兼顾主要元素和微量元素的部分熔融模拟计算方法及应用

本文提出了用线性约束条件下的非线性最优化方法,同时拟合部分溶融过程中的主要和微量元素;通过对新疆东天山某些花岗岩类成因的实际模拟计算,取得了良好效果;此方法解决了以往单纯考虑微量元素时难以解决的源岩矿物发生反应、残留相矿物含量难以确定等困难,赋予部分熔融程度更为实际的意义。     

直立堤前海床的局部冲刷

对不规则波作用下直立堤前海床的局部冲刷进行了研究。研究了由于波浪作用导致床面的底沙运动,从而造成提前海床的局部冲刷,即所谓的“相对粒沙”的情况。报导了;(1)堤前海床面为水平、堤下无基床情况下的堤前局部冲刷,以及堤下有明基床时基床尺度对堤前局部冲刷的影响;(2)堤前海床面为斜坡面时堤前的局部冲刷,以及当堤下有明基床时基床尺度对堤前局部冲刷的影响;(3)从波浪作用下床面边界层的理论分析出发,对于在不规则波作用下,离堤面愈远处的冲刷坑深度愈小的事实给出了解释。     

Distribution characteristics of size-fractionated chlorophyll a and primary productivity in Beibu Gulf

The distribution of the abundance of phytoplankton, chlorophyll a (Chl.a) concentration and primary productivity in the Beibu Gulf were observed from May 23 to June 4, 1994.The results show that there were marked featares of spatial zonation in the survey area due to the differences between the geographic environment and the hydrological conditions.Chlorophyll a and primary productivity were higher in the inshore than in the middle area and higher in the north than in the south of the Beibu Gulf.The average concentration of Chl.a, primary productivity and the abundance of phytoplankton were 0.94±0.45 μg/dm³, 351±172 mg/(m²·d) (C) and 0.97×10⁴-10.050×10⁴ ind./m³ in the area, respectively.There were 176 species belonging to 4 phyla and 56 genera based on microscope identification.The results of the size-fractionation show that the contribution of nanoplankton and picoplankton was 77% to total Chl.a and 91% to total primary productivity, which proved their importance to phytoplankton communities in the Beibu Gulf.     

Estimation of standing stock of chlorophylla and primary production from remote-sensed ocean color in the Oyashio region, the Western subarctic Pacific, during the spring bloom in 1997

In order to examine the applicability of remotely-sensed ocean color for the estimation of phytoplankton biomass and primary production in the Oyashio region, the western subarctic Pacific, vertical distributions of chlorophylla concentration and primary production were observed in April and May 1997. Spring bloom was observed in both April and May, and the surface concentration of chlorophylla exceeded 40 mg m⁻³. The relationship between the standing stocks of chlorophylla within the layer from the sea surface to one optical depth (0–1/k layer) and the surface chlorophylla concentration is expressed as a Michaelis-Menten equation. The mean ratio of the standing stock of chlorophylla in the euphotic layer to that in the 0–1/k layer was 4.41, this ratio did not significantly differ from 4.61 which was obtained at homogeneous distribution of chlorophylla within the euphotic layer. These facts suggest that the distribution of chlorophylla could be assumed to be homogeneous in the euphotic layer during the spring bloom. Results of primary production measurements by simulatedin situ method were compared with those by an algorithm with two variables; chlorphylla and non-spectral PAR. Daily primary production in the euphotic layer estimated by the algorithm varied in a range of 38–274% of that estimated by incubation, although the primary productions by the algorithm agreed with those by the incubation at a half of stations. Primary production within the euphotic layer calculated using simply the surface data was the same as that estimated using vertical distribution of chlorophylla. These results show that the primary production in the euphotic layer may be estimated from the remote sensed measurements during the spring bloom in the Oyashio region.     

A record of changing redox conditions in the northern Peru Basin during the Late Quaternary deduced from Mn/Fe and growth rate variations in two diagenetic manganese nodules

Two diagenetic manganese nodules from the Peru Basin were investigated by thermal ionization mass spectrometry and high resolution alpha spectrometry for uranium and thorium. The TIMS concentrations for nodule 62KD (63KG) vary as follows: 0.12–1.01 ppb (0.06–0.59) ²³⁰Th, 0.51–1.98 ppm (0.43–1.40) ²³²Th, 0.13–0.80 ppb (0.09–0.49) ²³⁴U, and 1.95–13.47 ppm (1.66–8.24) ²³⁸U. Both nodules have average growth rates of 110 mm per million years. However, from the variations of excess ²³⁰Th with depth we estimate partial accumulation rates which range from 50 to 400 mm per million years. The δ²³⁴U dating method cannot be applied due to remobilization of U from the sediment and subsequent incorporation into the nodules' crystal lattice, reflected by decay corrected δ²³⁴U values far above the ocean water value. Sections of fast nodule growth are related to those layers having high Mn/Fe ratios (up to 200) and higher densities. As a possible explanation we develop a scenario that describes similar glacial/interglacial trends in both nodules as a record of regional changes of sediment and/or deep water chemistry.     

