湖南宝山铜钼铅锌银多金属矿田围岩蚀变与矿化分带特征

宝山铜钼铅锌银矿田主要由中部、东部、西部和北部４个矿床组成,属岩浆期后高中温含矿热液接触交代矽卡岩型铜钼金属铋矿床、中低温热液充填交代铅锌银矿床。矿田围岩蚀变强烈,并与矿化关系密切,具有以岩体为中心向外呈现明显的围岩蚀变和矿化分带特征,可作为找矿的重要标志。     

香港地区地震风险评价和设防区划

香港地区隶属于中国板内地震区中的东南沿海块缘地震带。港-九块体为晚中生代至早第三纪以来以持续稳定上升为主的块体, 块体活动性明显地低于其周边相对下沉的中新生代盆地。为此, 赋予港-九块体为最大可信震级M=5.5级潜在震源区, 而其周边中新生代断陷盆地则为最大可信震级M6.0潜在震源。从大陆地震构造成因的环境、潜在震源可信震级范围M=5.0～7.5和近源地震动饱和等三个方面的可比性, 结合中国大陆地震震源破裂尺度和地震烈度影响场, 所建立的反映中国地震构造和震源破裂及地震烈度影响场特点的PGA和反应谱地震动衰减预测关系式可用于香港地区。以50%概率时的中值对中国强震记录的对比, 本研究所提供的经验期望预测关系式, 能包络实际的资料。因此, 用此地震动衰减预测模式对香港地区地震危险性进行评估, 将会得到相对保守地震动预测值。通过香港地区基岩地震动危险性分析和计算, 参照中国大陆地震设防标准, 进行了基岩设计参数确定和区划。以年概率P=0.02、P=0.002、P=0.0004三个概率标准, 对应的地震动重复周期大约分别约为50a, 500a, 2500a的基岩PGA和反应谱, 作为香港地区基岩上构筑物和建筑物可选的基     

Chloritoid–glaucophane schist in the north Qilian orogen, NW China: phase equilibria and P–T path from garnet zonation

Chloritoid–glaucophane‐bearing rocks are widespread in the high‐pressure belt of the north Qilian orogen, NW China. They are interbedded and cofacial with felsic schists originated from greywackes, mafic garnet blueschists and low‐T eclogites. Two representative chloritoid–glaucophane‐bearing assemblages are chloritoid + glaucophane + garnet + talc + quartz (sample Q5‐49) and chloritoid + glaucophane + garnet + phengite + epidote + quartz (sample Q5‐12). Garnet in sample Q5‐49 is coarse‐, medium‐ and fine‐grained and shows two types of zonation patterns. In pattern I, X_grs is constant as X_py rises, and in pattern II X_grs decreases as X_py rises. Phase equilibrium modelling in the NC(K)MnFMASH system with Thermocalc 3.25 indicates that pattern I can be formed during progressive metamorphism in lawsonite‐stable assemblages, while pattern II zonation can be formed with further heating after lawsonite has been consumed. Garnet growth in Q5‐49 is consistent with a continuous progressive metamorphic process from ～14.5 kbar at 470 °C to ～22.5 kbar at 560 °C. Garnet in sample Q5‐12 develops with pattern I zonation, which is consistent with a progressive metamorphic process from ～21 kbar at 540 °C to ～23.5 kbar at 580 °C with lawsonite present in the whole garnet growth. The latter sample shows the highest P–T conditions of the reported chloritoid–glaucophane‐bearing assemblages. Phase equilibrium calculation in the NCKFMASH system with a recent mixing model of amphibole indicates that chloritoid + glaucophane paragenesis does not have a low‐pressure limit of 18–19 kbar as previously suggested, but has a much larger pressure range from 7–8 to 27–30 kbar, with the low‐pressure part being within the stability field of albite.     

Micro-zircon: origin and evolution during metamorphism

The size and distribution of zircon within a garnet-mica-schist from the Scottish Highlands were assessed using scanning electron microscopy. The study reveals that abundant 0.2–3.0 μm sized zircon is preferentially concentrated within garnet and biotite porphyroblasts. The micro-zircon has grown during regional metamorphism and represents >90% of the total number of zircon in the schist. It is texturally distinct from a few larger detrital zircon grains in the schist that commonly preserve evidence of dissolution, and more rarely, small metamorphic outgrowths. The sequential incorporation of zircon in porphyroblasts allows prograde changes in the morphology of the zircon population to be identified. Zircon is reactive and soluble, and responds to medium-grade metamorphism in a series of dissolution and crystallization events, linked to possible changes in fluid composition. Deformation also has a significant influence on the distribution of zircon, allowing inclusions previously trapped within biotite to react. About 8 × 10⁶ micro-zircon occur as inclusions within a typical individual 5-mm garnet porphyroblast and their presence must be considered prior to trace-element or isotopic analysis of such metamorphic phases.     

