冀中坳陷饶阳凹陷留西地区古近系沙河街组沙三上亚段沉积相与隐蔽油藏

通过岩心观察和单井相分析,结合沉积背景资料,认为留西地区古近系沙河街组沙三上亚段发育辫状河三角洲相和湖泊相,以辫状河三角洲前缘亚相和滨浅湖亚相为主,主要发育辫状分流河道、越岸沉积、水下分流河道、河口坝、席状砂等微相。根据层序地层学基本原理,结合前人研究成果,认为本区沙三上亚段为一完整的三级层序,可划分为低位、湖侵和高位3个体系域,分别对应于沙三上亚段沉积时期的早期、中期和晚期,绘制了每个沉积阶段的沉积相图,在此基础上研究了沉积体系的平面展布特征。沙三上亚段沉积时期形成的北高南低的构造背景与辫状河三角洲近东西向展布的砂体形态相互配置,加之良好的油源供给,为后期成藏创造了条件。沙三上亚段沉积早期发育的辫状河三角洲前缘水下分流河道与河口坝砂体是主要的储集体,与沉积中期发育的烃源岩形成了十分有利的生储盖组合,具有优越的隐蔽油藏发育条件。总结了该区隐蔽油藏成藏的4种模式,确定留西地区中南部沙三上亚段沉积早期发育的辫状河三角洲前缘砂体是下一步隐蔽油藏勘探的有利目标。     

黄骅坳陷埕北断坡不整合特征与油气成藏

黄骅坳陷埕北断坡处于歧口凹陷向埕宁隆起过渡的斜坡带上,发育多个不整合,这些不整合对该区的油气成藏起重要作用。利用地震资料,在剖面上将不整合划分为5种类型：褶皱不整合、断褶不整合、削截不整合、超覆不整合、平行不整合。其中平行不整合分布在凹陷区,褶皱不整合分布在基底,断褶不整合分布在大断裂下降盘,削截不整合分布在大断裂上升盘,而超覆不整合多分布在隆起斜坡区;利用测井资料,在纵向上将不整合划分为3层结构：不整合面之上岩石、风化粘土层及半风化岩石,由于每层结构的岩性与厚度不同,形成ACE型、ADE型、BCE型和BDF型4种岩性配置模式。不整合构成埕北断坡油气侧向运移的重要通道,同时在其之上形成超覆不整合油气藏,在其之下依靠风化粘土层遮挡形成削截不整合与褶皱不整合油气藏。勘探证实,研究区众多油气显示或油气藏均位于不整合面上、下50 m范围内。开展不整合与油气成藏关系研究,将拓宽黄骅坳陷隐蔽油气藏的勘探空间,对我国东部油气资源挖潜具有重要的理论与实践意义。     

我国古生代海相碳酸盐岩成藏理论的新进展

近年来在中国古生界新发现大中型油气田40多个,其中大型油气田16个。在长期研究中国古生代海相沉积特征的基础上,总结归纳近几年来新发现的海相烃源岩,提出对碳酸盐岩有效烃源岩的新认识。从有效烃源岩、古岩溶储集体、油气成藏期次和成藏模式等四个方面概述油气成藏理论方面的新进展;根据油气成藏史研究,结合区域构造演化史、生烃史等,提出塔河油田奥陶系有四个成藏期:加里东中晚期至海西早期;海西晚期;燕山期-喜马拉雅早中期;喜马拉雅晚期。     

四川盆地泸州古隆起嘉陵江组储层特征研究

对研究区嘉陵江组沉积背景认识的基础上,通过岩心观察、岩石薄片确定了不同类型的储集岩和储集空间,得出本地区储层岩石类型和储渗空间类型均多样化的特点。从成因角度识别出来了溶蚀孔隙型储层、膏溶孔洞型储层、裂缝型储层等三类储层。研究不同类型储层的孔、渗特征及关系表明,溶蚀孔隙型储层物性要优于膏溶孔洞型储层,而溶蚀孔隙型储层中的颗粒云岩溶蚀孔隙型储层物性最好、颗粒灰岩溶蚀孔隙型物性其次、粉晶云岩溶蚀孔隙型储层物性最差,其原因是不同储层受沉积环境和成岩作用控制和影响。     

Ostracode carbonate δ18O- and δ13C-signature of hydrological and climatic changes affecting Lake Neuchâtel,Switzerland, since the latest Pleistocene

