中国稀土矿床成因类型

稀土矿床和稀土矿化地区在地质空间和地质时间的分布方面各有规律。空间上既分布于稳定地区(地台和准地台),亦分布于活动地区(地槽和褶皱系)。在地质时代方面,各造山运动和岩浆活动期都能够成矿,尤以海西期和燕山期矿化规模大,面积广。根据成矿条件,将稀土矿床划分为十种成因类型,即:1)花岗岩、碱性花岗岩、花岗闪长岩、钠长石化花岗岩型;2)碱性岩型;3)火成碳酸岩型;4)矽卡岩型;5)伟晶岩型;6)变质岩和沉积变质碳酸盐岩石型;7)热液交代和热液脉型;8)沉积岩型;9)稀土砂矿型;10)花岗岩类风化壳型。     

Evolution of Cretaceous–Cenozoic quartz pebble conglomerate gold placers during basin formation and inversion, southern New Zealand

Numerous auriferous fluvial quartz pebble conglomerates (QPCs) are present within the Late Cretaceous–Recent sedimentary sequence in southern New Zealand. The QPCs formed in low-relief settings before, during, and after regional marine transgression, in alluvial fan and a variety of fluvial and near-shore depositional settings: In particular, during slow thermal subsidence associated with Late Cretaceous–early Cenozoic rifting, and during the early stages of orogenic uplift following mid Cenozoic marine regression. QPC maturity characteristics are complex and vary with sediment transport and recycling history, stratigraphic proximity to the transgressive Waipounamu Erosion Surface, and the amount of first-cycle detritus incorporated during recycling. For pre-marine QPCs, the amount of first cycle detritus varies with tectonic intensity and proximity of the depositional setting to remnant Cretaceous topography. For post-marine QPCs, it varies with tectonic intensity and proximity to Late Cenozoic uplift of basement ranges.QPCs do not form during a single bedrock erosion–sediment deposition cycle: Non-oxidised and/or oxidized groundwater alteration (kaolinisation) of labile minerals in immature sediment and the upper part of underlying basement, and repeated sedimentary recycling, are fundamental processes of QPC formation regardless of the tectonic or sedimentary settings. Altered immature rock disaggregates easily upon erosion, and alteration clays are winnowed to leave quartz-rich residues containing resistant heavy minerals such as zircon and gold. Detrital sulfide survives recycling if deposition and burial in saturated sediments are rapid. QPCs result only if sediment recycling is not accompanied by excessive erosion of fresh basement rock. Uplift of many parts of the Otago Schist belt since late Miocene has raised rocks above the water table, increased erosion rates, and inhibited groundwater alteration and QPC formation. QPC formation is still occurring in Southland, where the water table is high, sediments are saturated and undergoing alteration, and uplift and erosion rates, topography, and fluvial gradients are all low. The QPCs accumulate as residual gravel on the valley floors of low-competence streams that are slowly incising pervasively altered dominantly late Miocene–Pliocene immature conglomerates.QPCs formation essentially represents physical and chemical lagging of precursor strata. Accumulation of detrital gold and other heavy minerals is an inevitable consequence, and most QPCs contain some gold. Three types of significant gold placer have developed in the QPCs. Type 1 placers are essentially eluvial and/or colluvial in origin and form without significant fluvial transport, by residual accumulation in low-competence valleys during low-rate uplift, fluvial incision and QPC formation. Type 2 placers have formed during significant fluvial transport and subsequent fluvial incision, mainly in higher energy proximal and medial reaches of larger pre-marine (Eocene) and post-marine fluvial systems. Type 3 placers formed by wave-base and marine current winnowing in the shallow shelf setting during low-rate regional marine transgression, especially in the Eocene.     

