Controls on metamorphic equilibration: the importance of intergranular solubilities mediated by fluid composition

A dramatic demonstration of the role of intergranular solubility in promoting chemical equilibration during metamorphism is found in the unusual zoning of garnet in pelitic schist exposed at Harpswell Neck, Maine, USA. Many garnet crystals have irregular, patchy distributions of Mn, Cr, Fe and Mg in their inclusion‐rich interiors, transitioning to smooth, concentric zoning in their inclusion‐poor outer rims; in contrast, zoning of Ca and Y is comparatively smooth and concentric throughout. We re‐assess the disputed origin of these zoning features by examining garnet growth in the context of the thermal and structural history of the rocks, and by evaluating the record of fluid–rock interaction revealed in outcrop‐scale veining and fluid‐inclusion assemblages. The transition in the character of garnet zoning correlates with the onset of a synkinematic, simple‐shear‐dominated phase of garnet growth and with a shift in the composition of the intergranular fluid from CO₂‐rich to H₂O‐rich. Compositional variations in garnet are therefore best explained by a two‐stage growth history in which intergranular diffusive fluxes reflect differences in the concentration of dissolved species in these two contrasting fluids. Interiors of garnet crystals grew in the presence of a CO₂‐rich fluid, in which limited solubility for Mn and Cr (and perhaps Fe and Mg) produced patchy disequilibrium overprint zoning, while appreciable solubility for Ca and Y permitted their rock‐wide equilibration. Rims grew in the presence of an H₂O‐rich fluid, in which high intergranular concentrations for all elements except Cr enabled diffusion over length scales sufficient for rock‐wide equilibration. This striking example of partial chemical equilibrium during reaction and porphyroblast growth implies that thermal effects may commonly be subsidiary in importance to solubilities in the intergranular medium as determinants of length scales for metamorphic equilibration.     

River evaporation,condensation and heat fluxes within a first‐order tributary of Catamaran Brook (New Brunswick,Canada)

Stream temperature plays an important role in many biotic and abiotic processes, as it influences many physical, chemical and biological properties in rivers. As such, a good understanding of the thermal regime of rivers is essential for effective fisheries management and the protection aquatic habitats. Moreover, a thorough understanding of underlying physical processes and river heat fluxes is essential in the development of better and more adaptive water temperature models. Very few studies have measured river evaporation and condensation and subsequently calculated corresponding heat fluxes in small tributary streams, mainly because microclimate data (data collected within the stream environment) are essential and rarely available. As such, the present study will address these issues by measuring river evaporation and condensation in tributary 1 (Trib 1, a small tributary within Catamaran Brook) using floating minipans. The latent heat flux and other important fluxes were calculated. Results showed that evaporation was low within the small Trib 1 of Catamaran Brook, less than 0.07 mm day^?1. Results showed that condensation played an important role in the latent heat flux. In fact, condensation was present during 34 of 92 days (37%) during the summer, which occurred when air temperature was greater than water temperature by 4–6 °C. Heat fluxes within this small stream showed that solar radiation dominated the heat gains and long‐wave radiation dominated the heat losses. © 2015 Her Majesty the Queen in Right of Canada. Hydrological Processes. © 2015 John Wiley & Sons, Ltd.     

Reaction softening by dissolution–precipitation creep in a retrograde greenschist facies ductile shear zone,New Hampshire,USA

We describe strain localization by a mixed process of reaction and microstructural softening in a lower greenschist facies ductile fault zone that transposes and replaces middle to upper amphibolite facies fabrics and mineral assemblages in the host schist of the Littleton Formation near Claremont, New Hampshire. Here, Na‐poor muscovite and chlorite progressively replace first staurolite, then garnet, and finally biotite porphyroblasts as the core of the fault zone is approached. Across the transect, higher grade fabric‐forming Na‐rich muscovite is also progressively replaced by fabric‐forming Na‐poor muscovite. The mineralogy of the new phyllonitic fault‐rock produced is dominated by Na‐poor muscovite and chlorite together with late albite porphyroblasts. The replacement of the amphibolite facies porphyroblasts by muscovite and chlorite is pseudomorphic in some samples and shows that the chemical metastability of the porphyroblasts is sufficient to drive replacement. In contrast, element mapping shows that fabric‐forming Na‐rich muscovite is selectively replaced at high‐strain microstructural sites, indicating that strain energy played an important role in activating the dissolution of the compositionally metastable muscovite. The replacement of strong, high‐grade porphyroblasts by weaker Na‐poor muscovite and chlorite constitutes reaction softening. The crystallization of parallel and contiguous mica in the retrograde foliation at the expense of the earlier and locally crenulated Na‐rich muscovite‐defined foliation destroys not only the metastable high‐grade mineralogy, but also its stronger geometry. This process constitutes both reaction and microstructural softening. The deformation mechanism here was thus one of dissolution–precipitation creep, activated at considerably lower stresses than might be predicted in quartzofeldspathic rocks at the same lower greenschist facies conditions.     

