Seismic image of the deep crust at the eastern margin of the Alps (Austria): indications for crustal extension in a convergent orogen

A 39-km-long deep seismic reflection profile recorded during two field campaigns in 1996 and 2002 provides a first detailed image of the deep crust at the eastern margin of the Eastern Alps (Austria). The ESE–WNW-trending, low-fold seismic line crosses Austroalpine basement units and extends approximately from 20 km west of the Penninic window group of Rechnitz to 60 km SSE of the Alpine thrust front.The explosive-source seismic data reveals a transparent shallow crust down to 5 km depth, a complexly reflective upper crust and a highly reflective lowermost crust. The upper crust is dominated by three prominent west-dipping packages of high-amplitude subparallel reflections. The upper two of these prominent packages commence at the eastern end of the profile at about 5 and 10 km depth and are interpreted as low-angle normal shear zones related to the Miocene exhumation of the Rechnitz metamorphic core complex. In the western portion of the upper crust, east-dipping and less significant reflections prevail. The lowermost package of these reflections is suggested to represent the overall top of the European crystalline basement.Along the western portion of the line, the lower crust is characterised by a 6–8-km-thick band of high-amplitude reflection lamellae, typically observed in extensional provinces. The Moho can be clearly defined at the base of this band, at approximately 32.5 km depth. Due to insufficient signal penetration, outstanding reflections are missing in the central and eastern portion of the lower crust. We speculate that the result of accompanying gravity measurements and lower crustal sporadic reflections can be interpreted as an indication for a shallower Moho in the east, preferable at about 30.5 km depth.The high reflectivity of the lowermost part of the lower crust and prominent reflection packages in the upper crust, the latter interpreted to represent broad extensional mylonite zones, emphasises the latest extensional processes in accordance with eastward extrusion.     

地质流体对砂岩储层黏土矿物的影响——以渤海海域古近系为例

根据偏光显微镜、扫描电镜和X-衍射等分析手段获取的数据和资料,分析对比了早期沉积水介质、幔源CO2流体、大气水、超压流体和充注烃类等对储层黏土矿物的控制作用。研究表明,早期沉积水介质是储层黏土矿物的决定性因素,微咸水-半咸水湖盆储层黏土矿物以伊利石为主,淡水湖盆储层黏土矿物以高岭石为主;幔源CO2流体侵位后带来明显的储层改造和热波动效应,储层中I/S中S%含量低于同深度泥岩,储层中高岭石含量明显偏高。欠压实超压储层中黏土演化明显滞后,表现在I/S中S%含量低于同深度泥岩和常压储层。油气层高岭石含量往往远高于相近深度的水层,可能与充注烃类携带的有机酸的溶蚀作用有关,另外,烃类充注后形成的惰性成岩环境也有利于高岭石的保存,高岭石的高含量带常与油层及高渗层相对应;受大气水淋滤的储层,以长石大量溶蚀,富含高岭石为特征,储层孔隙度一般较高。     

砌体和钢混结构建筑群的破坏概率模型研究

通过对已有震害预测的易损性矩阵进行研究,对目前易损性矩阵的概率模型进行了修改。分析了华南地区建筑群的3种主要结构类型:钢混结构,砖混结构和砖木结构。将3种结构在各种烈度下的破坏状态分别进行了拟合和参数计算,针对其差异性提出了偏态分布和正态分布,给出了不同的破坏概率模型。在广东省惠州市数据的验算下,证明了对于砌体和钢混建筑群易损性矩阵的呈现有一定的参考意义。     

西藏纳木错晚更新世以来湖面变化和湖相沉积中粘土矿物显示的环境信息

通过对西藏海拔最高、面积最大湖泊-纳木错周缘湖相沉积、湖岸堤的野外调查和湖岸阶地的水准测量,发现在纳木错沿岸拔湖48m以下,发育有6级湖岸阶地,拔湖48~139.2m发育有高位湖相沉积。湖相沉积物的同位素测年结果表明,纳木错湖泊发育与藏北高原东南部古大湖演化可划分为3个阶段:①116~37kaB.P.间的古大湖期;②37~30kaB.P.间的外流湖期;③30kaB.P.以来的纳木错期。根据纳木错晚更新世以来湖相沉积中粘土矿物的X光衍射分析结果,以及采用比值法、高岭石法和衍射峰法的研究,探讨了粘土矿物所显示的环境变化信息。粘土矿物成分变化表明,该区已具备了寒温带干旱、半干旱区的气候环境特征。为研究青藏高原的湖泊演化、气候变化、古地理变迁及其隆升过程等提供了新资料。      

Bragg resonant reflection of carrier waves composing wave groups

Numerical analyses for the Bragg resonant reflection of carrier waves associated long waves due to sinusoidally varying seabeds are performed by using a set of coupled ordinary differential equations derived from the Boussinesq equations. The Boussinesq equations are firstly approximated with the Fourier decomposition. The coupled governing equations are then derived and used to simulate evolution of both short and long wave components. It is also found that wave groups are generated by two carrier waves with slightly different frequencies. The wave energy of the initial wave components is transferred to other harmonic components during propagation over a long distance. Evolution and reflection of both short and long waves were largely affected by nonlinearity.     

