江苏孟中榴辉岩中单斜辉石向石榴石相转变的初步研究

苏鲁超高压榴辉岩的成因一直是一个令人困惑的问题。本文通过对榴辉岩的进变质作用——榴辉岩相向石榴石岩相转变的初步研究,为苏鲁榴辉岩带的地幔转换带(高压可达10GPa)成因提供了最初的证据。      

胶东威海地区榴辉岩退变质的地球动力学信息

威海地区榴辉岩退变质过程表现为三个阶段：第一阶段,原生绿辉石分解形成钠质单斜辉石＋斜长石合晶体;第二阶段,原生石榴石及钢质单斜辉石＋斜长石合晶体,周边出现角闪石＋斜长石　状反应边;第三阶段,石榴石及钢质单斜辉石消失。其后榴辉岩相退变质的ｐ－ｔ演化轨迹是压力相对温度快速降低的顺时针形式,反映本区榴辉岩折返的地球动力学过程可能是在经历了快速上升的构造侵位同时,晚元古宙巨量花岗岩浆可将相辉岩块体携带到上部地壳。     

Mineral oxygen isotope and hydroxyl content changes in ultrahigh-pressure eclogite–gneiss contacts from Chinese Continental Scientific Drilling Project cores

A combined study of mineral O isotopes and hydroxyl contents was carried out for the contacts between ultrahigh‐pressure eclogite and gneiss from main hole of the Chinese Continental Scientific Drilling Project in the Sulu orogen. While there is a large δ¹⁸O variation from ?8.3 to 7.3‰ for all minerals, different styles of mineral‐pair fractionation occur at the boundaries of different lithologies. Both equilibrium and disequilibrium O isotope fractionations are observed between quartz and the other minerals, with reversed fractionations between omphacite and garnet in some samples of eclogite. This suggests that both eclogite and gneiss acquired their negative δ¹⁸O values by meteoric‐hydrothermal alteration of their protoliths at high temperatures before subduction, and that fluid‐assisted O isotope exchange did take place across the boundary of different lithologies at local scales during amphibolite‐facies retrogression. Fourier Transform Infrared Spectroscopy analysis yielded H₂O concentrations of 50 to 1144 p.p.m. (by weight) for garnet and 139 to 751 p.p.m. for omphacite. The state of equilibrium or disequilibrium O isotope fractionations between omphacite and garnet are correlated with variations in their water content at local scales, indicating that the internally derived fluid plays a critical role in retrograde metamorphism during exhumation. The retrograde metamorphism results in mineral reactions and O isotope disequilibria between some of the minerals, but the fluid for retrogression was derived from the decompression exsolution of structural hydroxyl and thus internally buffered in the O isotope composition. A quantitative estimate suggests that a hand specimen (3 × 6 × 9 cm) of eclogite composed of 70% garnet and 30% omphacite can release 0.316 g water by the decompression exsolution of structural hydroxyl, which can form 14.4 g amphibole during exhumation. This provides sufficient amounts of water for the amphibolite‐facies retrogression.     

羌塘地区榴辉岩中矿物出溶体及其成因机制探讨

西藏羌塘地区榴辉岩石榴子石和磷灰石中均发育矿物出溶体,结合电子探针和扫描电镜分析及能谱分析,确定了石榴子石中的出溶体有金红石、石英和角闪石,指示其可能经历了高压/超高压变质作用。本研究在磷灰石中发现了金红石出溶,并认为其可能是在高压/超高压条件下元素相互置换的结果,置换方式为Ti~(4+)(Fe~(2+)、Si~(4+))=2Ca~(2+),这些出溶体的形成为榴辉岩曾经历高压/超高压变质作用提供了矿物学证据。     

大别山碧溪岭地区超高压变质岩构造分析

大比例尺 (1∶10 0 0 0 )构造制图及构造分析表明 ,碧溪岭地区超高压变质岩石含有丰富的构造演化历史记录。同碰撞或挤压组构只保留于榴辉岩及其它超高压变质岩透镜体内部 ,表现为高角度网络状超高压剪切带与弱应变透镜体域规律组合格式。前者由面理或糜棱岩化榴辉岩组成 ,后者由块状榴辉岩及石榴橄榄岩组成。碰撞期后伸展构造表现为区域性的假单斜状 ,内部呈低缓角度的网络状强应变带及所环绕的透镜状弱应变域组合格式 ,强应变带的岩石为由榴辉岩退变成的角闪岩相高压片麻岩及部分熔融形成的含榴花岗岩 ,透镜状弱应变域的岩石为弱角闪相改造的榴辉岩及石榴橄榄岩。不同尺度上同碰撞或挤压组构及碰撞期后伸展组构所显示的这种残斑基质流变学结构样式 ,虽然与先期原岩成分、结构、流变学的不均一性有关 ,但主要是多期递进应变分解作用的结果 ,支持榴辉岩“原地”成因模式。依据构造学证据和可利用的岩石学及同位素年代学资料 ,分析了超高压变质岩石的形成及折返过程 ,指出碧溪岭地区超高压变质岩石是在 2 45～ 2 10Ma形成的 ,碰撞期后伸展作用主要发生在 2 0 0～ 170Ma。在超高压变质岩石向地壳表层折返过程中 ,张扭作用可能有重要功能 ,不支持碧溪岭地区遭受过多期超高压变质作用的推论。     