Characteristics of diamondiferous Plio-Pleistocene littoral deposits within the palaeo-Orange River mouth, Namibia

The Orange River, the principal conduit transporting diamonds from hinterland sources to the Namibian coast in post-Cretaceous times, is characterised by an extreme wave dominated delta that has given rise to a progression of coarse rudaceous littoral deposits preserved onshore for > 150 km north of the mouth. Under the long-lived, prevailing vigorous wave, wind and northward longshore drift regimes, the Orange River outfall has been reworked into, amongst others, a series of economically viable, diamondiferous Plio-Pleistocene onshore gravel beach deposits. These placers comprise spits and barrier beaches in the proximal reach within the palaeo-Orange River mouth that, after ca. 5 km northwards, merge into extensive but narrow linear beaches that, in turn after ca. 70 km, give way to pocket beaches. Gravel and diamond size decreases northwards away from the ancestral Orange River mouth. The linear and pocket beach types have considerably higher diamond content but lower average diamond stone size than the two proximal units that are characterised by low diamond grade but comparatively large average diamond size. Given the risk of delineating low grade alluvial diamond deposits accurately, we present here sedimentological reconstructions of the subtidal, intertidal and supra-tidal facies that constitute the spit and barrier beach sequences, based largely on face mapping of exploration trenches and open-cast, mine cuts, as well as the results of large tonnage, sampling campaigns. Diamond distribution is also linked convincingly to basic littoral processes that were operational within the palaeo-Orange River mouth during the complex transgression that gave rise to the + 30 m package in Plio-Pleistocene times. In both the spit and barrier beach settings, the intertidal deposits prove to be the most promising targets whereas the subtidal sediments are the least economic. The constant raking associated with coarse, cobble–boulder-sized gravel foreshore deposits in an energetic micro-tidal wave regime increased the average diamond stone size in the intertidal deposits to 1 to 2 carats per stone (cts/stn), but the lack of fixed trapsites (no competent footwall within the palaeo-Orange River mouth at that level) prohibited the accumulation of substantially enriched diamondiferous gravels. Consequently, grades of only 1.5 to 6 carats per 100 tons (cpht) are realised. The highest grades (2 to 6 cpht) are found in the landward-facing, intertidal beach deposits on the spits where gentle reworking in that sheltered environment had somewhat enriched and preserved the diamond content. Significantly, the low average stone size of ca. 0.5 cts/stn in this lower energy setting probably reflects that of the general diamond population available at that time. In contrast, the sand-rich subtidal deposits in the spit sequence return the lowest grades (0.1 to 0.5 cpht), similar to those in the slightly younger, subtidal transgressive boulder lags of the barrier beaches. However, the stone size in the spit subtidal sediments is also low (0.1 to 0.5 cts/stn) due to the highly mobile, fine-grained character of those deposits, whereas that in the subtidal transgressive lag is large (2 to 3 cts/stn) as a result of the local, semi-permanent turbulence associated with the boulder-sized clasts in these gravel sheets. Diamond distribution is therefore also influenced by littoral facies and associated beach types, in addition to the spatial and temporal parameters that have already been documented for the onshore marine placers of the southern Namibian coast.     

Mineralogy and Geochemistry of Major,Trace and Rare Earth Elements in Sediments of the Hypersaline Urmia Salt Lake,Iran

Urmia Salt Lake(USL) is a hypersaline lake located at the NW corner of the Iran platform. The lake area is estimated to have been over 5000 km~2 at one point, but has now decreased to 1000 km~2 in the last two decades. It contains 4.6×10~9 tons of halite and other detrital and evaporative minerals such as calcite, aragonite, dolomite, quartz, feldspars, augite and sylvite. This study examined the mineralogy and geochemistry of bed sediments along the mid-east toward NE bank sediments collected from 1.5 meters depth and nearby augite placer. Due to the diverse lithology of the surrounding geology, bed sediments vary from felsic in the mid-east to mafic in the northeast. Weathering of tephrite and adakite rocks of the Islamic Island at the immediate boundary has produced a large volume of augite placer over a 40 km length, parallel to the shoreline. Based on the study result, weathering increases from south to north and the geochemistry of the sediments shows enrichment of Mg O, Ca O, Sr and Ba associated with Sr deployment in all samples. Rare earth elements(REE) patterns normalized to the upper continental crust(UCC) indicated LREEs enrichment compared to HREEs with an elevated anomaly of Eu, possibly due to surface absorbance of Mn and Fe minerals, associated with Sr elevation originating from adakites in the lake basin vicinity.     