围岩蚀变过程中地球化学组份质量迁移计算——以湖南沃溪Au-Sb-W矿床为例

在以往围岩蚀变的质量迁移研究基础上,本文提出了一种判定惰性元素的方法,同时结合等浓度线和加权最小二乘法,给出研究热液围岩蚀变中组分质量迁移的计算方法。在判定惰性元素时,更多地应用了线性回归分析中的方差分析与回归诊断参数与计算方法。这一系列的参数与方法被用于评述沃溪金锑钨矿床褪色化围岩蚀变质量迁移,取得了较好的效果。研究表明,在沃溪矿床围岩蚀变过程中,Ｔｉ表出现了一定的活动性。     

珊瑚礁工程地质研究进展

珊瑚礁是发育于热带海洋环境中由生物作用和地质作用共同形成的地质体,是一种特殊的岩土介质类型,有着独特的工程环境特性和工程地质性质。珊瑚礁工程地质研究是现代工程地质学的一个新课题,是近年来为适应珊瑚岛礁工程建设的需求而发展起来的。介绍了珊瑚礁工程地质研究的内容及意义,综述了国内外珊瑚礁工程地质研究的历史现状及其进展,指出应将珊瑚礁体作为工程岩体,进行工程地质环境区带划分及各区带工程地质条件评价;分析礁岩体结构特征和礁体稳定性及其影响因素;分析礁体工程适宜性、地基及其环境与工程活动相互关系。针对珊瑚礁岩土的土力学特点,加强珊瑚礁颗粒破碎机理及其对工程地质性质影响机制的研究;建立能够代表珊瑚礁应力—应变特性的本构关系。     

Primary Product Distributions from the Reaction of OH with m-, p-Xylene, 1,2,4- and 1,3,5-Trimethylbenzene

A study was conducted to examine the OH-initiated degradation products of the four title compounds in the presence of sub-part-per-million levels of NO_x. The oxidation was conducted in a dynamic reactor to minimize the conversion of the aromatic compounds. The experiments were designed to represent reaction pathways that occur in the atmosphere at ambient NO₂ concentrations. A wide range of ring-retaining and ring-cleavage products having widely varying yields were measured during the study. For m-xylene, the major primary products observed (with molar yields) were methyl glyoxal (0.40), 4-oxo-2-pentenal (0.12), glyoxal (0.079), and m-tolualdehyde (0.049). For p-xylene, the major primary products were p-tolualdehyde (0.103), 2,5-dimethylphenol (0.13), cis-3-hexene-2,5-dione (0.176), trans-3-hexene-2,5-dione (0.045), 2-methyl-butenedial (0.071), glyoxal (0.394), and methylglyoxal (0.217). Several other reaction products were measured at yields less than 3%. The primary products for OH + 1,2,4-trimethylbenzene were found as follows: methylglyoxal (0.44), glyoxal (0.066), cis-3-hexene-2,5-dione (0.13), trans-3-hexene-2,5-dione (0.031), biacetyl (0.114), 3-methyl-3-hexene-2,5-dione (0.079), and 2-methyl-butenedial (0.045). Six other (ring retaining) products were measured at yields less than 3%. The primary products for OH + 1,3,5-trimethylbenzene were methylglyoxal (0.90), 3-methyl-5-methylidene-5(2H)-furanone (0.1), 3,5-dimethyl-3(2H)-2-furanone (0.1), 3,5-dimethyl-5(2H)-2-furanone biacetyl (0.08), and 2-methyl-4-oxo-2- pentenal (0.05). Three other products were detected at molar yields less than 5%. In some cases, the yields for the ring fragmentation products could only be based on calibrations from surrogate compounds. Yields for several of the unsaturated dicarbonyl compounds have not been reported previously while yields for methylglyoxal, glyoxal, and biacetyl are largely consistent with previous reports. Some of the primary furanone products are the identical to those reported as secondary products in aromatic systems.     

景观地球化学研究在土壤地球化学测量中的作用

通过对内蒙古大水清金矿区地球化学景观的研究,分析了该地区金矿床的次生晕形成特点,特别是在次生晕中,主要成矿元素Au、Ag等偏低,形成了该区所特有的景观地球化学特点     

恢复沉积构造原始产状要素的微机程序

由于构造变动,改变了沉积岩层的原始水平状态,其中的沉积构造（砾石群或斜层理）的产状也随之发生了变化。因此,恢复其原始产状,是古水流分析的一项重要环节。以往是用吴氏（吴尔福,１９０２）网投影法完成的。现在提供设计的一微机程序,以快速、准确、批量及高效等优点弥补了旧法的诸多不足,为拟创新法的尝试。