Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

辽宁西丰一带侵入岩形成环境和成因探讨

西丰一带侵入岩即以前所说的西丰大岩体,是布列亚-张广才岭巨型花岗岩带组成部分.该巨型花岗岩带记录了造山带从古亚洲洋板块开始俯冲、洋盆闭合到增生造山演化过程的基本信息.现在已经将规模宏大的西丰大岩体进行了详细解体,重新归并成4个侵入期次,划分为11个侵入序次,统称辽宁省西丰一带侵入岩.在详细解体、重新归并和划分的基础上,进一步探讨了各序次侵入岩形成的温压条件、构造环境、物质来源与成因.早二叠世第一序次、第二序次侵入岩以及中侏罗世第一序次侵入岩为I型花岗岩,晚白垩世第三序次(闪长玢岩)也为I型,主要物质来源是地壳中岩浆岩重熔的成分.其余各序次侵入岩均为S型花岗岩,主要物质来源是地壳中沉积岩重熔的成分.西丰一带,早二叠世第一个序次侵入岩为火山弧型深成岩,早二叠世第二个序次侵入岩为火山弧型与同碰撞型的过渡类型.早二叠世第三序次至中侏罗世第各序次侵入岩和晚白垩世各序次侵入岩为同碰撞型和碰撞后型花岗岩.这些特征与古亚洲洋晚期的消减、闭合和增生造山演化序列基本吻合.     

吉林省油页岩勘探中聚合物钻井液防塌机理的试验研究与应用

在试验研究的基础上对比了无机聚合物硅酸盐和有机聚合物聚乙烯醇(PVA)、部分水解聚丙烯酰胺(PHPA)和非水解聚丙烯酰胺(PAM)的防塌能力;由试验得出吸附成膜的速度和保护膜的致密程度是决定钻井液体系防塌能力的关键因素;钻井液体系的防塌能力是无机聚合物和有机聚合物协同作用的结果;部分水解聚丙烯酰胺钻井液体系的防塌能力较非水解聚丙烯酰胺钻井液体系的防塌能力强。研制的无固相聚合物钻井液在吉林农安、伊通、舒兰和梅河口4个矿区近3 000 m的钻探施工中,孔壁稳定,孔内事故少,岩芯采取率达98%以上。     

青藏高原复杂地层地质钻探低固相冲洗液试验研究

青藏高原由于地质条件的多样性,分布有松散破碎地层、高应力地层、断层破碎带等复杂地层,在地质钻探中经常遇到塌孔、漏浆、缩径、卡钻、埋钻等问题。同时配套使用的冲洗液形成的泥皮质量差、胶结能力较差、携岩粉能力较弱等不足。冲洗液的性能是实现复杂地层顺利钻进的关键。结合青藏高原复杂地层的地质特点,研发了低固相聚合物新型冲洗液,该冲洗液以钠质膨润土和微泡剂等外加剂为基础,具有流动性好、胶结性强、降失水量适中的特点,适宜在青藏高原复杂地层地质钻探中使用。     

滦县地磁场井下观测系统抗干扰效果

近距离铁磁性物质干扰(农田耕作、基建等)、直流供电干扰(高压直流输电、地电阻率观测等)是地磁场地面观测的主要干扰方式。在滦县地震台布设地磁场井下观测系统,检验井下观测的抗干扰效果,结果发现,地磁场井下观测可抑制近距离铁磁性物质干扰,但无法抑制直流供电干扰(可通过避让一定距离解决),该分析结果为未来地震监测手段的选取提供技术参考指标和依据。     

地热井固井材料导热性能影响因素

固井材料导热性能是影响地热井取热效果的因素之一。为提升地热井固井材料导热系数,采用正交试验,借助层次分析-指标重复性相关（AHP-CRITIC）混合加权法和极差分析,进行固井材料导热性能研究。结果表明：添加天然鳞片石墨、铁粉和石英砂均可提高固井材料导热系数,其中石墨对导热系数的提升作用最为显著,铁粉次之,石英砂最小;石墨掺量和水固比分别是影响固井材料综合性能的主次要因素;随着石墨掺量递增,其导热系数递增、48 h抗压强度和流动度均递减;得出高导热固井材料的优选配合比为：水固比值0.44,石墨、铁粉和石英砂掺量分别占水泥质量的7.5%、3%、2%,其导热系数可达1.87 W/（m·K）,较常规固井材料提高约70%。研究成果可为地热能高效开发利用提供参考。     