Metamorphic and structural evolution of the Early Proterozoic Puolankajärvi Formation, Finland – I. Structural and textural relations

The amphibolite facies Puolankajärvi Formation (PjF) occupies the western margin of the Early Proterozoic Kainuu Schist Belt (KSB) of northern Finland. The lower and middle parts of the PjF consist of turbiditic psammites and pelites and tempestitic semipelites. This report concentrates on the pelitic lithologies which include quartz–two-mica–plagioclase schists with variable amounts of garnet, staurolite, andalusite and biotite porphyroblasts as well as sillimanite and cordierite segregations. The KSB forms a major north–south-trending synclinorium between two Archaean blocks. It contains both autochthonous and allochthonous units and is cut by faults and shear zones. The PjF lies on the western side of the KSB and is probably allochthonous. The formation has undergone six major deformation phases (D₁, D₂, D_3a, D_3b, D₄ and D₅). During D_3a-D₅ the maximum principal stress (σ₁) changed in a clockwise direction from south-west to north-east. Between D₂ and D₃ the intermediate principal stress (σ₂) changed from horizontal to vertical and the interval between D₂ and D₃ marks a transition from thrust to strike-slip tectonics. Relict structures in the porphyroblasts indicate the following mineral growth–deformation evolution in the PjF. (1) Throughout the PjF there was a successive crystallization of garnet (syn-D₁), poryphyroblastic biotite (inter-D_3/4) and staurolite (inter-D_3/4) during the pre-D₄ stage. (2) A syn-D₄-inter-D_4/5 crystallization of kyanite, sillimanite (fibrolite), porphyroblastic tourmaline, magnetite, rutile, cordierite and muscovite–biotite–plagioclase pseudomorphs after staurolite was most localized at and near D₄ shear zones. (3) A syn- to post-D₅ generation of andalusite, ilmenohematite and sheet silicates after staurolite and after cordierite occurred near D₅ faults. The evolution outlined here permits the relative dating of the PjF parageneses, which is used in the second part of the study (Tuisku & Laajoki, 1990), and, together with the knowledge of the pressure–temperature conditions during various growth events, makes it possible to compile pressure–temperature–deformation paths for the PjF.     

Synchronous peak Barrovian metamorphism driven by syn-orogenic magmatism and fluid flow in southern Connecticut, USA

Recent work in Barrovian metamorphic terranes has found that rocks experience peak metamorphic temperatures across several grades at similar times. This result is inconsistent with most geodynamic models of crustal over‐thickening and conductive heating, wherein rocks which reach different metamorphic grades generally reach peak temperatures at different times. Instead, the presence of additional sources of heat and/or focusing mechanisms for heat transport, such as magmatic intrusions and/or advection by metamorphic fluids, may have contributed to the contemporaneous development of several different metamorphic zones. Here, we test the hypothesis of temporally focussed heating for the Wepawaug Schist, a Barrovian terrane in Connecticut, USA, using Sm–Nd ages of prograde garnet growth and U–Pb zircon crystallization ages of associated igneous rocks. Peak temperature in the biotite–garnet zone was dated (via Sm–Nd on garnet) at 378.9 ± 1.6 Ma (2σ), whereas peak temperature in the highest grade staurolite–kyanite zone was dated (via Sm–Nd on garnet rims) at 379.9 ± 6.8 Ma (2σ). These garnet ages suggest that peak metamorphism was pene‐contemporaneous (within error) across these metamorphic grades. Ion microprobe U–Pb ages for zircon from igneous rocks hosted by the metapelites also indicate a period of syn‐metamorphic peak igneous activity at 380.6 ± 4.7 Ma (2σ), indistinguishable from the peak ages recorded by garnet. A 388.6 ± 2.1 Ma (2σ) garnet core age from the staurolite–kyanite zone indicates an earlier episode of growth (coincident with ages from texturally early zircon and a previously published monazite age) along the prograde regional metamorphic T–t path. The timing of peak metamorphism and igneous activity, as well as the occurrence of extensive syn‐metamorphic quartz vein systems and pegmatites, best supports the hypothesis that advective heating driven by magmas and fluids focussed major mineral growth into two distinct episodes: the first at c. 389 Ma, and the second, corresponding to the regionally synchronous peak metamorphism, at c. 380 Ma.     

模糊评判法在公路黄土洞穴发育程度分区中的应用

阐述了影响黄土洞穴形成的黄土湿陷性、崩解性、地质构造、节理裂隙、微地形地貌和水文及气候条件等工程地质特性和地质因素;在公路沿线地区,公路工程质量及人类活动也是黄土洞穴形成的影响因素。洞穴发育程度分区预测和评价极具复杂性、随机性和模糊性,为此,在对各影响因素分析的基础上,借助模糊综合评判法,对黄土区公路沿线洞穴发育程度分区进行了研究。与实际情况对比分析表明,预测评价结果合理可靠,可作为黄土区已建公路洞穴灾害的防治依据。     

