Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

软基深埋涵洞土压力和沉降的三维有限元分析

通过软基坝下深埋涵洞的三维有限元计算,对涵洞的土压力及沉降问题进行了分析研究。研究结果表明： （1）在洞顶采用减荷措施时,洞顶竖向土压力明显减小,减荷效果比较显著;而对洞体的最大不均匀沉降率基本没有影响,涵洞周边土压力的分布特征与无减荷时也是相同的。（2）洞基处理深度变化对洞体附近的应力有影响,且随处理深度的增大,洞顶竖向土压力和洞侧面水平土压力分别有缓慢增大和缓慢减少的趋势。（3）洞底沉降随处理深度的增大而有微弱的减小,但不均匀沉降均小于0.5 %,且从总体上看,其量值对工程的影响并无本质的差异,对洞基不进行处理时,洞基的不均匀沉降少许的增大不会对涵洞造成危害。     

谈滑坡勘察中的几个地下水压力问题

鉴于目前在滑坡勘察中对地下水压力问题尚有一些不够明确和难以确定之处,本文首先讨论地下水压力的分类及其概念,并简要叙述地下水压力的时、空变化和影响因素;然后结合实例分析不同条件下地下水压力在滑坡形成中的实际效用,并就地下水压力的确定问题发表了看法。     

Kinetic shear resistance,fluid pressures and radiation efficiency during seismic faulting

Summary During earthquake faulting, radiation efficiency and the degree stress relief are critically dependent on the kinetic shear resistance. This is often assumed to stay constant during slip, but geological evidence suggests that for moderate or large shallow earthquakes it may decrease dramatically to near-zero values once slip is initiated, either by melt formation or by transient increases in fluid pressure on the fault plane. The latter, probably more common process may arise partly through an interaction between temperature and water pressure, and partly through dilatancy recovery as shear stress is relieved. If the fault remains undrained, stress relief should be absolute with seismic efficiency reaching high values, so that stress drops give a measure of the level of tectonic shear stress in fault zones. Supporting evidence comes from the observation that apparent stress is generally about half the stress drop.     

青藏公路沿线通信光缆埋设地段冻土工程地质条件及评价

青藏公路沿线季节冻土和多年冻土的总长度为７６０ｋｍ，根据气温冻结指数和融化指数可估算最大季节冻结深度和最大季节融化深度。根据含水量划分出５种冻土类型和５个冻胀敏感性等级。提出了光缆埋设若干选线和施工建议。     

O2-O2云反演算法及其在TROPOMI上的应用

利用遥感技术对大气环境污染进行监测时,云是影响痕量气体反演精度的重要因素,因此在痕量气体反演中需要对云的影响进行校正,通常使用的云参数主要是有效云量和云压。本文基于O₂-O₂ 477 nm吸收波段构建了O₂-O₂云反演算法：首先,根据有效云量和云高与连续反射率和O₂-O₂斜柱浓度之间的对应关系,结合假定的云模型利用VLIDORT辐射传输模型建立关于有效云量和云压的查找表;然后,通过差分吸收光谱技术拟合卫星载荷观测的大气层顶辐射,获得O₂-O₂斜柱浓度并计算连续反射率;最后,结合辅助数据,根据查找表进行插值反演获得有效云量和云压。通过将算法应用到OMI观测数据,将反演结果与OMCLDO2产品进行对比验证,有效云量和云压空间分布一致,相关系数R均超过0.97;并还将该算法应用于下一代大气成分监测仪器TROPOMI,与FRESCO+产品对比,有效云量和云压空间分布基本一致,当地表类型为海洋时,有效云量相关系数R大于0.97,云压相关系数R大于0.94,云压反演结果存在一定的区别;通过将O₂-O₂云反演算法和FRESCO+云压反演结果与CALIOP Cloud Layer产品进行对比,结果表明,在低云情况下,O₂-O₂云反演算法线性回归方程斜率为0.782,截距为198.0 hPa,相关系数R为0.850,算法表现优于FRESCO+。而在高云情况下,FRESCO+反演结果更接近CALIOP云压结果。在OMI和TROPOMI上的应用表明O₂-O₂云反演算法在大气云反演中具有较高的准确性和可行性,可以为大气痕量气体反演的校正提供云参数,并为中国同类型卫星载荷的云反演算法提供算法参考。     

