Processing of oxidised nitrogen compounds by passage through winter-time orographic cloud

Four case studies are described, from a three-site field experiment in October/November 1991 using the Great Dun Fell flow-through reactor hill cap cloud in rural Northern England. Measurements of total odd-nitrogen nitrogen oxides (NO _y ) made on either side of the hill, before and after the air flowed through the cloud, showed that 10 to 50% of the NO _y , called NO _z , was neither NO nor NO₂. This NO _z failed to exhibit a diurnal variation and was often higher after passage through cloud than before. No evidence of conversion of NO _z to NO₃ ^- in cloud was found. A simple box model of gas-phase chemistry in air before it reached the cloud, including scavenging of NO₃ and N₂O₅ by aerosol of surface area proportional to the NO₂ mixing ratio, shows that NO₃ and N₂O₅ may build up in the boundary layer by night only if stable stratification insulates the air from emissions of NO. This may explain the lack of evidence for N₂O₅ forming NO₃ ^- in cloud under well-mixed conditions in 1991, in contrast with observations under stably stratified conditions during previous experiments when evidence of N₂O₅ was found. Inside the cloud, some variations in the calculated total atmospheric loading of HNO₂ and the cloud liquid water content were related to each other. Also, indications of conversion of NO _x to NO _z were found. To explain these observations, scavenging of NO _x and HNO₂ by cloud droplets and/or aqueous-phase oxidation of NO₂ ^- by nitrate radicals are considered. When cloud acidity was being produced by aqueous-phase oxidation of NO _x or SO₂, NO₃ ^- which had entered the cloud as aerosol particles was liberated as HNO₃ vapour. When no aqueous-phase production of acidity was occurring, the reverse, conversion of scavenged HNO₃ to particulate NO₃ ^-, was observed.     

Towards urbanisation of the non-hydrostatic numerical weather prediction model Lokalmodell (LM)

Numerical weather prediction models are increasingly employed for providing meteorological data for urban air quality applications. Model resolution, physiographic parameters and surface-layer parameterisations need to be adapted to the requirements of the urban boundary layer. The Lokalmodell of the German Weather Service was triple-nested down to a horizontal grid resolution of 1.1 km, urbanised physiographic parameters were implemented, and an additional anthropogenic heat source was introduced. Results of a sensitivity study for a spring dust episode in Helsinki show a clear urbanisation effect of these measures on temperature, humidity and the partitioning of surface fluxes, leading to an increased Bowen ratio and heat storage and an urban heat island effect.     

One-Equation Turbulence Modelling for Atmospheric and Engineering Applications

A new algebraic turbulent length scale model is developed, based on previous one-equation turbulence modelling experience in atmospheric flow and dispersion calculations. The model is applied to the neutral Ekman layer, as well as to fully-developed pipe and channel flows. For the pipe and channel flows examined the present model results can be considered as nearly equivalent to the results obtained using the standard k– model. For the neutral Ekman layer, the model predicts satisfactorily the near-neutral Cabauw friction velocities and a dependence of the drag coefficient versus Rossby number very close to that derived from published (G. N. Coleman) direct numerical simulations. The model underestimates the Cabauw cross-isobaric angles, but to a less degree than the cross-isobar angle versus Rossby dependence derived from the Coleman simulation. Finally, for the Cabauw data, with a geostrophic wind magnitude of 10 ms^–1, the model predicts an eddy diffusivity distribution in good agreement with semi-empirical distributions used in current operational practice.     

Modelling of the OASIS Energy Flux Measurements Using Two Canopy Concepts

Two land surface schemes, SCAM and CSIRO9, were used to model the measured energy fluxes during the OASIS (Observations At Several Interacting Scales) field program. The measurements were taken at six sites along a 100 km rainfall gradient. Two types of simulations were conducted: (1) offline simulations forced with measured atmospheric input data at each of the six sites, and (2) regional simulations with the two land surface schemes coupled to the regional climate model DARLAM.The two land surface schemes employ two different canopy modelling concepts: in SCAM the vegetation is conceptually above the ground surface, while CSIRO9 employs the more commonly used `horizontally tiled' approach in which the vegetation cover is modelled by conceptually placing it beside bare ground. Both schemes utilize the same below-ground components (soil hydrological and thermal models) to reduce the comparison to canopy processes only. However, the ground heat flux, soil evaporation and evapotranspiration are parameterised by the two canopy treatments somewhat differently.Both canopy concepts reproduce the measured energy fluxes. SCAM has a slightly higher root-mean standard error in the model-measurement comparison for the ground heat flux. The mean surface radiative temperature simulated by SCAM is approximately 1K lower than in the CSIRO9 simulations. However, the soil and vegetation temperatures (which contribute to the radiative temperature) varied more in the CSIRO9 simulations. These larger variations are due to the absence of a representation of the aerodynamic interactions between vegetation and ground.     

Observational and Numerical Study on the Influence of Large-Scale Flow Direction and Coastline Shape on Sea-Breeze Evolution

In this study radar, surface observations and numericalsimulations are used to examine the inland penetrationand intensity of the sea breeze during various large-scaleflow regimes along the curved coastline of the Carolinas,U.S.A. The results clearly indicate that the flow directionrelative to the curved coastline has a significant effecton the sea-breeze evolution.Overall, during northerly flow regimes alongthe curved North Carolina coast, observationsand numerical simulations show that the sea-breezefront has a tendency to remain close to the south-facingcoast. During these same flow regimes the frontmoves further inland relative to the east-facingcoast. The sea-breeze front during westerly flowcases progressed further inland relative to the southcoast and less so from the east-facing coastline.South-westerly flow allows the sea breeze to moveinland from both coastlines but the coastal shapeinfluence makes the inland penetration less fromthe easterly facing beaches. During periods of lightonshore flow (south-east), the sea breeze movesconsiderable distances inland but is not discernableuntil later in the afternoon. The simulations indicatedthat the sea-breeze intensity is greatest (least) when thelarge-scale flow direction has an offshore (onshore)component. Model results indicate the existence of astrong front well inland in the late afternoon duringlight onshore flow. Also noted was that the simulatedsea-breeze front develops earlier in the afternoon duringoffshore regimes and later in the day as the large-scaleflow becomes more onshore. It is concluded that thecoastline shape and coast-relative flow direction areimportant factors in determining how the sea-breezecirculation evolves spatially.