豫西小秦岭地区太华杂岩中花岗质片麻岩的元素地球化学及其构造意义

豫西小秦岭地区太华杂岩中花岗质片麻岩为古老侵入岩,主要由黑云斜长片麻岩、黑云钾长片麻岩和黑云二长片麻岩等类型岩石组成,具有ＴＴＧ岩系的组成特征,元素地球化学特征反映其形成于类似现代板块碰撞带的构造环境．     

铟-1-苯基-3-甲基-4-苯甲酰基吡唑啉酮-5-安替比林体系络合吸附波的研究

在ｐＨ４５的ＨＡｃ＿ＮａＡｃ介质中,Ｉｎ＿１＿苯基＿３＿甲基＿４＿苯甲酰基吡唑啉酮＿５（ＰＭＢＰ）＿安替比林体系于－０５７Ｖ（ｖｓ．ＳＣＥ）处产生一良好的极谱波。Ｉｎ在００１～０５ｍｇ／Ｌ与波高呈线性关系。检出限０１μｇ／Ｌ。实验证明,该波为可逆的络合物吸附波,络合物中的电还原体为中心离子Ｉｎ３＋。Ｉｎ３＋与ＰＭＢＰ的组成比为１∶２。在不改变峰电位的情况下,安替比林使Ｉｎ＿ＰＭＢＰ＿ＨＡｃ＿ＮａＡｃ体系的极谱波高显著增加,波形变得非常尖锐对称。探讨了安替比林增敏作用机理。     

山西孙家庄中酸性杂岩体及其邻近地区的找矿远景评价

通过“面型”岩石测量和多子样剖面岩石测量,对山西孙家庄中酸性杂岩体作出找矿远景评价,并对其邻近地段进行矿化追踪。确定该岩体的主要指示元素和伴生元素,圈出以Cu为主的斑岩矿化多元素组合异常,在Cu异常浓集中心发现斑岩矿化。孙家庄岩体周围地区,存在斑岩型矿化—接触交代矿化—热液多金属矿化的环带状分布模式。     

Tectonic implications of new age data for the Meratus Complex of south Kalimantan, Indonesia

Cretaceous subduction complexes surround the southeastern margin of Sundaland in Indonesia. They are widely exposed in several localities, such as Bantimala (South Sulawesi), Karangsambung (Central Java) and Meratus (South Kalimantan).
The Meratus Complex of South Kalimantan consists mainly of mélange, chert, siliceous shale, limestone, basalt, ultramafic rocks and schists. The complex is uncomformably covered with Late Cretaceous sedimentary-volcanic formations, such as the Pitap and Haruyan Formations.
Well-preserved radiolarians were extracted from 14 samples of siliceous sedimentary rocks, and K–Ar age dating was performed on muscovite from 6 samples of schist of the Meratus Complex. The radiolarian assemblage from the chert of the complex is assigned to the early Middle Jurassic to early Late Cretaceous. The K–Ar age data from schist range from 110 Ma to 180 Ma. Three samples from the Pitap Formation, which unconformably covers the Meratus Complex, yield Cretaceous radiolarians of Cenomanian or older.
These chronological data as well as field observation and petrology yield the following constraints on the tectonic setting of the Meratus Complex.
(1) The mélange of the Meratus Complex was caused by the subduction of an oceanic plate covered by radiolarian chert ranging in age from early Middle Jurassic to late Early Cretaceous.
(2) The Haruyan Schist of 110–119 Ma was affected by metamorphism of a high pressure–low temperature type caused by oceanic plate subduction. Some of the protoliths were high alluminous continental cover or margin sediments. Intermediate pressure type metamorphic rocks of 165 and 180 Ma were discovered for the first time along the northern margin of the Haruyan Schist.
(3) The Haruyan Formation, a product of submarine volcanism in an immature island arc setting, is locally contemporaneous with the formation of the mélange of the Meratus Complex.     

四川石棉草科穹状岩浆核杂岩构造特征

位于扬子陆块西缘的石棉草科穹状变形变质体,据近年来的研究表明,该穹隆体经历了三次变形变质时期：早期为收缩滑脱变形的区域动力变质、中期热隆伸展动热变质和后期岩浆热接触变质。对主期变质划分出黑云母带、石榴石带、红柱石－十字石带和矽线石带,确定为低压相系,利用变质反应、矿物地质温压计及相关的同位素年龄资料,建立了草科穹状变形变质体演化的ｐ－Ｔ－ｔ－Ｄ轨迹。轨迹图呈顺时针形式,具碰撞造山带环境的特点,变形变质过程受变质体前缘西油房韧性剪切带逆冲－推覆作用和后缘碰撞晚期岩浆大规模上侵的双重制约,为深源岩浆热动力变质成因,属穹状岩浆核杂岩构造。     

Late Cretaceous blueschist facies metamorphism in southern Thrace (Turkey) and its geodynamic implications

