古剂量勘查技术

本文首次报道了我国 An晕勘查法和石英电子自旋共振勘查法的理论和实现该方法研制出的微机化仪器和测量技术 ,以及古剂量勘查法应用于拉拉铜矿中得到的新认识     

小寺沟铜钼矿成岩-成矿系统浅析

河北小寺沟斑岩铜钼矿是华北地区一个大型铜钼矿床。本文通过分析小寺沟岩体地质特征,认为本岩体为脉动式侵入的浅成复式岩体,呈岩枝状产出,且岩石具典型的斑状结构;通过剖析岩体主量元素与稀土元素特征,认为属典型的Ⅰ型花岗岩;综合分异指数、Mg#指数和无铕异常等多方面特征,认为结晶分异作用在斑岩岩浆演化中不占主导地位,而岩浆来源于下地壳部分熔融与加入的玄武质岩浆。以上特征均与斑岩型铜钼矿床含矿岩体相当。最后,通过矿床硫同位素及硫化物稀土元素特征的研究,利用对比分析法,揭示研究大型斑岩型矿床的要素。     

高钙碳酸盐地质样品中铜镍的测定

用电感耦合等离子体质谱法和电感耦合等离子体发射光谱法测定高钙碳酸盐样品中的铜和镍。通过试验分析了高钙碳酸盐样品中钙对铜、镍测定的影响,并确定其影响因子,提出两套检测高钙碳酸盐样品中铜、镍的方案。方法经国家标准物质验证,测定值与标准值相符;相对标准偏差(RSD,n=10)两元素均小于2%。     

The Whole‐Rock Geochemical Composition of the Wudaogou Group in Eastern Yanbian,NE China–New Clues to Its Relationship with the Gold and Tungsten Mineralization and the Evolution of the Paleo‐Asian Ocean

The late Paleozoic Wudaogou Group, one of the oldest metamorphic units in the eastern Yanbian area, has important tectonic and metallogenic significance. Here, we provide new insights into their protoliths, tectonic setting of the metamorphic rocks and their relationships with the gold and tungsten mineralization, using new petrographic and whole‐rock geochemical data for various lithologies within the Wudaogou Group. The protolith of the metamorphic rocks of the Wudaogou Group was intermediate–basic volcanic rocks (e.g. basaltic andesite, trachyandesite, and basalt) and sedimentary rocks including argillaceous rocks, quartz sandstone, arkose and clayish greywacke, as well as pyroclastic sedimentary rock, covering tuffaceous sandstone. Before undergoing late Paleozoic epidote–amphibolite facies regional metamorphism, these protoliths were formed during the middle–late Permian in an island arc setting within a continental margin collage zone. Combined with the regional tectonic evolution, it can be speculated that the formation and the subsequent metamorphism of the protoliths of the metamorphic rocks from the Wudaogou Group were influenced by the change from subduction to collision of the Paleo‐Asian Ocean. Similarities of the rare earth element (REE) patterns and parameters among the metamorphic rocks within the Wudaogou Group, auriferous ores from the Xiaoxi'nancha gold (copper) deposit, and scheelites from the Yangjingou tungsten deposit, together with the favorable metallogenic element contents within the metamorphic rock series, imply that the Wudaogou Group could provide parts of metallic material for the gold and tungsten mineralization in the eastern Yanbian area, as exemplified by the Yangjingou deposit and Xiaoxi'nancha deposit, respectively. Further, the metamorphic sedimentary rocks, especially the metamorphic sandstones, quartz schists and quartz mica schists within the Wudaogou Group, have closer genetic relationships with the Yangjingou tungsten mineralization. However, the specific lithologies within this group which control the gold mineralization are still uncertain, and need further research.     

