A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.     

钱塘江流域的地球化学质量平衡研究

从地球化学角度出发，对钱塘江流域的物质平衡关系及起控制作用的化学风化反应进行了探讨和计算。结果表明，降雨提供了河水中大部分的Ｋ~＋、Ｎａ~＋和ＳＯ~２－＿４。另外，灰岩地区碳酸钙的溶解反应提供了河水中大部分的Ｃａ~２＋和ＨＣＯ~－＿３，硅酸盐岩地区钠长石和黑云母生成高岭石的风化反应提供了剩余的Ｋ~＋、Ｎａ~＋、Ｈ＿４ＳｉＯ＿４和大部分的Ｍｇ~２＋及少量的ＨＣＯ~－＿３。石膏和白云石的风化反应控制了ＳＯ~２－＿４和Ｍｇ~２＋的平衡，其中碳酸钙的溶解反应占主导地位。流域的化学侵蚀率和机械剥蚀率分别为０．０２２和０．０７１（ｋｇ·ｍ－２·ａ－１），碳酸盐岩区的物质流出量是硅酸盐岩区的２倍。     

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.     

北京房山花岗闪长岩体及其附近现今应力状态分析

由本区实测原地应力资料分析认为,总体呈北东走向的八宝山、黄庄-高丽营断裂带总体活动性质为顺时针扭动。断裂带不同地段的实测应力状态各具的特征,不同于京津唐地区实测主压应力的主导方向。运用弹性理论的应力叠加原理计算出断层附近的附加应力状态,则显示了总体呈北东走向的断裂带存在张性反扭活动分量,大灰厂和牛口峪地段断层也存在同样特征。认为自唐山大震后,本区应力状态仍处于调整阶段。测得的较深部位的应力状态也似乎受到了构造活动的影响     

格尔木冲洪积扇地下水锶物质流通量分析

在分析格尔木含锶矿水田供锶环境和水迁移条件的基础上，将形成含锶矿水田的地质空间分为两个区：山区淋溶迁移区和平原迁移聚集区，运用物质流通量分析的观点，对锶的迁移聚集进行了系统分析，山区为锶矿水的形成提供了物质环境，平原区为锶矿水提供了贮存环境。     

重力均衡与质量均衡

均衡理论，无论是艾礼模式，还是普拉特模式，都是建立在平面地壳的基础之上，并不考虑重力随高程的变化；这事实上相当于质量的均衡。如果在球面上考察均衡理论，并且考虑重力随高程的变化，则得到的均衡模型为重力的均衡。定量计算表明，质量均衡和重力均衡之间的差别是不可忽略的。这种差别对研究地壳的应力状态意义重大。     

岩体损伤力学研究进展

论述了岩体损伤力学在岩体力学中的地位，并从细观和宏观两个方面系统介绍了其最新研究进展；对岩体损伤力学研究中的几个重要问题提出了见解，认为分形几何是研究损伤的有效手段。     

甘肃西部地区高放废物处置库场址预选调查

本文根据高放废物处置库场址选择的基本要求，对区域地质及深部构造特征、新构造运动及地震分布规律进行了调查，确定北山南带地区为稳定区。在稳定区内根据处置库有利围岩的出露情况，结合岩体工程地质特征分析，初步选出了４个以花岗岩为主体的场址预选区。经综合分析，认为在４个场址预选区中，以Ｉ号预选区的条件最优，其次是Ⅱ号预选区，再次是Ⅲ号和Ⅳ号预选区。场址区的最后确定尚待进一步调查和论证。     

岩体水力学概述

本文通过伙在工程活动与地质环境相互作用分析，揭示了人类工程、岩体与地下水之间的关系；论述了岩体水力学的研究对象，学科地位，研究内容以及研究方法。     

节理岩体断裂的分形机理研究

本文在考察了节理化岩体的断裂力学特征的基础上，结合现代分形几何原理，建立起追踪裂纹裂分形模型，对不连续岩体的断裂韧性的分形效应进行了深入研究，并通过压剪试验得到难。