成都粘土裂隙成因研究

根据成都粘土中裂隙特征与地质环境条件的分析，提出成都粘土中途中眩要裂隙类型的成因模式，上升剥蚀引起的垂向卸荷作用产生波状水平裂隙，冲沟切割引起的侧向卸荷作用，产生平行斜列隙裂。     

秦家屯油田储层的敏感性评价

储层的敏感性评价是研究储层损害机理、保护储层或减小储层损害的依据,是搞好油田注水开发的基础。采用岩心流动实验装置,开展了储层敏感性的室内实验。结果表明秦家屯油田储集层对流体速度表现为弱敏感性,对盐敏表现为中等偏弱盐敏性,对酸表现为无敏感性,随着注水速度的增加,岩心的渗透率也随之增大,并未出现“桥堵”和“卡堵”现象,说明储层中不稳定的固相颗粒含量低,不能堵塞地层,油层增产可采用提高注入速度、酸化等措施,油层水敏为中等偏弱到中等偏强,注水前要注入稳定剂。碱敏表现为弱碱敏或中等碱敏,对该区三次采油作业中,尤其是碱水驱油要特别注意。     

多孔介质非饱和导水率预测的分形模型

多孔介质非饱和导水率是地下水污染预测与评价的重要参数。根据分形几何的基本原理和方法,推导出了与Campbell经验公式在形式上完全一致的多孔介质非饱和导水率的预测公式。公式中的幂指数为介质孔隙分维和随机行走分维的函数,分别体现了多孔介质的静态性质与动态性质对其中水分运动的影响,但静态性质的影响是主要的,即导水率主要受多孔介质的结构控制。根据文献中报道的大量数据,利用笔者推导的预测公式计算得到的幂指数的统计值与试验测定的幂指数的统计值基本一致,说明推导的理论公式预测多孔介质非饱和导水率是较为可靠的。     

鲁西南深埋粘性土物理力学指标多元统计研究

运用R因子分析和R型聚类两种多元统计分析方法,对鲁西南地区深埋粘性土的20组样的8个物理力学指标数据进行了分析。利用R因子分析方法,揭示了各指标对鲁西南地区深埋粘性土状态和力学性质的影响关系。利用R型聚类分析方法,研究了深部粘性土各物理力学指标之间的相关性,为进一步从物理力学指标对深埋粘性土的特殊状态和力学特性的研究打下基础。     

广西新型矿物材料发展方向初探

新材料是发展高新技术产业的基础。根据广西的矿产资源优势和在矿物材料方面的研究基础和技术力量，提出了加强工艺矿物学研究，大力发展广西新型矿物材料的研究开发方向，特别提出了超细改性矿物粉体材料、环保矿物材料、节能保温矿物材料、高技术陶瓷材料和合成矿物晶体材料等材料体系中的重点开发方向。     

疏降地下水引起地面塌陷浅析--以淮南煤矿区为例

以淮南西部矿区为例，介绍了该地区自20世纪60年代开采煤矿以来，由于疏降地下水，引起的地面塌陷。为了研究灰岩水动力场规律，先后在该区进行多时段、多水平放水试验。研究表明，覆盖粘土层、岩溶及人工疏降地下水，是该地区岩溶塌陷形成的基本条件。通过对粘土盖层性质、疏降地下水岩溶塌陷演化过程及塌陷机理与对应阶段过程综合分析，结合区域地质条件，掌握了塌陷点的分布规律。对目前西部地区塌陷“复活”、整治及未来城市规划，提出了建设性建议。     

Analysis of Sediments and Soils by X-Ray Fluorescence Spectrometry Using Matrix Corrections Based on Fundamental Parameters

Wavelength dispersive X-ray fluorescence spectrometry (WD-XRF) is widely used for the analysis of soils and sediments using well characterised procedures. However, difficulties can occur with samples such as unknowns containing small amounts of ore materials and samples collected from contaminated sites where trace elemental concentrations can exceed the concentration range for routine analysis. We studied the performance of a commercially available method, based on fundamental parameters (FP) to correct matrix effects. The spectrometer was originally calibrated with elemental or simple compound calibrants. Samples were analysed as pressed powder pellets. Eighteen sediment and soil reference materials, three of them with certified values for some of their constituents, were used to evaluate accuracy, by comparing results with recommended values and their standard deviations (RV ± 2s) or certified values and their confidence intervals (CV ± Cl). When results fell systematically outside these intervals, calibrations were refined with geochemical reference materials. The best agreement of results with recommended and certified values was obtained when the contents of H₂O and C in each sample were included as matrix constituents during calculations. The detection limits of trace elements tended to be relatively high, because the measuring conditions employed were not maximised for sensitivity. The main advantage of the method tested was that it enabled the analysis of samples with high concentrations of trace elements and the determination of elements such as F, Bi, Sb and W, which are not commonly included in quantitative XRF analysis of geological samples.     

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.     

Nuclear Waste Disposal Simulations: Couplex Test Cases

We give some results obtained for the Couplex test cases proposed by the ANDRA. In this paper our aim is twofold. Firstly, to compute the release of nuclides out of the repository by concentrating on the 3D near field (Couplex 2). The simulation of the transport phenomena takes into account the dissolution of the glass containers and congruent emissions of the radio-nuclides including filiation chains and some simplified chemistry. Secondly, it is to use the near field computations in order to simulate the nuclide migrations in a 2D far field (Couplex 3). Coupling in between the two simulations takes into consideration the periodicity of the disposal modules and the geometry of the repository described in Couplex 1. The mixed finite element and discontinuous Galerkin methods are used to solve the convection–diffusion equations. In order to handle the nonlinear precipitation/dissolution term, we developed a new iterative technique that combines Picard and Newton–Raphson methods.