基于颜色迁移的单极化SAR图像伪彩色增强

本文从颜色信息角度出发,提出了一种基于颜色迁移的单极化SAR图像彩色增强方法。该方法通过伪彩色编码将SAR图像变为过渡彩色图像,运用保持细节的颜色迁移方法在颜色迁移的过程中保留SAR图像的细节信息,用改变各通道系数的方式进行色调调整使得SAR图像与光学图像有着相同的颜色信息,并通过实验证明该方法的有效性。     

迁移学习支持下的高分影像山地滑坡灾害解译模型

无人机低空遥感是近年来新兴的一种快速获取灾情信息的手段,如何利用无人机高分影像构建滑坡灾害解译模型是实现快速自动解译滑坡的关键。针对该问题,对比了多种影像特征提取方法,将迁移学习(TL)特征和支持向量机(SVM)引入到构建滑坡灾害自动解译模型中,提出了一种TL支持下的高分影像滑坡灾害解译模型。选取5·12汶川地震及4·20芦山地震系列无人机影像构建了滑坡灾害样本库并进行了实验,TL特征方法整体分类准确度ACC为95%,ROC达到0.98,识别准确率达到97%。结果表明,所提方法可用于高分影像滑坡自动解译,同时可用于大面积高分影像中快速山地滑坡灾害定位及检测。     

从平衡-封闭-静态转向非平衡-开放-动力学研究-热液矿床成因的若干新概念概述

热液金属矿床成因研究过程中,观测与实验始终是密切结合的。上世纪70年代,平衡热力学的实验数据的快速积累,使人们用热力学理论计算可以预测和反演矿石和岩石的成因。但是,没有矿物-水溶液的反应速率数据,又没有与流体力学的结合,搞清楚矿石成因是困难的。七、八十年代,开始研究矿物与水溶液的反应动力学实验。科学家们开始瞄准了从平衡-封闭-静态转向非平衡-开放-动力学研究的这个大方向。1992年我们建立地球化学动力学开放研究实验室。研究高温高压矿物与水反应速率,发现固液的开放体系的自组织现象。实验发现温度影响矿物的各个元素反应速率改变,发现在跨越水临界态时矿物与水反应速率涨落、在近临界的气-液两相不混溶区一些金属进入气相、超临界流体的氧化作用及特别的溶剂性能影响矿物溶解性质。实验证实:临界态区流体与矿石成因有关。水岩相互作用的反应动力学实验温度从低温到550度,揭示矿石的金属来源、迁移、金属与蚀变分带机制。一大批大于300度的矿物与水反应动力学实验在国际界是少有报道的。九十年代,超高压的科学发展,与同步辐射光源的技术进步的结合,使固体地球科学又迈向了地球深内部。我们发展了高温高压流体性质的原位直测(测量850℃水溶液)红外谱,发现深部流体的新性质:气液两相流体的新结构,在临界温度区(300~400℃),水分子氢键网络的破坏受压力影响不大(23MPa~3GPa),同时,出现水的高电导率。研发新仪器为开放-流动-非平衡的反应动力学实验与极端条件下物质性质的直接观测结合,在科学前沿领域开辟了创新道路。     

Reactivity of micas and cap-rock in wet supercritical CO2 with SO2 and O2 at CO2 storage conditions