Spectral identification of materials by reflectance spectral library search

Spectral library search is emerging as a viable approach for material identification and mapping by reusing spectral knowledge gained from hyperspectral remote sensing across space and time. The potential of retrieving meaningful spectral material identifications in the presence of reflectance of spectra of various material types and with various similarity metrics has been assessed in this study. Test reflectance spectra of various vegetation, minerals, soils and urban material types are identified by searching through the composite reflectance spectral library obtained by combining various institutional reflectance spectral libraries. The accuracy of material identifications under various conditions: (i) in the presence of identical, similar and dissimilar spectra; (ii) in the presence of only identical and dissimilar spectra; and (iii) in the presence of only dissimilar spectra has been assessed with several similarity metrics. Results indicate the possibility of obtaining 100% accurate material identifications by library search if the spectral library contains identical spectra. However, the presence of a large number of similar spectra, despite the presence of identical spectra, is found to increase false positives, thereby reducing the accuracy of retrievals to 82% at best. Further, the accuracy of material identifications in the presence of similar spectra is similarity metric-dependent and varied from about 52% (obtained from Binary Encoding) to 82% (obtained from Normalized Spectral Similarity Score). Overall, results support the possibility of using independent reflectance spectral libraries for material identification while calling for robust spectral similarity metrics.     

膜分离技术的应用及发展趋势

综述世界和中国膜分离技术的发展，并对膜分离技术的基本特性、技术特点、膜材料、分类及膜分离装置进行了简单介绍；并介绍了膜分离法在化工及石油工业、食品工业、医药工业和医疗设备、生物技术和环境工程中的应用，并分析了膜分离技术将会在膜材料、新的膜过程和集成膜过程3个方面的发展趋势。同时指出如果能解决膜产品的价格、膜污染和膜分离性能的提高这3个膜的制约因素，膜分离技术将在人类社会的发展史上起到不可替代的作用。     

贵州下寒武统黑色岩系多金属矿层成矿物质来源的铅同位素示踪

为探讨贵州黑色岩系多金属矿层的成因和成矿物质来源,文章对镇远江所出露的黑色岩系多金属层铅同位素进行了测试。结果表明,黑色岩系多金属矿石铅来源于壳源混合铅,且具有富铀铅贫钍铅的特点,下寒武统牛蹄塘组的下伏灯影组富铀铅而贫钍铅的化学沉积物可能提供了较多的成矿物质。成矿物质主要来源于地壳,具有地幔铅混染的特点,是岩浆作用,化学沉积作用,海底热水作用共同参与的结果。黑色岩系多金属矿层的形成是多种成矿作用过程叠加的结果,具有多来源,多期次的成矿特点。     

广西姑婆山地区钨锡矿床地质特征及幔源物质参与成矿显示

姑婆山地区钨锡矿床位于南岭钨锡成矿带西南缘,是我国重要的钨锡产地。区内有新路、水岩坝和珊瑚三个钨锡矿田,矿床类型多样。其中,锡锌硫化物型、黑钨石英脉型和钨锡石英脉型矿床较为典型,区内钨锡成矿与壳幔混源型花岗岩体和断裂关系密切。笔者在前人工作基础上,总结了区内主要钨锡矿田和典型矿床地质特征,认为钨锡矿化在空间上具有一定的分带性;通过对区内构造和矿床的D-O同位素、H e-A r同位素、Pb同位素、S同位素及流体包裹体分析,认为深大断裂可能为幔源物质上侵提供了通道,钨锡成矿与岩浆作用关系密切,幔源物质参与了区内钨锡成矿。