四川夏塞银铅锌多金属矿床1号矿体原生晕地球化学特征

四川夏塞银铅锌多金属矿床位于西南"三江"义敦岛弧构造带中段,是与绒伊措岩体密切相关的浅成中低温热液型银铅锌矿床。对夏塞矿区1号矿体9个中段采样分析,通过数理统计分析、分带序列研究、地球化学参数计算、建立剥蚀模型等方法,系统详细地研究了矿体原生晕地球化学特征。研究表明:(1)1号矿体原生晕找矿的主要指示元素:Ag、Pb、Zn、Cu、Sb、Hg、Cd、Sn,次要指示元素:Bi、W、B、As、Au、Mn;(2)原生晕轴向分带序列为:Hg-Pb-Bi-Sn-Cd-Zn-Cu-As-Ag-W-Au-Sb-Ba-V-Mo-Mn,出现"反分带"现象;(3)成矿过程存在多次叠加,轴向地球化学参数变化曲折,出现多次转折,反应成矿过程复杂。综合各项特征,推测1号矿体深部可能有盲矿存在。     

构造变形对煤储层孔隙结构与比表面积的影响研究

煤的孔隙结构和比表面积不仅影响煤层气吸附与储集能力,而且对气体渗流和扩散有重要的控制作用。通过对芦岭煤矿8,9煤层煤样低温液氮实验,对比分析了原生结构煤和不同变形强度构造煤的孔隙结构与比表面积的变化。结果表明,构造煤的比表面积和总孔体积平均值是原生结构煤的2.95倍和3.84倍。随着煤体韧性变形强度增加,构造煤的比表面积逐渐增大,微孔占比增加,小孔和中孔占比较少,总孔体积变化以糜棱煤为界呈现先增加后减小的特点。     

石棉尾矿硫酸铵焙烧法提取氧化镁制备碱式碳酸镁的实验研究

基于石棉尾矿中富含氧化镁组分的特点,在矿物学特征研究基础上,采用硫酸铵焙烧法提取氧化镁,利用浸出液硫酸镁制备碱式碳酸镁。采用XRD、SEM、FT-IR和TG-DTA对不同温度条件下所获得的产物的物相、形貌、分子振动光谱和热效应变化等特征进行了分析和表征。结果表明:利用硫酸铵焙烧产物的浸取液,在低于65℃的水溶液中所制备的产物为针状水合碳酸镁;在高于85℃时制备的产物为片状碱式碳酸镁;在75℃温度时形成短柱状或颗粒状水合碳酸镁和片状碱式碳酸镁的混合物。对水合碳酸镁加热,在100℃脱去部分水合水和二氧化碳后转变为片状碱式碳酸镁。研究结果对石棉尾矿的资源化利用和环境保护具有一定的理论和实际意义。     

陕西省略阳县铧厂沟金矿床主矿带地球化学原生晕特征及其地质意义

陕西省铧厂沟金矿是一个主要赋存于海底基性火山喷流细碧岩中的金矿床。在野外地质工作的基础上,对主矿带样品的测试数据进行了数学地质分析和原生晕分带序列计算。结果表明,Au11矿体的原生晕轴向分带序列从上至下为:Hg-Sb-Ni-As-Bi-Cu-Au-Co-Zn-W-Mo-Mn-Pb-Ag-Cd;Au8矿体的原生晕轴向分带序列从上至下为:Cu-Co-W-Au-Ni-Sb-Mn-As-Pb-Bi-Hg-Mo-Ag-Zn-Cd;并提出了主矿带理想原生晕分带序列:Sb-As-Cu-Hg(前缘晕)→Au-Ag-Bi-Pb-W(近矿晕)→Ni-Co-Mn-Mo-Zn-Cd(尾晕)。结合微量元素衬值空间变化规律,建立了2个矿体的原生晕叠加理想模型。Au11矿体在1 150 m中段以前缘晕和尾晕叠加为特征;在1 110 m中段,发育较强的尾晕。Au8矿体在1 150 m和1 070 m中段以前缘晕和尾晕叠加为特征;在1 110 m中段,矿体减薄,近矿晕减弱,发育很弱的前缘晕和尾晕。综合分析认为,Au11矿体到达中下部,向深部仍有一定延伸;Au8矿体已经接近尾部,深部可能存在新的矿体。     

Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 microug L(-1) Irgarol vs. > 200 microg L(-1) M1; S. costatum, 0.29 microg L(-1) Irgarol vs. 11.32 microg L(-1)M1; and T. pseudonana, 0.41 microg L(-1) Irgarol vs. 16.50 microg L(-1)M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.     