CCSD主孔100-2950m榴辉岩类和片麻岩类叶理及微断层产状特征

CCSD主孔100~2950m榴辉岩、退变榴辉岩类岩石叶理倾角明显较片麻岩类岩石叶理倾角陡,前者总体倾角55°左右,后者28°左右,局部可见片麻岩类叶理切割榴辉岩类叶理,因此两者叶理可能形成于不同时期;两类岩石之间现部分为韧性剪切带接触关系,韧性剪切带形成于苏鲁地体折返主期自SEE向NWW的韧性剪切作用。榴辉岩、退变榴辉岩类岩石叶理产状对发育于该类岩石内的微断层产状有一定控制作用,而片麻岩类岩石叶理产状对发育于该类岩石内的微断层产状控制作用相对较弱。孔区脆性变形主要反映白垩纪以来SEE-NWW向伸展构造应力场的变形特征,主孔100~1620m倾伏向以SEE向占绝对优势的微正滑断层擦痕即为该期变形的产物。     

Experimental modelling of corona textures

Formation of corona textures along olivine–plagioclase and orthopyroxene–plagioclase interfaces has been experimentally reproduced at 670 and 700 °C and 5 kbar with either a pure H₂O fluid phase or 0.1 and 37 m NaCl–H₂O solution fluid. In these experiments, we investigate the interaction of primary olivine and/or orthopyroxene and plagioclase in powders and polished crystals, and in small samples of a natural gabbro. The experiments result in the formation of corona textures with several layers of different assemblages (according to the experimental conditions) consisting of garnet (grossular), clinopyroxene, orthopyroxene, amphibole, chlorite and phlogopite. The experiments show major differences in the number of layers, the mineral assemblages and mineral composition, and in the trends of composition of plagioclase in coronas around olivine and orthopyroxene. The fluid phase composition influences the corona assemblages and the composition of the minerals in the experimental coronas; for example, garnet appears in the coronas in the second experiment where the NaCl–H₂O ratio is low. Experimental modelling of corona textures confirms a model of simultaneous growth of layers by the mechanism of diffusion metasomatism with participation of a fluid phase through which mass is transferred. Zoning in the experimental coronas shows opposing diffusion of Al and Ca from plagioclase and Mg and Fe from olivine/orthopyroxene; difference in the mobility of the components is inferred from observations in the coronas. The experimental corona textures are compared with natural coronas from the Belomorian belt (Baltic shield), developed at 670–690 °C and 7–8 kbar, and the Marun‐Keu complex (Polar Urals), developed at 670–700 °C and 14–16 kbar, where the corona textures correspond to a transitional stage of the gabbro‐to‐eclogite transformation.     

大别山北部蛇绿岩的地球化学制约

常量元素,微量元素,稀土元素,Ｎｄ同位素及氧同位素地球化学特征表明,太别山北部变质镁铁－超镁铁质岩带中存在变质的蛇绿岩,它主要由变质橄榄岩,辉长岩（－辉绿岩？）和基性熔岩三部分组成,其中,变质的基性熔岩的亏损地幔模式年龄ｔＤＭ／Ｍａ＝１０３６．８～１２９３．８,εＮｄ（ｔ）＝７．２～７．７,表明它可能代表１０００Ｍａ左右形成于中等扩张速率（２ｃｍ／ａｄ左右）洋盆条件下的洋壳残片。     

大别山榴辉岩一片麻岩杂岩的成因

大别山榴辉岩由辉长岩、大陆拉斑玄武岩和少量泥灰质经高压变质作用形成。大别地块可划分出四个形成条件不同的榴辉岩区,它们代表一种构造－岩石组合体。片麻岩杂岩中各种高压变质岩类的发现证明它们与榴辉岩一起经历了原地高压变质过程。二者变质作用Ｐ－Ｔ参数的差异归因于抬升过程中退变质反应速度的不同。不同地区榴辉岩退变质组合及Ｐ－Ｔ条件与围岩的一致性表明,大别杂岩现今所展示的“递增”变质带是由榴辉岩相退变质作用形成的。高压榴辉岩－片麻岩杂岩的产生是印支期扬子与华北两个大陆板块碰撞的结果。     

中国境内可能存在一条新的高压/超高压(?)变质带——青藏高原拉萨地体中发现榴辉岩带

新发现榴辉岩带位于拉萨北东方向,产在青藏高原拉萨地体中东部。观察到的榴辉岩带宽度约500~600m,呈近东西向延伸,已知规模10km以上。榴辉岩为常见的金红石榴辉岩、石英榴辉岩和多硅白云母榴辉岩。榴辉岩的单斜辉石中含硬玉分子变化较大,Jd=16%~44%,但均落于绿辉石成分区间;石榴子石中镁铝榴石(Pyrope)端元组分16%~33%,铁铝榴石(Alm)40%~54%,钙铝榴石(Gross)22%~31%。利用Grt-Omp-Phe和Grt-Omp矿物组合对变质温-压初步估算,获得金红石榴辉岩样品06Y-334的变质p、t分别为2.58GPa、635℃和2.67GPa、730℃,样品06Y-345的t主要在680~780℃区间,样品06Y-336的t主要在640~740℃区间,3个样品获得的结果相近。显微镜观察表明多硅白云母可能为折返阶段的退变质矿物而不属变质峰期的矿物,推测峰期的压力值有可能高于2.67GPa而进入柯石英稳定区间(p>2.8GPa)。石榴子石和绿辉石中出现的一些类似柯石英假象的石英包裹体与这一推断相吻合。以上初步研究结果表明,拉萨地体的榴辉岩带可能是中国境内又一条高压/超高压(?)变质带。