表面活性剂的应用研究—：——动力学光度法测定痕量硒蹄

研究了表面活性剂在Ｓｅ和Ｔｅ诱导反应中的作用,对反应机理进行了初步探讨。实验表明,在选定条件下,加入适量非离子表面活性剂Ｔｗｅｅｎ－８０,使Ｔｅ的诱导反应速度加快,灵敏度提高１倍,并利用其对Ｓｅ有抑制反应速度的作用,使Ｔｅ对Ｓｅ的抗干扰能力增强。阴离子表面活性剂十二烷基苯磺酸钠对Ｓｅ和Ｔｅ均有加速反应的作用,Ｓｅ的灵敏工提高１．３倍：Ｔｅ的灵敏主提高４０％。基于此,所建立的中用于地质样品中纳克级Ｓ     

Review of the Tropical Gyre in the Indian Ocean with Its Impact on Heat and Salt Transport and Regional Climate Modes

Due to the IO monsoon impact, the tropical IO circulation has significant seasonal variation, especially in the northern IO. However, in mean-state, a relatively closed current loop is established by eastward current along the equator and westward current south of equator, which is regarded as Tropical Gyre in the Indian Ocean. Based on this circulation system, relevant studies were reviewed. Its impact on heat and salt transports and regional climate changes were discussed.     

Evaporites,brines and base metals: Low‐temperature ore emplacement controlled by evaporite diagenesis

Salt beds and salt allochthons are transient features in most sedimentary basins, which through their dissolution can carry, focus and fix base metals. The mineralisation can be subsalt, intrasalt or suprasalt, and the salt body or its breccia can be bedded or halokinetic. In all these evaporite‐associated low‐temperature diagenetic ore deposits there are four common factors that can be used to recognise suitably prepared ground for mineralisation: (i) a dissolving evaporite bed acts either as a supplier of chloride‐rich basinal brines capable of leaching metals, or as a supplier of sulfur and organics that can fix metals; (ii) where the dissolving bed is acting as a supplier of chloride‐rich brines, there is a suitable nearby source of metals that can be leached by these basinal brines (redbeds, thick shales, volcaniclastics, basalts); (iii) there is a stable redox interface where these metalliferous chloride‐rich waters mix with anoxic waters within a pore‐fluid environment that is rich in organics and sulfate/sulfide/H₂S; and (iv) there is a salt‐induced focusing mechanism that allows for a stable, long‐term maintenance of the redox front, e.g. the underbelly of the salt bed or allochthon (subsalt deposits), dissolution or halokinetically maintained fault activity in the overburden (suprasalt deposits), or a stratabound intrabed evaporite dissolution front (intrasalt deposits). The diagenetic evaporite ‐ base‐metal association includes world‐class Cu deposits, such as the Kupferschiefer‐style Lubin deposits of Poland and the large accumulations in the Dzhezkazgan region of Kazakhstan. The Lubin deposits are subsalt and occur where long‐term dissolution of salt, in conjunction with upwelling metalliferous basin brines, created a stable redox front, now indicated by the facies of the Rote Faule. The Dzhezkazgan deposits (as well as smaller scale Lisbon Valley style deposits) are suprasalt halokinetic features and formed where a dissolving halite‐dominated salt dome maintained a structural focus to a regional redox interface. Halokinesis and dissolution of the salt bed also drove the subsalt circulation system whereby metalliferous saline brines convectively leached underlying sediments. In both scenarios, the resulting redox‐precipitated sulfides are zoned and arranged in the order Cu, Pb, Zn as one moves away from the zone of salt‐solution supplied brines. This redox zonation can be used as a regional pointer to both mineralisation and, more academically, to the position of a former salt bed. In the fault‐fed suprasalt accumulations the feeder faults were typically created and maintained by the jiggling of brittle overburden blocks atop a moving and dissolving salt unit. A similar mechanism localises many of the caprock replacement haloes seen in the diapiric provinces of the Gulf of Mexico and Northern Africa. Evaporite‐associated Pb–Zn deposits, like Cu deposits, are focused by brine flows associated with both bedded and halokinetic salt units or their residues. Stratabound deposits, such as Gays River and Cadjebut, have formed immediately adjacent to or within the bedded salt body, with the bedded sulfate acting as a sulfur source. In allochthon/diapir deposits the Pb–Zn mineralisation can occur both within a caprock or adjacent to the salt structure as replacements of peridiapiric organic‐rich pyritic sediments. In the latter case the conditions of bottom anoxia that allowed the preservation of pyrite were created by the presence of brine springs and seeps fed from the dissolution of nearby salt sheets and diapirs. The deposits in the peridiapiric group tend to be widespread, but individual deposits tend to be relatively small and many are subeconomic. However, their occurrence indicates an active metal‐cycling mechanism in the basin. Given the right association of salt allochthon, tectonics, source substrate and brine ponding, the system can form much less common but world‐class deposits where base‐metal sulfides replaced pyritic laminites at burial depths ranging from centimetres to kilometres. This set of diagenetic brine‐focusing mechanisms are active today beneath the floor of the Atlantis II Deep and are thought to have their ancient counterparts in some Proterozoic sedex deposits. The position of the allochthon, its lateral continuity, and the type of sediment it overlies controls the size of the accumulation and whether it is Cu or Pb–Zn dominated.     

