Composition and pre-metamorphic geodynamic setting of the ultrahigh-pressure metabasic rocks from Dabie Shan,E-China

As part of the Yangtze plate, segments of the Dabie Shan terrane of Central China underwent ultra-high pressure metamorphism during Triassic subduction. We studied the geochemistry of the abundant eclogites to evaluate the nature of the protoliths and their geodynamic setting. Although some previous geochemical work exists, the analyses and interpretation herein are based on a new subdivision of the ultra-high pressure sequence into basement and cover units (Changpu and Ganghe Unit), revealing new and important results. In addition, eclogites of the so-called HP Unit south of the UHP units were studied. Whereas the large ion lithophile elements indicate postmagmatic, metasomatic changes of some samples, the high-field strength elements and the rare earth elements display original magmatic trends. The geochemical characteristics of the eclogites of the ultra-high pressure areas display a strong dependence on their “structural” and geographic position. The eclogites of the basement and the Changpu Unit indicate melt intrusion and extrusion in a continental rift system, i.e. during extensional tectonics. In contrast, the Ganghe Unit is characterized by a pronounced chemical homogeneity. The composition of the eclogites indicates generation from a mantle source highly influenced by slab-derived fluids. Those of the HP Unit show similar characteristics. Magmatism of the Ganghe and HP Unit probably occurred in a continental arc setting. A similar age for both units, geographically and/or tectonically separated, is possible. The geodynamic interpretation based on the geochemistry of the four units points to a Neoproterozoic scenario in which the protoliths of the HP and the cover units could have been of similar age and deposited in one evolving geological system. A rift-related larger-scale basin might have formed, e.g. a continental back-arc basin behind a magmatic arc after or simultaneous to sedimentation and magmatism in the magmatic arc. Alternatively, magmatism occurred in independent geodynamic settings, distinct in time and space. The units were juxtaposed during exhumation, after subduction to varying depths.     

双作用水泵泡沫增压装置应用及前景分析

双作用水泵泡沫增压装置是利用双缸双作用水泵的高压能力将低压空气和泡沫液二次增压至水泵的额定压力,并混合产生泡沫.采用BWZ-1200双作用水泵泡沫增压装置在北京地区深度为1 000 m以下的地热井钻探中,成功地克服了地热井钻进中井内漏失和洗井的难题;在极度缺水的宁夏南部地区水井钻探中,采用BWZ-1100双作用水泵泡沫增压装置解决了水井孔内严重漏失和施工用水的难题.该装置可代替价格昂贵的高压空压机实现气举反循环钻探,应用于深地热井、深水井和油气井钻探.     

煤炭采空区处理的新方法与实例分析

位于乌鲁木齐市南湖路以西的煤炭采空区面积达67 100.5m^2,区内构造从南到北主要由八道湾向斜和七道湾背斜组成,地层产状变化不大。该矿区开采较深,且采空区塌陷区有明显的地下水活动迹象。在对深孔大体积采空区注浆时,比较各种常见注浆治理方法,均存在不同的制约因素,故决定采用灌浆爆破压密法对采空区进行压实加固。经现场爆破试验,该区重复爆破次数在3～5次左右。灌浆爆破压密处理后,对不同土层进行取样对比分析,得到其相应密度（增加）及空隙比（减少）的变化分别为：杂填土14.1%,-7.9%;素填土5.9%,-3.3%;塌落煤层7.8%,-7.7%。根据压缩数据及现场测量,处理后的土体沉降2～4m,部分空体地段的沉降量达10～20m,治理效果明显。     

Upper Cretaceous carbonate hosted zinc–lead–barite deposits in Northern Thrust Zone, northern Iraq: petrography and geochemistry

Zinc–lead–barite deposits located in Lefan and Lower Banik localities of about 25 km northeast of Zakho City, Northern Iraq consist of a group of strata-bound sulfides hosted in Upper Cretaceous (Upper Campanian–Maastrichtian) dolomitic limestone. Carbonate-hosted ores contain 3.77% Zn, 2% Pb, and 5% Fe, while in lower Banik, they contain 1.5% Zn, 0.37% Pb, and 1.4% Fe. Diagenetic processes, such as dolomitization and recrystalization in addition to the type of microfacies, provided appropriate physical and chemical conditions that permitted the passage of ore-bearing fluids and participated in precipitation and ore localization. These deposits are precipitated in a platform and developed within the Foreland Thrust Belt. Ore precipitated as infill of intergranular dolomite porosity with replaced dolomite and rudist shells forming disseminated crystals that occupy intergranular pore spaces around dolomite and calcite and as infill of dissolution spaces and fractures.     

