Comparison between natural and artificial maturation series of humic coals from the Mahakam delta,Indonesia

Type III (humic) organic matter from the Mahakam delta (Indonesia) was chosen to compare artificial and natural coal series. Powdered and concentrated immature organic matter was heated in sealed gold tubes for 24 hr at temperatures ranging from 250 to 550°C and under pressures ranging from 0.5 to 4 kb, with and without water. Both elemental and Rock-Eval analyses were used to characterize the products. A comparison between our results, published data and the natural model shows that, quantitatively, natural maturation is simulated better when pyrolysis is performed under confined conditions (no free volume, no diluting inert gas). Thus, pyrolysis in a medium swept by an inert gas, vacuum pyrolysis and some pyrolysis in sealed glass tubes must be considered to be poor simulation tools. The presence of water does not seem to have an essential effect. Allowing the hydrocarbons formed to reach a certain value of partial pressure seems to be important. Results are unchanged when external pressure varies from 0.5 to 4 kb.     

合成斜方辉石系列的红外光谱研究

在30kbar和900℃条件下,用等化学计量氧化物混合物合成了11个斜方辉石系列的样品,并对合成的样品进行了X射线粉晶分析和红外光谱分析。分析结果表明,晶胞参数和红外光谱随化学成分的改变而产生复杂的变化。不仅晶胞参数b和M而且频率ν_(670cm)-1和M之间存在很好的线性相关关系,通过用最小二乘法所拟合的相关方程可容易地测定斜方辉石的成分,但是α和c与M之间只有较差的线性关系,而ν_(450cm)-1和M以及ν_(380cm)-1和M之间并无简单的线性相关关系,这可归因于Fe~(2+)在M_1和M_2位置的有序分布。     

Borehole pressure correction equation

Conclusion A method of calculation for borehole pressure has been developed and compared to measured data for PETN. The results show that by adjusting the ratio of the specific heats using an equation derived from a curve fit of a pressure as a function of decoupling ratio graph, the plot shifts to a position within the ranges of the measured data. Also, at this point the proper specific heat may be obtained for a given gaseous mixture. Although other mixtures have been considered the results are not yet conclusive, but preliminary values seem to hold for the methodology used.     

吉林省太古宙TTG岩类固结的温度压力条件

吉林省太古宙ＴＴＧ岩类型成于变质上壳岩系麻粒岩相变质作用晚期阶段。详细的岩相学研究表明，ＴＴＧ岩类中存在岩浆结晶的绿帘石，角闪石和黑云母等。绿帘石的出现标志了一定的压条件。     

地层压力和大直径套管抗挤压力计算

介绍了上覆地层压力和粘土吸水膨胀对套管挤压以及大直径管受外挤力失稳破坏的计算方法。解决了现场遇到的实际问题。     

盆地烃类运移二维二相流动数学模型分析与应用实例

从地质固体系统与流体系统相互作用所形成的能量流、物质流的观点，系统地论述了建立烃类运移主要控制方程，即烃水两相拉格朗日型异常地层压力方程和饱和度方程，研制了开发了烃类运移数值模拟系统，阐明了该耦合系统的要素功能和求解方法，提供了改善系统模拟精度的措施，最后介绍了该模拟系统在松辽盆地东南隆起某测线的应用实例。     

盐用做高温高压实验传压介质一种新方法

固体传压高温高压岩石三轴实验中，固体传压介质是影响实验结果的重要因素，ＮａＣｌ介质以它流动性好，围压均匀等特点，八十年代以来越来越受到人们青睐。本文用ＮａＣｌ介质在〈３ＧＰａ固体传压三轴流变仪〉上进行了高温高压岩石流变特性的实验研究，并达到了较高的压力（〉２ＧＰａ）和温度（〉１２００℃）；本文同时利用ＮａＣｌ介质对样品装样方式及温度、压力等相关测定方面进行了研究。     

Early deformation fabrics of melange in the Mesozoic Waipapa Terrane, North Island, New Zealand

Abstract The Waipapa Terrane in northern North Island, New Zealand, is a Mesozoic accretion-ary complex formed along the Gondwana margin. It contains abundant melange rocks with distinctive characteristics. Precise analyses of their mesoscopic fabrics in Waiheke Island near Auckland have revealed the following sequence of deformation. The earliest phase of deformation of the sandstone/mudstone association, which is the main constituent of this terrane, originated by chaotic mixing of sand and mud due to liquidization of water-saturated, poorly consolidated sediments. The second phase was characterized by hydrofracturing and subsequent forceful injection of ductile mud into rather brittle sand. Local intrusions of sand forming dykes and sills followed these events, as well as intrusions of pelagic/hemipelagic green argillite originally underlying the sandstone/mudstone association. An abundant occurrence of these mixing and multi-stage injection/intrusion fabrics strongly suggest that the Waipapa Terrane around the study area was a site of high pore-fluid pressure. Scaly-foliated melange fabrics with monoclinic symmetry, originating from layer-parallel shearing, were then locally superimposed on the pre-existing melange fabrics. Similar scaly-foliated fabrics also developed in the chert beds originally intercalated between the green argillite and the uppermost part of the oceanic crust. These scaly fabrics might have been related to the regional stacking and juxtaposition of the accreted sediments. The sequence and variation in style of deformation forming the melange fabrics presumably reflected changes in porosity and state of compaction of accreted sediments in a shallow tectonic level.     

岩溶地层水文水井泡沫钻井压力和排量计算

分析了岩溶地层水文水井施工中,泡沫实现平衡压力或欠平衡压力钻井的原理及影响泡沫钻井有效井眼压力的因素,采用迭代法逆循环计算方法,计算井口压力和井口气液排量。     

Physical and chemical environments of abnormal vitrinite reflectance evolution in the sedimentary basins

Based on the tested data of pressure and vitrinite reflectance of some wells in sedimentary basins, abnormal high pressure is regarded as not the only factor to retard the increase of vitrinite reflectance (R _o). Apart from the types of the organic matter, the physical environment (temperature and pressure) and chemical environment (fluid composition and inorganic elements) will result in the abnormal vitrinite reflectance values in the sedimentary basins. This paper tested trace elements and vitrinite reflectance data from the the abnormal high pressure and normal pressure strata profiles, respectively, and found that the acidic and lower salinity starta are favorable for the increase of R _o. By discussing the corresponding relationship between the contents of some trace elements in the mudstone and the vitrinite reflectance values, the typical trace elements were found to suppress and/or catalyze the vitrinite reflectance of organic matter, while the elements of Ca, Mn, Sr, B, Ba and P may result in the retardation of R _o. However, elements of Fe, Co, Zn, Ni and Rb may catalyze the organic matter maturation. This study is conductive to the organic maturation correction, oil and gas assessment and thermal history reconstruction by the paleothermometry. Translated from Acta Geologica Sinica, 2006, 80(11): 1760–1769 [译自: 地质学报]