Determination of part-per-trillion levels of atmospheric dimethyl sulfide by isotope dilution gas chromatography/mass spectrometry

Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min.     

中国西部干旱地区太阳直接辐射通量密度与大气质量的关系

本文根据中国西部干旱地区大气物理状态(大气可降水量和大气浑浊度)的变化范围,利用太阳直接辐射通量密度的理论计算公式,计算了各种大气透明系数状况下的太阳直接辐射通量密度。计算结果表明,大气质量m=2时的透明系数P_2和m相同时,由于水汽和气溶胶的含量配置不同而引起太阳直接辐射通量密度的差异,在辐射日变程的主要时段(m=1-3)内并不大。于是得到各种透明系数P_2状况下太阳直接辐射通量密度随大气质量变化的平均关系。不同海拔高度比较,当透明系数P_2相同时,各自的大气物理状态虽然不同,但m相同时的太阳直接辐射通量密度基本相同。现有的表征太阳直接辐射通量密度值和大气质量联系的关系式都不能很好地描述计算结果。根据太阳直接辐射通量密度随大气质量变化的特性,我们提出了新的关系式。最后,整理了不同拔海高度和不同地理景观的四个日射站(西藏那曲、青海格尔木、甘肃敦煌和民勤)的多年观测资料。经验计算结果与观测值比较,一致性良好。     

A simple method of estimating rock mass porosity and permeability

Conclusion A simple method of estimating fracture porosity and permeability based on empirical relations between fracture aperture andJRC andJCS can be developed. This shows very close correlation with existing data, using simple discontinuity models. There is quite a good correlation between fracture porosity and permeability and depth for larger initial apertures.     

STUDY OF THE POSSIBILITIES OF USING AN AIR MASS TRANSFORMATION MODEL IN TAIYUAN

An AMT-model,consisting of a trajectory model and a one-dimensional boundary layer model,is tested fortrajectories arriving in Taiyuan to study the possibility of using it in Taiyuan.The sensitivity of the model tothe different processes was studied.Some parameters of the model were modified for the purpose of forecast-ing in specific mountainous terrain and dry climate conditions.Results of examples which we have workedout for Taiyuan circumstances for the periods of July(summer)1985 and January(winter)1986,show that the12h runs of the AMT-model are able to reproduce(on historical data)the sounding of Taiyuan.The AMT-modelcontributes fruitfully to short-range weather forecasts(12—36h ahead)during periods of severe air pollution andwhen cold waves occur.     

The control of the production process of phytoplankton by the physical structure of the aquatic environment with special reference to its optical properties

This tutorial was designed for nonbiologists requiring an introduction to the nature and general timescales of phytoplankton responses to physical forcing in aquatic environments. As such, an effort was made to highlight biological markers which might assist in identifying, measuring and/or validating physical processes controlling the variability in the distribution, abundance, composition and activity of phytoplankton communities. Given the recent advances in environmental optics and remote sensing capabilities, a special emphasis was placed on the nature and utility of phytoplankton optical properties in current bio-optical modelling efforts to predict temporal and spatial variability in phytoplankton productivity and growth.     

On the scavenging of SO2 by cloud and rain drops: IV. A wind tunnel and theoretical study of the absorption of SO2 in the ppb(v) range by water drops in the presence of H2O2

An experimental study involving the Mainz vertical wind tunnel is described where the rate of SO₂ removed from the air by freely suspended water drops was measured for SO₂ concentrations in the gas phase ranging between 50 and 500 ppb, and for various H₂O₂ concentrations in the liquid phase. In a first set of experiments, the pH inside the SO₂ absorbing drops was monitored by means of colour pH indicators added to the drops. In a second set of experiments, the amount of SO₂ scavenged by the drops was determined as sulfate by an ionchromatograph after the drops had been removed from the vertical air stream of the wind tunnel after various times of exposure to SO₂. The results of our experimental study were compared with the theoretical gas diffusion model of Walcek and Pruppacher which was reformulated for the case of SO₂ concentrations in the ppbv(v) range for which the main resistance to diffusion lies in the gas phase surrounding the drop. Excellent agreement between experiment and theory was obtained. Encouraged by this agreement, the theory was used to investigate the rate of sulfate production inside a drop as a function of pH. The sulfate production rate, which includes transport and oxidation, was compared with the production rate based on bulk equilibrium, as cited in the literature.     

Time-dependent behaviour of the rock mass

Summary The strength of intact rock and the rock mass is time-dependent. For intact rock experimental verification is available, for the rock mass the scale of time-dependence is a matter of judgement. Rock mass classifications do however emphasize the effect of time on tunnel stability. This paper examines the source of time-dependence in rocks and the rock mass and suggests a technique for estimating the long term strength. The long term strength of the rock mass is controlled by the time-dependent weakening of intact rock. Frictional resistance, a major source of rock mass strength, increases rather than decreases with time. Lifetime estimation for rocks can be accomplished phenomenologically or mechanistically. The first is a statistical process of wide applicability, the second is more restrictive in usage as its applies only to materials that suffer time-dependent strain (creep). Although the mechanistic route is more appealing, it has a major drawback as it concentrates on steady state creep. There is no strong evidence for steady state creep in rocks. The technique for long term prediction is developed through the analysis of the failure rate under constant load. The failure rate for a given load and environment is established from the frequency distribution of time-to-failure data as measured in static fatigue tests. As expected, the failure rate is strongly affected by both the loading and the environmental condition. The influence, however, is systematic and predictable.     

低Peclet数下剪切流中气溶胶粒子的传质率

本文研究了低Péclet数下剪切流中气溶胶粒子的传质率。Péclet数(Pe)是物质浓度的对流输送项对分子扩散项的比。它等于Reynolds数(Re)与Schmidt数的(Sc)之积。本文应用奇异扰动方法得到了无因次传质率Nu(Nusselt数)在小Péclet数条件下的四项渐近展式，因而?改进了前人的结果。