Platinum-group mineral assemblage of the Prizhimny Creek (Koryak Highland)

In the alluvial deposits of the Prizhlimny Creek (southern part of the Koryak Highland), grains of platinum-group minerals are found along with gold. We have established that the grains are native platinum (Pt, Fe) containing Cu (up to 5 wt.%), Os (up to 8 wt.%), and Rh (up to 2 wt.%). Inclusions in the platinum are native osmium (the content of Ir impurity reaches 12 wt.%, the average content being 0.2–4 wt.%), an unnamed intermetallic compound of composition PtRh, sulfides and arsenides of PGE (cooperite, laurite, malanite, cuproiridsite, cuprorhodsite, sperrylite, hollingworthite, unnamed compounds PdS, (Ir,Ru)S₂, (Ir,Pt)S₂, Cu, and Fe (bornite, chalcopyrite), chromite, and Cr-magnetite. Replacement of native-osmium crystals by compound IrO₂ is described. It has been established that this compound formed during oxidation accompanied by the replacement of isoferroplatinum by native platinum. The data obtained agree with the results of study of platinum-group mineral assemblages from placers localized in weakly eroded Ural–Alaskan-type massifs whose apical parts formed under high oxygen activity conditions. Clinopyroxenites of the Prizhimny massif are considered to be the potential source of PGE.     

中国海域固体矿产资源分布及其区划——砂矿资源和铁锰(微)结核-结壳

综述和研究了我国海域砂矿资源和(微)结核—结壳的分布及其区划。我国的滨海砂矿广泛分布于渤海、黄海、东海和南海,但各省区的砂矿资源分布不同。近年来在我国海域新发现和圈定了多处砂矿品位异常区和矿物高含量区,可分为3个成矿带和24个成矿远景区,资源储量可观。在黄海、东海仅分布铁锰结核,没有发现铁锰结壳,但它们的金属元素含量低,没有潜在资源意义。南海东北陆坡、中央海盆西部和中部是(微)结核、结壳分布较多的区域。南海东北陆坡、海山及其周缘坡脚处的(微)结核、结壳其稀土元素含量较高,可能具有一定的潜在经济价值,今后调查中应引起重视。     

Gold dispersion in Andean desert environments (Atacama, Chile)

The mechanism of Au dispersion in sediments of mountainous desert environments has been studied in two different areas of the Chilean Andes. The San Pedro de Cachiyuyo placer (ca. 1800 m a.s.l.) consists of alluvial fans and ephemeral stream sediments deposited in a stable piedmont. The primary Au source is Cu–Au-bearing hydrothermal tourmaline breccia. The relief of this area is low (1850 m) and the average annual rainfall is ca. 20 mm. The La Coipa area (ca. 4000 m a.s.l.) is characterized by a rugged relief. The annual average rainfall is ca. 100 mm. The sedimentary deposits are less sorted than in San Pedro de Cachiyuyo and consist of ephemeral stream alluvium and slope deposits formed in a periglacial environment. The primary Au sources are two volcanic-hosted epithermal precious metal deposits. At San Pedro de Cachiyuyo, the halo is less than 1 km in length and the highest Au concentration are observed at the break in slope between the hillside and the piedmont. In the La Coipa area, Au was only detected by chemical analysis in the 125–63 μm and <63 μm fraction; however, the dispersion halo extends for over 10 km from the source. In both cases the geochemical signal of gold was strongest in the fraction <63 μm.     

福建南靖砂金表生化学成因的探讨

福建南靖砂金地表地球化学、生物化学成因特征明显,不同于传统的机械成矿模型。区域火山岩地层是砂金的矿源,地表赤红壤化可能是砂金形成的主要阶段。     

黑龙江布鲁嘎里河砂金矿地质特征及成因探讨

布鲁嘎里河砂金矿产于兴华渡口群下兴华组和晋宁期花岗岩分布区。研究区为低山丘陵,经长期风化剥蚀和堆积形成了一系列侵蚀堆积地貌。第四纪松散物覆盖在下兴华组地层和花岗岩之上。目前已圈定２条矿体。矿体连续性好,平面上呈条带状,多为粒状,板状,片状,ＮＥ,ＮＷ向断裂不但控制区内的地貌形态,也为砂金的形成提供了有利地质条件。砂金分布区应该是原生金矿（化）的集中区,在普勘勘探砂金的同时更要注意寻找原生金矿,在兴