石墨炉原子吸收法测定地球化学样品中痕量银

本文采用石墨炉原子吸收光谱法测定地球化学样品中痕量银。选择硝酸镁和硫脲混合溶液为基体改进剂,银的灰化温度为800℃,研究了最佳的分析测定条件。该方法检出限为0．01μg／g。用该方法对国家地球化学标准样品的测定结果与标准值相符。     

主成分分析法在林甸Ms5．1地震回顾性预测中的应用

用2005年林甸Ms5．1级地震前后震中附近的地震资料,选择与地震强度有关的3级以上地震频次N、b值、Mf值、C值、和Ac值等6个参量进行主成分分析,实现对上述参量的有效约简。这6个参量之间有一定的相关性,各参量在不同时段的变化各有所异,预报效果并不理想。但是根据主成分分析可以得到反映地震强度的综合指标W,发现该指标在震源区附近出现明显的异常变化,震后异常恢复。表明综合指标W可以较好的反映地震活动的异常特征。     

Response of the shortgrass steppe plant community to fire

Fire is an important driver of ecological pattern and process in grasslands worldwide, although its role in semi-arid systems is less well known. We used published studies and new experimental research to 1) provide a synthesis of existing knowledge of fire in the semi-arid grasslands of the North American Great Plains, and 2) assess the degree of similarity in semi-arid and mesic grassland responses to fire in this region. Based on published studies, burning has neutral to negative effects on aboveground productivity in semi-arid grasslands and variable effects on plant communities. To more rigorously assess fire effects, replicated experimental plots were established in ungrazed shortgrass steppe in northern Colorado and prescribed spring fire was applied in 2006 and 2007, 2006 only, or not at all. Aboveground net primary productivity decreased or remained unchanged with burning. Plant community changes included increases in perennial forbs, decreases in annual grasses and a positive response in annual forbs to the combination of fire and a wet spring in 2007. Combined, these results indicate that post-fire changes in productivity in semi-arid grasslands are neutral to negative, in contrast to positive responses in mesic grasslands, and not strongly negative as previously assumed.     

硫酸钾镁肥防结块剂的开发研究

分析了青海中信国安科技发展有限公司生产的"国安"牌硫酸钾镁肥产品在生产和运输中产生的结块现象,针对硫酸钾镁肥产品产生结块的原因,开发研制了一种主要成分为阴离子表面活性剂(分子的活性部分有一个带负电荷的离子如磺酸盐、烷基芳基磺酸盐、烷基磺酸盐和脂肪酸铵盐等)的防结块剂产品。     

油气初次运移理论新探

应用渗流力学的基本原理,研究油气初次运移的机制问题。研究认为,油气的初次运移是以连续相、而不是以溶液相和扩散相的形式进行的;油气初次运移的动力是浮力,因而初次运移的方向是向上的;油气初次运移所需的时间与源岩的渗透能力有关,与油气的粘度有关,还与源岩的厚度有关;油气藏的异常高压是一种暂时的压力状态,气藏的异常高压多于油藏,新生油气藏多于古油气藏;油气初次运移的通道就是源岩的粒间孔隙,源岩的非均质性和微裂缝对油气初次运移十分不利,因形成微油气藏而降低油气运移效率;源岩的厚度越大,越有利于油气聚集;“倒灌”现象是不存在的,缺少基本的动力驱动,基岩油气藏的形成是二次运移过程中侧向运移的结果。初次运移与二次运移具有相同的动力机制、运移相态和运移方向,因而两者是完全统一的。