靖边气田北部上古生界储层微观孔隙结构及其对生产动态影响

靖边气田北部盒8、山1段砂岩气藏气井投产存在井筒积液、稳产时间短等问题.通过扫描电镜、铸体薄片、常规压汞等技术对储层岩样进行了测试分析,研究了岩石学特征和孔隙类型.将其微观孔隙结构分为4类并研究了微观孔隙结构特征和气井生产动态的关系.研究表明,盒8、山1段储层的孔隙类型主要为溶孔、晶间微孔,孔隙组合类型主要为晶间微孔、...     

地质导向技术在L型煤层气水平井 T-P05井中的应用

通过分析山西L型煤层气水平井的技术难点,着重建立造斜着陆与水平段导向两大导向模型,形成了以标志层划分与对比、地层倾角推算、地质建模和实时轨迹控制四个方面为主的L型煤层气水平井地质导向技术流程,该技术在T-P05井的成功应用,不仅丰富了煤层气水平井地质导向技术的内容与方法,更进一步验证了该技术在现场具有较强的可操作性和良好的应用前景,值得大力推广。     

Evolution of the Extensional Rifted Yunnan-Guizhou-Guangxi Oceanic Basin During the Late Hercynian to Middle Indosinian Stage

On the basis of exhaustive researches on the facies sequences and depositlonal evolutionary process of various depositional systems, the genetic stratigraphic framework of the extensional rifted oceanic basin, which has undergone strong structural destruction, has been reconstructed by means of dynamic genetic stratigraphic analysis. Five depositional episodes have been distinguished from various isochronous stratigraphic boundaries and stratigraphic sequences with the three-dimensional structure of each depositional episode analysed in detail. The tectonic paleogeographic environment corresponding to different stages of each depositional episode has been reconstructed for individual depositional system tracts. And the evolution history of this rifted basin has been divided into four stages' initial rifting and oceanization of continental crust, stretching and spreading of the basin, subduction and basin differentiation, and convergence and collision. A NNE-trending intracontinental soft collision sutur     

井筒与油藏耦合的压裂水平井非稳态产能计算模型

为了准确预测压裂水平井的产量,综合考虑流体在储层、井壁、压裂裂缝、射孔孔眼以及水平井筒中的流动过程,根据势叠加原理,建立了考虑射孔孔眼、压裂裂缝生产干扰作用下的井筒、油藏耦合压裂水平井非稳态产能计算模型。结果表明:只考虑裂缝生产与裂缝、孔眼同时生产时的水平井产量在生产初期差别较大,生产后期差别变小;由于裂缝、孔眼的干扰,水平井筒两端裂缝的产量高于中间裂缝的产量;由于井筒摩阻作用,关于水平井筒中心对称的裂缝流量不相等;随着裂缝长度增加,裂缝、射孔孔眼、水平井产量增大;随着裂缝导流能力增加,裂缝产量增大,射孔孔眼产量降低,水平井产量增大;射孔段越长,孔眼与裂缝的干扰愈强,单个孔眼的产量降低,但由于射孔数增加,水平井产量增大;射孔深度增加,压裂水平井产量增加。     

浅议测井曲线在松树头煤矿含水层解释中的应用

以松树头煤矿水文地质勘查为例,介绍了测井曲线在含水层解释中的应用。实例表明,自然伽马、自然电位和视电阻率三种曲线对含水层具有明显的异常反应,在含水层中,前二种曲线表现为负异常,后者表现为正异常;对于隔水层,前二种曲线则表现为正异常,而视电阻率表现为负异常。根据测井解释成果与钻孔消耗量、岩心及抽水试验资料相互印证,解释松树头煤矿ZK5-2钻孔368.30～406.42m段,从上到下依次为含水层、隔水层、含水层、隔水层四段。另外,从实例应用的三种曲线可知,视电阻率曲线对于岩石粒度及含水层具有明显的响应特征,极差高达117Ω.m。     

ADM6-4H井四开水平段钻井液技术

ADM6-4H井是AHDEB油田使用常规随钻测量仪器（MWD）和螺杆动力钻具组合完成的一口水平段长度1500 m、最大水平位移1915.17 m的6 in小井眼大位移水平井,也是AHDEB油田目前水平位移最大的一口水平井。该井四开水平段钻进使用聚磺混油钻井液体系,在携砂、井眼稳定和润滑减阻等方面效果突出。四开水平段钻速快,钻进扭矩小,钻井液性能稳定,无井壁失稳,无漏失,无卡钻,无托压,其经验技术值得借鉴。     

密集交叉井网井眼轨道精确制导技术的应用

本着充分依托原有海上油田设施降本增效原则,渤海Q油田在原有生产平台附近新建井口平台、对原有密集井网成功实施了整体加密调整,作业难度急剧增大。通过老井眼数据再处理、新井轨道设计优化、轨道防碰设计、防碰监测等手段形成密集交叉井网井眼轨道精确制导技术。该技术的成功应用提高了作业时效,有效保障了在老油田密集交叉井网整体加密井眼轨迹的顺利实施、减小了碰撞风险。