含方解石铜矿石微生物氧化作用的实验研究

矿山固体废物中硫化物经微生物作用形成的酸性矿山排水及其引起的重金属污染是备受关注的环境问题,而岩石和矿石中的方解石能够影响酸性矿山排水的生成和迁移。为了考察方解石对硫化物-微生物氧化作用的影响,开展了系统的模拟实验,利用ICP-AES、XRD、XRF等分析手段,测定了实验溶液的pH值、Eh值、离子浓度和次生沉淀成分。结果表明,在无方解石或方解石含量低时,黄铜矿的微生物氧化过程中,pH值下降、Eh值上升,有多种重金属离子进入溶液,并生成大量黄钾铁矾、自然硫等次生沉淀。添加过量方解石能有效中和氧化过程产生的酸并能显著抑制氧化菌的活动。因此通过添加碳酸盐矿物的方法可使溶液pH调节至微碱性,降低微生物的活性、阻滞铜矿石的氧化,能够有效降低重金属的释放。     

北祁连山石居里富铜矿选矿性试验与研究

石居里铜矿床矿石中主要矿石矿物由黄铜矿及黄铁矿等组成。铜含量一般为4％～20％，由于黄铜矿与黄铁矿复杂的嵌布关系，采用传统的老三样(丁黄药、石灰、2#油)浮选(一段磨矿，小于0．074mm占70％左右)精矿粉的铜品位仅达15．03％。造成了一定铜资源的浪费。通过对该类型铜矿石的矿物学组构及特征的研究，经多次试验后采用DY-1捕收剂及两段磨矿流程，即一段粗磨矿(小于200目即0．074mm占70％左右)丢尾，二段粗精矿再磨(小于325目即0．043mm占95％左右)后精选，使铜精矿Cu品位达20．73％，同时使硫回收率由51．26％上升到74．11％。     

钾玄岩系列:藏东玉龙铜矿带含矿斑岩元素地球化学特征

西藏东部玉龙铜矿带,包括玉龙、扎拉尕、莽总、多霞松多和马拉松多等斑岩型Ｃｕ,Ｍｏ,Ｐｂ,Ｚｎ,Ａｕ,Ａｇ和Ｐｔ等多金属矿床．由于分析技术条件的限制,前人所获得的含矿斑岩微量元素数据精度较低．采用先进的ＰＥＥｌａｎ６０００型电感耦合等离子质谱仪（ＩＣＰ－ＭＳ）分析微量元素（包括稀土元素）,结果表明含矿斑岩和共生的钾质碱性深成岩、火山岩和煌斑岩在时空上具一致性,岩石化学成分均富碱（ｗ（Ｋ２Ｏ）＋ｗ（Ｎａ２Ｏ）＞８％）,高钾和ｗ（Ｋ２Ｏ）／ｗ（Ｎａ２Ｏ）比值远大于１,微量元素富集Ｓｒ,Ｂａ等大离子亲石元素和轻稀土元素等,均显示出钾玄岩系列岩石的特征,暗示西藏东部玉龙铜矿带的含矿斑岩属于典型的钾玄岩系列的斑岩     

阿舍勒黄铁矿型铜矿床地质特征

本文通过对矿床的成矿地质条件、控矿因素和物质组份的分析研究,认为该矿为火山成因块状黄铁矿型铜矿。矿体受火山机构控制,产于火山穹窿叠加背斜构造中或火山管道及火山口附近。矿体形态复杂、矿床规模大、品位富、矿种多,矿化垂直分带明显,可作为典型矿床进行研究,以期找到同类矿床。     

2-（5-硝基-2-吡啶偶氮）-5-二甲氨基苯胺分光光度法测定铜

研究了2 (5 硝基 2 吡啶偶氮) 5 二甲氨基苯胺(5 NO2 PADMA)与铜的显色反应。结果表明,在pH4.5的HAc NaAc介质中,Cu与5 NO2 PADMA形成1∶2的紫红色配合物,λmax=550nm,ε=3.24×104L·mol-1·cm-1,Cu的含量在0～1.4mg/L内符合比尔定律。方法经铝合金和矿样管理样品分析验证,结果与原结果相符,5次测定的RSD小于0.7%。     

与峨眉山玄武岩有关的铜矿床的成矿机制剖析

本文剖析了与峨眉山玄武岩有关的铜矿的产出特征、形成机制,侧重论述了火山机制与成矿的关系,并指出了找矿的方向。