不等长工作面台阶区域覆岩运动诱冲机制及防治

针对阳城煤矿不等长工作面台阶区域发生冲击地压灾害问题,基于工作面特殊布置方式及覆岩赋存特征,采用理论分析、数值模拟和现场实测等方法,分析了台阶区域覆岩结构运动特征和围岩应力演化规律,研究了台阶区域冲击地压诱发机制。研究结果表明：1304工作面台阶区域覆岩经历了“OX-S-C”型较为复杂的结构演变,覆岩空间结构由OX向S型转换时,顶板岩层大面积破断下沉,在台阶区域形成多个悬臂梁结构,越往高位,悬臂梁长度越大;受覆岩运动和采动应力场叠加影响,煤岩体形成高应力集中区,在顶板岩层动载冲击作用下,煤岩体弹性应变能突然释放,诱发冲击地压。采用COMSOL软件对不同卸压钻孔参数下煤体应变能分布特征进行模拟研究,优化了台阶区域卸压钻孔参数。根据模拟结果,随着钻孔孔径、孔深增大及间距减小钻孔卸压效果越明显,考虑工程实际,确定孔径为150 mm、孔深为30 m、间距为1 m为合理有效的卸压钻孔参数,并应用于1302工作面台阶区域的冲击地压防治,取得了较好的防冲效果。     

Mapping susceptibility of rainfall-triggered shallow landslides using a probabilistic approach

To prepare a landslide susceptibility map is essential to identify hazardous regions, construct appropriate mitigation facilities, and plan emergency measures for a region prone to landslides triggered by rainfall. The conventional mapping methods require much information about past landslides records and contributing terrace and rainfall. They also rely heavily on the quantity and quality of accessible information and subjectively of the map builder. This paper contributes to a systematic and quantitative assessment of mapping landslide hazards over a region. Geographical Information System is implemented to retrieve relevant parameters from data layers, including the spatial distribution of transient fluid pressures, which is estimated using the TRIGRS program. The factor of safety of each pixel in the study region is calculated analytically. Monte Carlo simulation of random variables is conducted to process the estimation of fluid pressure and factor of safety for multiple times. The failure probability of each pixel is thus estimated. These procedures of mapping landslide potential are demonstrated in a case history. The analysis results reveal a positive correlation between landslide probability and accumulated rainfall. This approach gives simulation results compared to field records. The location and size of actual landslide are well predicted. An explanation for some of the inconsistencies is also provided to emphasize the importance of site information on the accuracy of mapping results.     

超重力场中界面土压力的测量

测量诸如孔隙水压力、位移和载荷等物理量能够达到相当高的精度,但土压力的测量则困难得多。在吸取了国内外同行经验后,为离心模型试验设计研制了一种微型土压力盒,主要用于土与结构物界面土压力的测量。水压力、干砂压力和砂土压力三种标定结果表明,这种微型土压力盒的线性度良好;在研究地下连续墙的侧向土压力分布的离心模型试验中,根据这种微型土压力盒的测试结果,获得了合理的侧压力系数。     

煤层气径向钻井压耗计算与井口压力预测

对煤层气径向钻井过程中钻井管柱系统压耗和高压水射流破岩机理进行分析,列出了钻井管柱系统各部分磨阻系数的计算公式和喷嘴射流动力公式。通过理论分析与室内试验,提出了煤的水力冲击破碎压力与其物理力学参数之间的关系式,以及水力冲蚀速度与无因次冲击压力之间的关系。结果表明：通过加权平均值法计算得到的临界破碎压力与实际值吻合良好;在3~8倍临界破碎压力下,冲蚀速度约为无因次冲击压力的0.4倍。根据文中压力预测步骤,对现场作业进行压力预测,得到的井口压力预测结果比实际施工压力低3~5 MPa。