Seal or cap-rock integrity is a safety issue during geological carbon dioxide capture and storage (CCS). Industrial impurities such as SO₂, O₂, and NOx, may be present in CO₂ streams from coal combustion sources. SO₂ and O₂ have been shown recently to influence rock reactivity when dissolved in formation water. Buoyant water-saturated supercritical CO₂ fluid may also come into contact with the base of cap-rock after CO₂ injection. Supercritical fluid-rock reactions have the potential to result in corrosion of reactive minerals in rock, with impurity gases additionally present there is the potential for enhanced reactivity but also favourable mineral precipitation.The first observation of mineral dissolution and precipitation on phyllosilicates and CO₂ storage cap-rock (siliciclastic reservoir) core during water-saturated supercritical CO₂ reactions with industrial impurities SO₂ and O₂ at simulated reservoir conditions is presented. Phyllosilicates (biotite, phlogopite and muscovite) were reacted in contact with a water-saturated supercritical CO₂ containing SO₂, or SO₂ and O₂, and were also immersed in the gas-saturated bulk water. Secondary precipitated sulfate minerals were formed on mineral surfaces concentrated at sheet edges. SO₂ dissolution and oxidation resulted in solution pH decreasing to 0.74 through sulfuric acid formation. Phyllosilicate dissolution released elements to solution with ∼50% Fe mobilized. Geochemical modelling was in good agreement with experimental water chemistry. New minerals nontronite (smectite), hematite, jarosite and goethite were saturated in models. A cap-rock core siltstone sample from the Surat Basin, Australia, was also reacted in water-saturated supercritical CO₂ containing SO₂ or in pure supercritical CO₂. In the presence of SO₂, siderite and ankerite were corroded, and Fe-chlorite altered by the leaching of mainly Fe and Al. Corrosion of micas in the cap-rock was however not observed as the pH was buffered by carbonate dissolution. Ca-sulfate, and Fe-bearing precipitates were observed post SO₂-CO₂ reaction, mainly centered on surface cracks and an illite rich illite-smectite precipitate quantified. Water saturated impure supercritical CO₂ was observed to have reactivity to rock-forming biotite, muscovite and phlogopite mineral separates. In the cap-rock core however carbonates and chlorite were the main reacting minerals showing the importance of assessing actual whole core.     

耦合长期预报的跨流域引水受水水库调度模型

为提高跨流域引水工程受水水库引水有效性,研究了耦合长期径流预报信息的跨流域引水受水水库调度模型。首先选取汛期径流预报信息,采用径流预报概率修正先验概率来描述径流的不确定性,建立了贝叶斯随机动态规划模型(BSDP-LTF)。然后将模型应用于碧流河水库,并与仅考虑径流相关的随机动态规划模型(SDP-I)、仅考虑长期预报信息的随机动态规划模型(SDP-LTF)进行比较。比较结果得出在供水保证率基本一致且不增加调度风险的情况下,BSDP-LTF模型相比SDP-I、SDP-LTF模型,可分别减少引水8.2%、4.1%。表明贝叶斯随机动态规划模型BSDP-LTF有效改进了径流描述,提高了跨流域引水的有效性。     

中国城市流动人口户籍迁移意愿的空间格局及影响因素——基于2012年全国流动人口动态监测调查数据

基于2012年全国流动人口动态监测调查数据和相关统计年鉴数据,对中国地级以上城市流动人口的户籍迁移意愿、空间格局及影响因素进行了系统分析。研究发现,中国城市流动人口户籍迁移意愿的整体水平并不高;等级高、规模大的城市流动人口的户籍迁移意愿高,而等级低、规模小的城市流动人口的户籍迁移意愿低;沿海城市群流动人口的户籍迁移意愿高,其他城市流动人口的户籍迁移意愿低,但内陆部分省会城市和交通区位与资源禀赋较好的中小城市也已经形成了一批流动人口的户籍迁移意愿高值区。中国城市流动人口户籍迁移意愿的空间分布特征受到流入城市和流动人口自身双重力量的影响,流入城市因素的正向影响作用大于流动人口自身因素。其中,流入城市的社会、经济发展水平和流动人口在流入城市的社会融合程度是核心要素,对城市流动人口户籍迁移意愿的提升具有正向的促进作用,而流动人口过于集中在次级劳动力市场的就业特征和较高的家庭财富与收入对户籍迁移意愿的提升却具有显著的抑制作用。最后,提出了相关政策启示。     

Seismicity and fault aseismic deformation caused by fluid injection in decametric in-situ experiments

Seismicity induced by fluid perturbations became an important societal concern since felt earthquakes (M_w up to 6) occurred after anthropogenic activities. In order to mitigate the risks associated with undesired seismicity, as well as to be able to use the micro-seismicity as a probe for in-depth investigation of fluid-driven processes, it is of crucial importance to understand the links between seismicity, fluid pressure and flow. We have developed a series of in-situ, decameter-scale experiments of fault zone reactivation by controlled fluid injection, in order to improve the near-source geophysical and hydromechanical observations. The deployed geophysical monitoring close to the injection allows one to cover the full frequency range of the fault responses from the static deformation to the very high-frequency seismic emissions (up to 4 kHz). Here, we focus on the microseismicity (M_w ∼ –4 to –3) recorded during two fluid injection experiments in low-permeable shale and highly-fractured limestone formations. In both experiments, the spatio-temporal distribution of the seismic events, the energy balance, and the seismic velocity changes of the fractured medium show that most of the deformation does not actually emit seismic signals. The induced deformation is mainly aseismic. Based on these high-resolution multiparametric observations in the near-field, we therefore proposed a new model for injection-induced seismicity: the seismicity is not directly induced by the increasing fluid pressure, but it is rather triggered by the stress perturbations transferred from the aseismic motion caused by the injection.