中带→锋带相配套，显示重力驱动流动可能是主要的流体流动机制。成矿流体在不同构造部位流动的通畅及流体．岩石系统的封闭-开放程度等流体流动性质与矿化发生的强度和规模有关，兰坪北部逆冲推覆构造中带的流体通畅地流动及沉淀时处于相对开放状态，有利于该区形成较大规模的浅成热液多金属矿化。