Ultraviolet absorption cross-sections of chloro and chlorofluoro-methanes at stratospheric temperatures

Absorption cross-sections of nine halomethanes (CCl₄, CHCl₃, CH₂Cl₂, CH₃Cl, CFCl₃, CF₂Cl₂, CF₃Cl, CHFCl₂, and CHF₂Cl), measured between 174 and 250 nm for temperatures ranging from 225 to 295 K, are presented with uncertainties ranging from 2 to 4% and compared with previous determinations made for comparable temperature ranges.The largest temperature effect which takes place near the absorption threshold, decreases the absorption cross-section up to 50% for highly chlorinated methanes, but is negligible for molecules highly stabilized by hydrogen and/or fluorine. Extrapolated values for temperatures of aeronomical interest are presented, as well as parametrical formulas which give absorption cross-section values for given wavelength and temperature ranges.     

钇铝石榴石晶体高压相变研究

采用金刚石压砧高压设备,对立方结构掺钕钇铝榴石多晶进行高温高压相变研究。实验分同时加温加压、独立加压、独立加温三类。对压力温度作用后相变产物进行了 X 射线衍射研究,对相变前后样品的配位数、晶体结构、晶胞参数、体积、密度进行了对比。     

漳州地热普查区地球化学异常的讨论

本文以漳州热田为例,通过对该区的地质及构造特征、地下热水分布、水化学特征及土壤地球化学异常的分析对照,论证了化探工作在地热勘查中的应用效果。同时,对热田的化探异常成因进行了初浅的探讨。     

Attenuation of compressional waves in peridotite measured as a function of temperature at 200 MPa

A technique has been developed to determine attenuation in rocks at high temperature using a gas-media, high-pressure apparatus. A pulse transmission technique and a spectral ratio method are used to study compressional seismic properties of rocks. Seismic waves are transmitted to and from the sample through buffer rods of mullite. The effect of seismic wave reflections within the sample assembly are cancelled out by taking ratios of the spectra measured at different temperatures. In order to obtain good signal-to-noise ratio for resolving the attenuation at high pressure and temperature, special care is taken in the sample assembly and the ultrasonic coupling between the sample, buffer rods and transducers. A very tight connection of the sample-buffer rod-transducer is essential for obtaining high frequency signals (>300 kHz) at high temperature. A small mass is attached to each outside end of the transducer to drive low frequency signals (<250 kHz) into the sample. Before attenuation measurements, the sample and the buffer rods are tightly compacted in a platinum tube at high pressure and room temperature to ensure pressure seal of the sample assembly. The frequency range of measurement covers 50 to 450 kHz for the sample. Attenuation is very small in the buffer rod compared to the sample for the entire temperature range of the study. Because of the small attenuation, a wide frequency band of 50 kHz to 3.2 MHz can be covered for investigating the attenuation in the buffer rod. The technique has been used to measure attenuation at high confining pressure, and temperatures including sub- and hyper-solidus of upper mantle rocks. Therefore, effects of partial melting on attenuation can be studied.The method is applied to the attenuation measurement in a peridotite as a function of temperature to 1225°C at 200 MPa confining pressure. At high temperature, signal amplitude decays more rapidly at high frequency than at low frequency, from which attenuation (andQ) can be determined using a spectral ratio method. No frequency dependence ofQ is resolved for both the sample and the buffer rod over the entire temperature and frequency ranges of the measurement. The results show thatQ decreases rapidly with increasing temperature even in the temperature range below the solidus of peridotites. Such temperature sensitivity ofQ is probably more useful to probe thermal structure in the upper mantle than that of conductivity at temperatures below the solidus. The results in this study are compared with available seismic velocity, electrical conductivity and solidus data for peridotites, suggesting that there is no discontinuous change in both mechanical and electrical properties of peridotites at the solidus temperature. Even at hypersolidus temperatures, it appears that velocity drops and conductivity increases continuously (not abruptly) with increasing melt fraction. This implies that mechanical and electrical properties of the upper mantle will gradually change at the boundary where the geotherm crosses the solidus.     

Diurnal freeze–thaw depth in rockwalls: Field measurements and theoretical considerations

Rock temperatures were monitored for a year at two alpine rockwalls in the Akaishi Range, Japan, where permafrost is absent. Diurnal frost and thaw penetration depths were evaluated from subsurface isotherms drawn on the basis of the temperature records at 0, 10 and 40 cm depths. The surface of the rockwalls experienced more than 100 diurnal freeze-thaw cycles, most of which accompanied a frost or thaw penetration shallower than 50 cm, and several long duration cycles with deeper frost or thaw penetration. Theoretical frost and thaw depths were also calculated by incorporating the surface freezing indices into the modified Berggren equation, the results from which were then compared with the actual values. The modified Berggren equation provided values that showed a strong correlation with observed depths, despite somewhat underestimating the actual values. Using the modified Berggren equation, the seasonal frost depth in the observed winter was estimated to be about 4·5 m. The frost and thaw depths are considered to give the maximum estimation of the depth to which frost-induced cracking can propagate in the bedrock.     

矿物热敏参数测试仪及其在地质找矿中的应用

介绍了国内外第一台矿物热敏参数测试仪研制的原理、应用范围和对一些金属矿物、半导体矿物的测试情况以及仪器在浙江、赣南等地区金矿找矿中的初步应用。     

四川盆地紫色土温度状况的确定

以气象资料为基础，为土壤系统分类的需要，估计了四川盆地紫色土的温度状况，采用逐步回归方法，从与土温相关的１０项气象因素中，筛选出６项主要影响因素。根据本区土层浅薄的特点，建立了不同深度土层的土温计算方程。计算结果表明，按土壤系统分类的土温状况诊断标准，本区拥有热性土壤温度状况。     

区域次生地球化学负异常模型及其意义

原生地球化学负异常的研究已经引起重视,特别是前苏联的化探工作者还总结出利用地球化学原生负异常对热液矿床进行普查和评价的准则.但是,由于缺乏可供对比的划分负异常的适当方法,使得对负异常的研究不能系统化,研究结果也不能互相对比,尤其是对于区域水系沉积物测量中发现的负异常研究很少.本文通过对几个地区衬值负异常的分析,系统地探讨了区域性负异常的分布特征、负异常与正异常的关系、负异常的地质意义和找矿信息等.总结出单元素和多元素区域负异常的分布模型.建立了AU和Cu矿床的区域正负、异常模型.提出了地球化学异常是由正异常和负异常组成的.     

我国月平均气温场遥相关结构的观测研究

研究了我国月平均气温场的遥相关结构。指出，我国冬季月份的气温场的跷跷板特征不明显。夏季月季有明显的遥相关结构。给出了各月的遥相关模态及强度。指出，月平均气温遥相关表现为从南向东北，西北方向的辐射状。在１０５°Ｅ以东呈东北－西南向。在１０５°Ｅ以西呈西北－东南向。这种遥相关结构是由环流异常造成的。而且可以在区域的月平均气温场预报中使用。