A blueschist facies tectonic sliver, 9 km long and 1 km wide, crops out within the Miocene clastic rocks bounded by the strands of the North Anatolian Fault zone in southern Thrace, NW Turkey. Two types of blueschist facies rock assemblages occur in the sliver: (i) A serpentinite body with numerous dykes of incipient blueschist facies metadiabase (ii) a well‐foliated and thoroughly recrystallized rock assemblage consisting of blueschist, marble and metachert. Both are partially enveloped by an Upper Eocene wildflysch, which includes olistoliths of serpentinite–metadiabase, Upper Cretaceous and Palaeogene pelagic limestone, Upper Eocene reefal limestone, radiolarian chert, quartzite and minor greenschist. Field relations in combination with the bore core data suggest that the tectonic sliver forms a positive flower structure within the Miocene clastic rocks in a transpressional strike–slip setting, and represents an uplifted part of the pre‐Eocene basement. The blueschists are represented by lawsonite–glaucophane‐bearing assemblages equilibrated at 270–310 °C and ～0.8 GPa. The metadiabase dykes in the serpentinite, on the other hand, are represented by pumpellyite–glaucophane–lawsonite‐assemblages that most probably equilibrated below 290 °C and at 0.75 GPa. One metadiabase olistolith in the Upper Eocene flysch sequence contains the mineral assemblage epidote + pumpellyite + glaucophane, recording P–T conditions of 290–350 °C and 0.65–0.78 GPa, indicative of slightly lower depths and different thermal setting. Timing of the blueschist facies metamorphism is constrained to c. 86 Ma (Coniacian/Santonian) by Rb–Sr phengite–whole rock and incremental ⁴⁰Ar–³⁹Ar phengite dating on blueschists. The activity of the strike–slip fault post‐dates the blueschist facies metamorphism and exhumation, and is only responsible for the present outcrop pattern and post‐Miocene exhumation (～2 km). The high‐P/T metamorphic rocks of southern Thrace and the Biga Peninsula are located to the southeast of the Circum Rhodope Belt and indicate Late Cretaceous subduction and accretion under the northern continent, i.e. the Rhodope Massif, enveloped by the Circum Rhodope Belt. The Late Cretaceous is therefore a time of continued accretionary growth of this continental domain.     

湘南西山铝质A型花岗质火山-侵入杂岩的地球化学及其形成环境

初步研究表明,以往被认为是典型的S型花岗质岩石的湘南西山火山侵入杂岩应为铝质A型花岗质岩石。该杂岩富硅碱贫钙镁、K2O/Na2O>1、准铝过铝质(0.94～1.26);FeO /MgO比值大(平均12.05),高于M型,S型和I型花岗岩。在微量元素和稀土元素组成上,岩石富LREE,Ga,Y,Nb,Zr等大离子高场强元素及亏损Ni,Cr,Eu,Ti,V,P,Sr等,与国内外A型花岗岩相似。与一般A型花岗岩来源于I型花岗岩或大量抽提了S型花岗岩物质后的地壳源区不同,西山火山侵入杂岩的I(Sr)(0.71612～0.71823)较高,εNd(-7.0～-8.0)较低,钕模式年龄(1 517～1 600Ma)略小于区域上变质基底和中国东南部中生代花岗岩类的钕模式年龄,显示其直接来源于地壳物质的部分熔融,但可能有少量新生地幔物质的加入。西山铝质A型花岗质火山侵入杂岩是中侏罗世晚期挤压造山作用趋于结束,造山带崩塌,岩石圈强烈伸展减薄、热流值上升的构造背景下形成的造山后花岗质岩石。     

A complex variable solution for stress and displacement field around a lined circular tunnel at great depth

By applying the series expansion technique in the complex variable method established by Muskhelishvili, the plane elasticity problem for the stress and displacement field around a lined circular tunnel in conjunction with the consideration of misfit and interaction between the liner and the surrounding geomaterial is dealt with. The tunnel is assumed to be driven in a homogeneous and isotropic geomaterial. The coefficients in the Laurent series expansion of the stress functions are determined. The complex potentials in the liner and the surrounding geomaterial are explicitly derived, respectively. As an example, the case of a lined circular tunnel located in an isotropic initial stress field but subjected to uniform internal pressure is numerically considered. Numerical results indicate that the installation of tunnel liner can reduce the influences of the tunnel excavation on the in situ displacement and stress fields. However, the relative thickness and rigidity of the liner should be in an appropriate range. In addition, the effect of the tunnel excavation upon the displacement field is more significant than that upon the stress field. As far as the stress field in the surrounding geomaterial is concerned, when the ratio between the cover depth of tunnel and the tunnel radius is larger than 5, the results for the stress field in the paper are applicable. When the ratio between the tunnel depth and the tunnel radius is larger than 20, the results are applicable for the displacement field. Copyright © 2008 John Wiley & Sons, Ltd.     

Synthesis, Characterization and Antibacterial Activity of New Ln（Ⅲ ） Complexes with an Unsymmetrical Schiff Base Ligand

1Introduction SomeSchiffbasecomplexesderivedfromaminoacidsareparticularlyactiveinbiologycatalysisandmaterial.Thestudyofthemisfocusofthestudyof coordinationchemistry.Recently,studiesofsuchmetalcomplexesofmono Schiffbaseshavebeenre ported(Fanetal.,2003a,b;L…