山东省邹平火山岩盆地铜矿地球物理综合找矿模型及找矿方向

邹平地区是山东省内最主要的铜矿产地和成矿远景区,先后发现了王家庄铜矿和碑楼铜矿,构成了区内典型的次火山岩型矿床系列。该文通过搜集和研究邹平火山岩区以往多年的信息资料,并结合近几年的地质物化探工作及其找矿成果,初步建立了邹平火山岩盆地铜矿的地球物理综合找矿模型,并以此为基础就下一步该区找矿方向进行了分析和探讨。     

双频激电法在云南新发地区的应用

经过在测区进行双频中梯测量,圈定了4个激电异常,综合测区岩石的电性、物性特征,对异常进行了推断和解释。根据所测量的视幅频率和视电阻率结果分析,双频激电法完适应于云南地形起伏较大的地区,并能取得良好的地质效果。     

中国西南地区铜矿资源现状及对地质勘查工作的几点建议

铜作为重要的战略性矿产资源,是中国当前最为突出的大宗性紧缺矿种之一。西南地区成矿地质背景优越,铜矿资源的找矿潜力巨大,国土资源大调查10年来的发现和进展已基本改变了中国铜矿资源新的战略分布格局。进一步加快西南地区铜矿资源的勘查工作进程,紧紧围绕重要成矿区带和主要的铜矿类型,不断提高工作程度,尽快实现新一轮找矿的重大突破,大幅度提高铜矿资源的储量,对全面提升国内铜矿资源的保证程度具有重要作用。     

内蒙古赤峰市鸭鸡山钼铜矿成矿流体特征及矿床成因

鸭鸡山钼铜矿床所处大地构造位置为蒙古—鄂霍次克造山带的温都尔庙—翁牛特旗褶皱带,该带是我国重要的有色金属成矿带之一。鸭鸡山钼铜矿床分布受控于区域EW向深断裂,矿体产于EW向主断裂F1上盘的二长花岗岩体中,严格受东西向F1断裂和北东向断裂控制。该矿床矿石自然类型为石英脉型和蚀变岩型,矿石中硫化物主要有黄铁矿、辉钼矿和黄铜矿。石英流体包裹体有气液两相、含子矿物三相和纯气相3种类型。流体盐度(w(NaCl))为2.06%～44.00%,集中在40%～44%和4%～8%;流体密度为0.85～1.25 g/cm3,集中在1.20～1.24 g/cm3和0.88～0.92 g/cm3;成矿温度为167～380℃,集中在320～360℃和200～220℃;流体盐度、密度、成矿温度在直方图上均表现为双峰特征。研究表明:成矿早阶段流体为高盐度、高密度和高温的岩浆流体,气相包裹体与含子晶三相包裹体共存,表明该阶段发生过强烈的沸腾或不混溶;成矿晚阶段为低盐度、低密度和中温的混合流体。通过等容线图解法估算成矿压力为274.7～368.5 MPa,用静岩压力梯度估算成矿深度为8.32～11.2 km。矿床成因类型为中成、中高温热液脉型...     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

新显色剂四-(3-磺基-4-氯苯基)卟啉分光光度法测定微量铜

研究了新显色剂四-(3-磺基-4-氯苯基)卟啉在微酸性介质中,表面活性剂OP与CPC存在下测定微量铜的显色反应。络合物在波长420 nm处有最大吸收峰,摩尔吸光度系数为3.44×105L·mol-1cm-1,用双峰双波长光度法测定摩尔吸光系数为6.72×105L·mol-1·cm-1,铜含量在0.5~4.5μg/25 m L范围内符合比耳定律。方法应用于矿样中微量铜的测定,结果令人满意。     

山东福吉山铜矿构造控矿因素分析

福吉山铜矿成矿地质特点不同于山东已有的铜矿类型,属于构造热液成因类型。近SN向的平移断裂同时具有张扭性和压扭性双重力学性质,其中张扭性破碎带造就成矿空间,造成了矿体近等间距雁列式排列。受断裂构造的影响,矿区内节理、裂隙发育,为成矿热液的运移和积聚提供了良好的空间。区内沿裂隙充填形成的石英脉、褐铁矿脉、铜矿脉发育。     