滇西马厂箐铜钼多金属矿床成矿流体来源及演化过程——来自石榴子石原位微量元素及H- O同位素组成的限定

滇西马厂箐铜钼多金属矿床位于三江特提斯成矿域,是一个与喜马拉雅期富碱斑岩侵入有关的多金属矿床。前人研究表明,马厂箐铜钼多金属矿床形成于斑岩-矽卡岩成矿系统,但由于缺乏系统矿物学研究,目前对矽卡岩矿化过程和成矿效应仍不清楚,限制了对该矿床成矿过程的全面认识。因此,本文以马厂箐矿床矽卡岩型矿化中的石榴子石为研究对象,利用H-O同位素、电子探针(EPMA)以及LA-ICP-MS原位微区技术开展了同位素及成分分析,限定成矿流体来源以及反演成矿流体演化过程。石榴子石可分为早期自形石榴子石(Grt I)和晚期他形石榴子石(Grt II)。Grt I与辉石共生,并伴有黄铁矿、黄铜矿等金属矿物组合,属于钙铝-钙铁榴石固溶体(And_{49.37～99.58}Gro_0～49.79);Grt II更富Fe,属钙铁榴石系列(And_{67.50～99.85}Gro_0～31.84)。两期石榴子石均富含Th、U、Nd,亏损Ba、Sr、Hf、Nb,富轻稀土。基于石榴子石矿物化学特征认为,Grt I可能是在弱酸性、氧化、低水岩比(W/R)条...     

1951-2013年浙江热量资源变化研究

基于1951—2013年浙江71个常规气象站逐日气温资料和1971—2013年土温资料,采用M-K检验、气候倾向率等气候统计诊断方法,分析浙江地区气温、地温、农业界限温度等热量资源要素的变化规律及气候变化下浙江热量资源区划的年代际变化特征,以期为充分利用气候资源、优化农业结构和作物引种提供科学依据。研究结果表明：1）1951—2013年浙江四季和年平均气温变化幅度分别为0.24 ℃·10a-1(P0.01)、0.10 ℃·10a-1(P0.05)、0.14 ℃·10a-1(P0.01)、0.14 ℃·10a-1(P0.05)和0.18 ℃·10a-1(P0.05),突变起始年分别为1997、2005、2002、1993和1999年;2）1951—2013年浙江平均极端最高、最低气温的气候倾向率分别为0.10 ℃·10a-1(P0.01)和0.30 ℃·10a-1(P0.10);3）土温与农业密切相关,0—20 cm土温与日平均温度通过0.01显著性相关;4）气候变暖导致浙江农业界限温度(0 ℃、5 ℃、10 ℃、15 ℃、20 ℃)初日提前、终日延后、持续天数和积温增加,农业界限温度初日、终日、持续天数和积温的气候倾向率平均值分别为-3.2～-1.5 d·10a-1、0.3～1.6 d·10a-1、2.8～4.1 d·10a-1、95.7～107.3 ℃·d·10a-1;5）1951—2013年浙江初霜延迟、终霜提前、无霜期增加,初霜、终霜和无霜期气候倾向率平均为-3.62 d·10a-1、1.32 d·10a-1和4.97 d·10a-1;6）气候变暖导致浙江热量资源区划变化显著,2001—2010年淳安建德浦江义乌诸暨嵊州天台三门线以南地区≥10 ℃积温超过5600 ℃·d。     

Mineral Geochemical Compositions of Tourmalines and Their Significance in the Gejiu Tin Polymetallic Deposits, Yunnan, China

Abstract: The Gejiu tin polymetallic deposits are located in the southeastern part of Yunnan Province in China. A detailed electronic microprobe study has been carried out to document geochemical compositions of tourmalines from the deposits. The results indicate a systematic change of mineral geochemical compositions, which might be used as a mineral geochemical tracer for post-magmatic hydrothermal fluid, basin fluid and their mixture. The tourmalines from granite are schorl with Fe/(Fe+Mg) ratios of 0.912-1.00 and Na/(Na+Ca) ratios of 0.892-0.981. Tourmalines as an inclusion in quartz from the ore bodies are dravite with Fe/(Fe+Mg) ratios of 0.212-0.519 and Na/ (Na+Ca) ratios of 0.786-0.997. Tourmalines from the country rocks are dravite with Fe/(Fe+Mg) ratios of 0.313-0.337 and Na/(Na+Ca) ratio of 0.599-0.723. Tourmalines from cassiterite-tourmaline veins that occur in crannies within the country rocks show distinct optical zoning with alternate occurrence of dravite and schorl, Fe/(Fe+Mg)=0.374-0.843, Na/(Na+Ca)=0.538-0.987. It suggests that schorl in granite and dravite in carbonatite are related to magmatic fluid and basin fluid respectively. When magmatic fluid rose up and entered into crannies of the country rocks, consisting mainly of carbonatite, basin fluid would be constantly added to the magmatic fluid. The two types of fluid were mixed in structural crannies of the sedimentary basin accompanied with periodic geochemical oscillations to form material records in chemical composition zonings of tourmalines.