中国铝物质流历史变化分析和再生铝资源利用研究

本文采用物质流分析(Material Flow Analysis, MFA)的方法, 构建了铝全生命周期动态物质流分析框架, 自上而下的追踪了1949—2021年中国铝的流量、存量和供需情况。结果表明: 1)1949—2021年中国铝土矿铝物质累计流入量5.86亿t, 国内开采与进口各占一半左右。实际铝物质累计消费量3.74亿t。生命周期内铝损失严重, 铝物质损失量2.39亿t。2)2021年人均铝物质社会存量208.9 kg/人, 与同经济发展时期的北美、日本基本一致。3)1990年以来中国再生铝产量快速增长, 累计0.77亿t, 以国内生产为主, 占比76.7%。随着含铝产品到达寿命及未来铝需求量的持续走高, 将迎来含铝产品的报废时代。建议从全生命周期的角度出发, 减少铝在各个环节的损失量; 合理布局再生铝产业, 提高再生铝的利用, 优化铝供应结构, 促进铝工业低碳转型, 支撑“双碳”目标的实现。     

三元复合驱采出污水回注渗透率的影响因素分析

基于大庆油田三元复合驱采出污水回注对地层存在的损害现象,研究了污水回注渗透率的影响因素。采用室内水驱实验方法,对三元复合驱采出污水中悬浮物、油、碱、聚合物等因素进行了分析,阐述了各种成分对渗透率的影响机理。结果表明,悬浮物颗粒会堵塞孔隙喉道,油产生的“贾敏效应”将增大油水流动阻力,碱与岩石及黏土矿物问的物理化学作用会使地层结垢,聚合物在岩芯中的吸附和滞留共同造成地层渗透率的下降。因此,建议将三元复合驱采出污水中悬浮物、油、碱、聚合物等处理合格后再进行回注,以减轻对地层的损害。     

Isotopic tracing of ore-forming source materials for Dexing porphyry copper deposit of Jiangxi, China

Dexing copper deposit is the biggest porphyry copper deposit in China. By researching isotopes of C, Si and Cu from the samples of Tongchang and Fujiawu ore-field, the authors found that δ^13 CpDB values of siderite were close to the δ^13 CpDB value of original magma; δ^30Si values of the samples at the ore-forming stage were close to the δ^30 Si value range of magma, δ^30Si values of partial samples were far away from it; Cu isotopic compositions of massive chalcopyrite formed at the early ore-forming stage are higher than that of veinal chalcopyrite formed at the later ore-forming stage. The results show that ore-forming materials were mainly derived from the porphyry body, and part of them were from wall rock materials.     

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Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.     

初论成矿场与矿产勘查意义

成矿场是指地质历史时期某成矿地区引起岩石变形的应力场,承载成矿作用引起流体效应的流体场,以及成矿元素迁移、沉淀、富集、叠加改造形成的物质场的总称.分析了一个成矿地区应力场、流体场、物质场的空间关系、研究内容与研究方法.根据成矿背景、控制因素、成矿环境将其分为7类成矿场,即:逆冲(推覆)-后伸展构造背景成矿场、走滑-伸展(伸展-走滑)-后逆冲构造背景成矿场、中酸性火山(次火山)岩浆活动背景成矿场、基性-超基性岩浆活动背景成矿场、盆地裂谷-海底喷流环境成矿场、外生海相建造环境成矿场、外生陆相建造环境成矿场.对前5类成矿场(以内生矿产为主)进行了系统的内涵表述.在此基础上对前5类成矿场的矿产勘查过程中关键地质因素进行了归纳分析,这对具体矿产勘查工作具有现实的指导意义.     

云南建水水草冲铜矿矿床地质特征及成矿物质来源

本文通过研究云南建水水草冲铜矿地质特征、围岩玄武岩和矿石矿物的微量元素、S、C、O同位素的组成,示踪了该矿床的成矿物质来源和性质。研究结果表明,云南建水水草冲铜矿位于滇东南哀牢山变质体北侧,容矿围岩为峨眉山玄武岩,矿体受北东向逆断层及其次级断裂控制,延深大于延长,形状不规则,矿体内多夹灰岩角砾及矿化玄武岩角砾,矿石矿物主要为黄铜矿,矿化蚀变以硅化、碳酸盐化、绿泥石化为主。水草冲铜矿黄铜矿与黄铁矿稀土元素具有相同的稀土元素组成与含量,ΣREE平均为1.901×l0-6,富集轻稀土元素,轻重稀土元素比(LREE/HREE)平均为8.188,（La/Yb）N值平均为10.259;δEu值平均为0.977;Ce呈现弱负异常,δCe值平均为0.808。黄铁矿中的Co/Ni比值为0.835,显示水草冲铜矿床为中温热液矿床;黄铁矿的Y/Ho比值平均为38.23,表明水草冲铜矿床的成矿流体为混合来源。结合黄铁矿的稀土微量元素特征,推断水草冲铜矿床的成矿流体是Cl多于F的流体。S的来源复杂,黄铁矿δ34SCDT（‰）的变化范围（18.3~29.4）与海水硫酸盐(海相蒸发岩)的δ34S值接近或略低;黄铜矿δ34SCDT（‰）变化范围是-0.5~10.1,表明有深部硫的参与。δ13C V-PDB（0.9‰~2.6‰）,δ18O V-SMOW（14.3‰~15.9‰）反映了方解石流体可能为热液循环萃取沉积岩地层混合形成。综上,推测成矿物质为后期构造热液萃取围岩（玄武岩和灰岩等）所得,其中铜主要来自于玄武岩本身,而硫的来源以地层硫为主。     

从可持续发展的物质体系谈辽宁省的矿业与环境

从矿业资源、环境与生态的平衡关系出发,讨论了矿业资源领域在社会经济发展中的极其重要的基础地位;从矿产资源的不可再生性等特点讨论了矿业资源的可持续发展对全社会经济可持续发展战略实施的决定性作用; 从矿产资源开发、利用的现状已对环境产生的危害和正在产生的危害,讨论了矿业可持续发展的必要性、紧迫性和艰巨性。通过对辽宁省矿产资源的特点、矿业开发利用的现状及其矿业环境的分析, 讨论了矿业开发利用与矿山环境保护之间内在的、不可分割性和影响因素,并在此基础上提出了建议。     

关于土地资源质量

本文在阐述土地资源质量概念的基础上,结合相关学科理论,重点论述了反映土地资源质量的两方面内容;一是空间形态特征,包括起伏量、坡度、坡长、坡形及侵蚀和沉积程度;二是物质特征,包括土体构型、结构质地、物理性质、物质组分、化学性质以及生态功能等