Floating and grounded peat plateaus were studied in fens in the Yukon Territory (Canada). The peat deposit may be over 4 m thick and consists of a lower bed of aquatic peat overlain by humic fen peat, mesic fen peat and woody peat. Permafrost in the grounded peat plateaus is older than the 1200 year old White River Ash, whereas permafrost in the floating peat plateau is younger.Peat accumulation rates since 1200 years B.P. were greater in the fens (85–100 cm) than on the surface of the peat plateaus (25–55 cm). Where the peat plateau is free-floating, it will persist until the climate changes, causing the icy core to thaw. Where the peat plateau is frozen to the mineral substrate, it slowly drowns since the fen peat accumulates faster than the woody peat. This drowning results in degradation of the landform independently of the climate. Only degradation of floating peat plateaus can be used to identify climatic changes.This publication is the first paper in a series of papers presented at the session on Past Climatic Change and the Development of Peatlands at the ASLO and SWS Meetings in Edmonton, Canada, May 30–June 3, 1993. Dr. P. Kuhry and Dr S. C. Zoltai are serving as Guest Editors.     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.     

珠江口盆地西江主洼油气差异分布机制

西江主洼是珠江口盆地一个低勘探程度洼陷，油气差异聚集特征明显，但其机理不清。本文在断陷盆地油气成藏理论指导下，利用研究区地质、地球物理和地球化学等资料，开展了烃源岩、断盖组合、储集体系和运聚模式等方面的研究。结果表明，裂陷期沉降、沉积中心有序迁移，造成主力烃源岩自东向西由文四段迁移至文三段、文一+二段，控制东、西部油气差异分布。恩平组区域性泥岩发育且晚期断裂缺乏，导致油气纵向上更易聚集于下构造层；区域泥岩减薄尖灭或晚期断裂切开盖层的区域，上构造层有一定油气分布。"源-汇"类型从宏观上控制储层优劣，影响下构造层油气富集程度；"仓储"运移是控制上构造层油气规模聚集的主要模式。下构造层古近系应作为重点部署方向，东部围绕文四段、西部围绕文三段、文一+二段烃源岩构成的含油气系统展开；上构造层勘探需关注珠海组，在隆起周边寻找具备"仓储"运移模式的有利区带。     

Channel overflows of the Pōhue Bay flow,Mauna Loa,Hawai'i: examples of the contrast between surface and interior lava

A number of overflows from a large lava channel and tube system on the southwest rift zone of Mauna Loa were studied. Initial overflows were very low viscosity gas-rich phoehoe evidenced by flow-unit aspect ratios and vesicle sizes and contents. Calculated volumetric flow-rates in the channel range between 80 and 890 m³/s, and those of the overflows between 35 and 110 m³/s. After traveling tens to hundreds of meters the tops of these sheet-like overflows were disrupted into a surface composed of clinker and phoehoe fragments. After these 'a' overflows came to rest, lava from the interiors was able to break out on to the surface as phoehoe. The surface structure of a lava flow records the interaction between the differential shear rate (usually correlated with the volumetric flow-rate) and viscosity-induced resistance to flow. However, the interior of a flow, being better insulated, may react differently or record a later set of emplacement conditions. Clefts of toothpaste lava occurring within fields of clinker on proximal-type 'a' flows also record different shear rates during different times of flow emplacement. The interplay between viscosity and shear rate determines the final morphological lava type, and although no specific portion of lava ever makes a transition from 'a' back to phoehoe, parts of a flow can appear to do so.     

Field calibration and performance of sediment traps in a eutrophic holomictic lake

In wind-stressed and unstratified Lough Neagh low aspect ratio sediment traps, which allow for internal resuspension, collected sediment at a rate close to the natural sediment accumulation rate inferred from dated sediment cores. High aspect ratio traps grossly overestimated the natural rate of sediment accumulation as did, but to a lesser extent, burial rate measurements on an artificial stratigraphic marker. The former type of trap deployed over long exposure periods is therefore recommended as providing the best estimate of net downward particle flux in lakes such as Lough Neagh. However, it is emphasized that all sediment trap types, when operated in shallow turbulent lakes, will to a greater or lesser extent be contaminated by secondary or redeposited material and so will not provide a direct measure of primary sedimentation. Use of tube traps in lakes such as Lough Neagh should not, however, be discounted since they can provide a record of the quality of sedimenting material through time.