Zinc and copper bioaccumulation in fish from Laizhou Bay,the Bohai Sea

Abstract Zinc （Zn） and copper （Cu） concentrations were determined in the tissues （muscle, stomach, liver, gills, skin, and gonads） of five commercial fish species （mullet Liza haematocheilus, flathead Platycephalus indicus, mackerel Scomberomorus niphonius, silver pomfret Pampus argenteus, and sea bass Lateolabrax japonicus） from Laizhou Bay in the Bohai Sea. Metal bioaccumulation was highest in the metabolically active tissues of the gonads and liver. Bioconcentration factors for Zn were higher in all tissues （gonads 44.35, stomach 7.73, gills 7.72, liver 5.61, skin 4.88, and muscle 1.63） than the corresponding values for Cu （gonads 3.50, stomach 3.00, gills 1.60, liver 5.43, skin 1.50, and muscle 0.93）. Mackerel tissues accumulated metal to higher concentrations than did other fish species, but bioaccumulation levels were not significantly correlated with the trophic levels of the fish. Zn and Cu concentrations in the tissues were generally negatively correlated with fish length, except for a few tissues of sea bass. Risk assessment based on national and international permissible limits and provisional tolerances for weekly intake of Zn and Cu revealed that the concentrations of these two metals in muscle were relatively low and would not pose hazards to human health.     

Effect of copper on the growth of shrimps Litopenaeus vannamei: water parameters and copper budget in a recirculating system

Shrimps( Litopenaeus vannamei) were intensively cultured in a recirculating aquaculture system for 98 days to investigate effects of 0.3 mg/L Cu on its performance, Cu budget, and Cu distribution. Shrimps in Cu-treated systems had greater mean final weight(11.10 vs 10.50 g), body length(107.23 vs 106.42 mm), survival rate(67.80% vs 66.40%), and yield(6.42 vs 5.99 kg/m 3), and lower feed conversion ratio(1.20 vs 1.29) than those in control systems but the differences were not significant. Vibrio numbers remained stable(10 4 –10 6 colony forming units/mL) in the rearing tanks of both control and treated systems. Total ammonium-N, nitrite-N, nitrate-N, pH, chemical oxygen demand, 5-day carbonaceous biochemical oxygen demand, and total suspended solids were similar in controls and treatments. Dissolved Cu concentration in the treated systems decreased from 0.284 to 0.089 mg/L while in the control systems it increased from 0.006 2 to 0.018 mg/L. The main sources of Cu in the treated systems were the artificially added component(75.7% of total input), shrimp feed(21.0%), water(2.06%), and shrimp biomass(1.22%). The major outputs of Cu occurred via the mechanical filter(41.7%), water renewal(15.6%), and draining of the sediment trap(15.1%). The foam fractionator removed only 0.69% of total Cu input. Harvested shrimp biomass accounted for 11.68% of Cu input. The Cu concentration of shrimps in the Cu-treated systems(30.70 mg/kg wet weight) was significantly higher than that in control systems(22.02 mg/kg). Both were below the maximum permissible concentration(50 mg/kg) for Cu in seafood for human consumption in China. Therefore, recirculating systems can be used for commercial on-growing of Litopenaeus vannamei without loss of shrimp quality, even in water polluted by 0.30 mg/L Cu. The mechanical filter is the main route for Cu removal.     

安徽池州杨北寨铜矿与铜山铜矿等矿床的比较研究

杨北寨铜矿、施村金矿位于湖区,可利用的工作方法手段有限,找矿难度大。通过将以往所取得的两矿区片段地质资料的结合,在区域地质背景分析和与相邻的铜山铜矿成矿地质条件对比研究的基础上,明确找矿思路,进行预测定位,并经有效可行的物探方法再对比论证,优化设计方案。施工首孔于相应的设计部位打穿五通组顶板,各预测主要见矿部位均见矿体;其后的验证又获得很多重要发现:深部发现花岗闪长斑岩岩体、斑岩型钼矿化及赋存于不同部位的铜多金属矿化。经再次与相邻矿集区铜陵狮子山等矿田对比研究,认为杨北寨矿区具"多位一体"矿化特征,找矿潜力大,提出新的找矿思路,进行了新的预测定位;同时对池州其他地区的找矿也提出设想。