浅谈（TCP）射孔技术在松辽地区应用与发展

油管传佃式射孔是近几年来射孔新技术,应用于石油、天燃气勘探、开发井中。的使用,大大提高了油气井的射孔效率,增加油气产量,降低了作业成本,从而能获得较好的经济效益,解决了正压射孔存在的不足,是一项新的负压射孔方式。通过几年来在松辽地区的应用,效果很佳。大部分的高产油气流都是采用这种射孔方法进行的。     

Variation in the composition of Lake Bonneville marl: a potential key to lake-level fluctuations and paleoclimate

Lake Bonneville marl provides a stratigraphic record of lake history preserved in its carbonate minerals and stable isotopes. We have analyzed the marl in shallow cores taken at three localities in the Bonneville basin. Chronology for the cores is provided by dated volcanic ashes, ostracode biostratigraphy, and a distinctive lithologic unit believed to have been deposited during and immediately after the Bonneville Flood.A core taken at Monument Point at the north shore of Great Salt Lake encompasses virtually the entire Bonneville lake cycle, including the 26.5 ka Thiokol basaltic ash at the base and deposits representing the overflowing stage at the Provo shoreline at the top of the core. Two cores from the Old River Bed area near the threshold between the Sevier basin and the Great Salt Lake basin (the main body of Lake Bonneville) represent deposition from the end of the Stansbury oscillation ( 20 ka) to post-Provo time ( 13 ka), and one core from near Sunstone Knoll in the Sevier basin provides a nearly complete record of the period when Lake Bonneville flooded the Sevier basin (20–13 ka).In all cores, percent calcium carbonate, the aragonite to calcite ratio, and percent sand were measured at approximately 2-cm intervals, and ¹⁸O and ¹³C were determined in one core from the Old River Bed area. The transgressive period from about 20 ka to 15 ka is represented in all cores, but the general trends and the details of the records are different, probably as a result of water chemistry and water balance differences between the main body and the Sevier basin because they were fed by different rivers and had different hypsometries. The Old River Bed marl sections are intermediate in position and composition between the Monument Point and Sunstone Knoll sections. Variations in marl composition at the Old River Bed, which are correlated with lake-level changes, were probably caused by changes in the relative proportions of water from the two basins, which were caused by shifts in water balance in the lake.This is the second paper in a series of papers published in this issue on Climatic and Tectonic Rhythms in Lake Deposits.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

大别杂岩中混合岩的矿物空间分布研究

介绍了矿物空间分布研究的基本原理及两种统计方法(接触频数法和线切法)。作者对混合岩矿物空间分布的研究表明:(1)前人提出的统计方法存在方法上的缺陷和应用上的局限性,作者推导出矿物接触类型的概率公式;(2)部分浅色体中矿物显示聚集分布的特征,而绝大部分的浅色体中矿物具有分散分布的特点。结合质量平衡和地球化学研究认为:大别杂岩中主体混合岩成因机制是重熔和交代作用。     

Tectonometamorphic evolution of the Bohemian Massif: evidence from high pressure metamorphic rocks

The Variscan orogenic belt, of which the Bohemian Massif is a part, is typically recognized for its characteristic low pressure, high temperature metamorphism and a large volume of granites. However, there are also bodies of high pressure rocks (eclogites, garnet peridotites and high pressure granulites) which are small in size but widely distributed throughtout the Massif. Initially the high pressure rocks were considered to be relicts of a much older orogenic event, but the increasing data derived from isotopic and geochronological investigations show that many of these rocks have Palaeozoic protoliths. Metamorphic ages from the high pressure rocks define no single event. Instead, a number of discrete clusters of ages are found between about 430 Ma and the time of the dominant low pressure event at around 320–330 Ma.Most of the eclogite and granulite facies rocks are assigned to allochthonous nappes that arrived close to the end of the low pressure event, but before final granite intrusion. The nappes contain a mixture of different units and the relationship between rocks with high pressure relicts and host gneisses with no apparent signs of deep burial is still problematic. Some of the high pressure rocks retain evidence of multiple stages of partial re-equilibration during uplift. Moreover, it can be shown in certain instances that host gneisses also endured a multistage metamorphic development but with a peak event convergent with one of the breakdown stages in the enclosed rocks with high pressure relicts. It thus appears that the nappe units are composite bodies probably formed during episodic intracrustal thrusting. Fluids derived from prograde dehydration reactions in the newly under thrusting slab are taken to be the catalysts that drove the partial re-equilibrations.On the scale of the whole Massif it can be seen within the units with high pressure relicts that the temperature at the peak recorded pressure and that during the breakdown are variable in different locations. It is interpreted that regional metamorphic gradients are preserved for given stages in the history and thus the present day dismembered nappe relicts are not too far removed from their original spatial distribution in an original coherent unit. From the temperature information alone it is highly probable that the refrigerating underthrusting slab was situated in the north-west. However, this north-west to south-east underthrusting probably represents the major 380–370 Ma event and is no guide to the final thrusting that emplaced the much thinned nappe pile with high pressure relicts.Granite genesis is attributed to the late stage stacking, during the final Himalayan-type collision stage, of thinned crust covered by young, water-rich, sediments — erosion products of the earlier orogenic stages. Regional metamorphism at shallow depths above the voluminous granites was followed by final nappe emplacement which rejuvenated the granite ascent in places. Correspondence to: P. J. O'Brien     

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。