老挝甘蒙省钾镁盐矿床中微量硼矿物的鉴定和准确定名

以老挝甘蒙省钾镁盐矿床ZK318钻孔的含矿段(下盐层)为研究对象,对其开展了微量硼矿物的鉴定研究工作,以完善矿床的矿物组合类型。全岩样品的XRD初步结果给出,在顶部钾盐岩层中含有少量方硼石。为了进一步全面鉴定硼矿物的种类,对全岩样品溶解后得到的不溶物多晶集合体进行XRD分析,结果表明,不溶物中的硼矿物主要为方硼石(55%),其次为三斜晶系3A型氯硼钙石(15%)。3A型氯硼钙石在全岩样品中的含量不足1%,属微量矿物,因低于XRD的检出限,故在全岩样品的XRD图谱中无该矿物的衍射峰出现。此外,对三斜晶系3A型氯硼钙石的中文准确命名进行了讨论,指出中文定名应与国际惯例一致,即废除副水氯硼钙石(parahilgardite)一词,定名为3A型氯硼钙石(hilgardite-3A)以体现结构的微细差别,同时达到中文命名规范统一的目的。因此,该矿床中的硼矿物为少量方硼石和微量3A型氯硼钙石。     

矿山酸性水中铝相次生矿物及环境学意义的研究进展

酸性矿山排水（AMD）是硫化矿床矿山环境污染防治的难点,因而持续受到国内外学者的关注。众多的学者对矿区AMD中次生矿物进行了研究。为深入了解AMD中次生矿物的形成和演化,为AMD污染防治提供科学依据,笔者对前人不同环境下AMD中的次生矿物类型、次生矿物形成顺序,以及铝相次生矿物的形成、特征、环境危害及意义进行了简要综述。目前与AMD有关的主要次生矿物存在3种类型,即铁相次生矿物、铝相次生矿物和其他相次生矿物,AMD中的pH、Eh和温度对于次生矿物的形成具有控制性的作用。铁、铝相次生矿物具有吸附金属能力,这一性质有助于在一定程度上实现河流的自净化作用。由于AMD形成条件高,矿物相不稳定,目前有关AMD中铝相次生矿物及“酸性白水”的研究成果有限。因此,加强铝相次生矿物以及“酸性白水”的研究,可以更好地解析蒿坪河流域石煤矿区河流酸性磺水–酸性白水的形成演化机制,以及铝相次生矿物吸附重金属的地球化学过程。     

Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

塔中地区顺9井区柯坪塔格组黏土膜成因及其油气地质意义

为寻觅致密砂岩储层中发育的优质储层提供理论依据,分析铸体薄片鉴定、扫描电镜资料、结合压汞及物性资料.结果表明:塔里木盆地塔中顺9井区志留系柯坪塔格组沥青砂岩中发育的黏土矿物薄膜形成于成岩早期(同生成岩期),以自生式为主,含少量原生式黏土膜;黏土膜的发育与分布受到沉积作用、成岩环境及成岩温压系统的共同控制,早成岩期(同生期)发育的黏土膜在中—低压实强度下对储层的孔隙保护具有一定的建设性作用,因其占据一定的孔喉空间,又降低储层的渗透率,随着埋深增大,黏土膜矿物成分也逐渐向伊利石转化并分布在孔隙中,伊利石赋存状态也由蜂窝状变为毛发状、丝网状及搭桥状,分割甚至堵塞孔隙,使得储层砂体渗透率大幅度降低;沉积环境中的沉积微相对黏土膜发育与分布的控制体现在中—下临滨微相中黏土膜较为常见,而在上临滨—前临滨微相中,因水体的淘洗降低储层砂体中的泥质含量,黏土膜不发育,储层砂体中的黏土膜含量制约储层质量,发育黏土膜的井段储层孔隙度大于不发育黏土膜的井段,黏土膜含量在0.5%～5.0%井段的储层孔隙度要好于黏土膜含量超过5.0%井段的.     

华北板块北缘东段中元古代造山带地质特征及构造演化

研究区内的中元古代魏家沟岩群原岩为一套碳酸盐岩、陆缘碎屑岩及火山岩建造,形成于大陆裂谷-活动大陆边缘阶段,并于1036 Ma左右遭受变质变形.通过岩浆岩形成构造环境的判别,研究区中元古代岩浆活动贯穿于板块碰撞前、同碰撞及碰撞后.伴随着造山带的演化,本区中元古代经历了3期韧性变形,分别形成于大陆裂谷、活动大陆边缘及碰撞造山阶段.通过上述研究,确定了本区中元古代造山带的存在,并经历了大陆裂谷-被动大陆边缘-活动大陆边缘-碰撞造山的地质演化过程,证实了格林维尔造山运动在华北板块北缘的存在和对中元古代末期Rodinia超大陆拼合的响应.