A modified analytical method for the shipboard determination of nanomolar concentrations of orthophosphate in seawater

A method for the determination of nanomolar concentrations of orthophosphate in oligotrophic seawater developed by Liang et al. (2007) has been modified to make it fully feasible for shipboard application and for faster sample throughput with minimized sample volume. The technique is based on the flow injection method with solid phase extraction on a Sep-Pak C18 cartridge and colorimetric detector. The Schlieren effect was minimized by rinsing the cartridge sequentially with 5 mL water and 2 mL 95% ethanol solution. With three micro pumps in parallel, savings of up to 80% in amount of reagents and 25% volume of seawater samples could be achieved in comparison to the previous method. Variation of stopped flow time and sample loading time gave 3 different standard curves, which corresponded to 3 linear ranges within 3.4 and 515 nM. The modified method permits the analysis of samples over a wide range of concentrations, and has been successfully applied to shipboard determination of trace orthophosphate in more than 200 seawater samples during a one-month cruise in the South China Sea. For seawater at concentrations of 20.6, 82.5, 206.2 nM orthophosphate, the relative standard deviations (RSD) (n = 6), determined daily for 6 days on board ship were 4.45%, 4.73% and 6.75%, respectively. Five seawater samples collected in the Station SEATS (South East Asia Time Series Station at 18°N, 116°E) were analyzed using the present method both on board and in a land-based laboratory, as well as with the magnesium hydroxide-induced coprecipitation (MAGIC) method, and showed no significant difference according to the statistical t-test.     

中咀湾避风港工程波浪分析及其应用

中咀湾是一个天然的避风良港,一般情况下外海波浪影响很小,主要受局部风场产生的局部风浪影响。本文采用曹宏生在Massel的扩展缓坡方程基础上推导出来的考虑陡变地形和能量耗散效应的缓坡方程为控制方程,结合固边界的反射边界条件,构成波浪传播变形的联合折射、绕射和反射的数学模型。文中将此方法运用在中国台州市大陈岛中咀湾避风港中,用波浪数学模型计算极端高水位和设计高水位时3种波况分别在3组重现期时工程海域的波浪要素,提供防波堤的堤前波高,并分析比较此处实心式和透空式防波堤的防浪性能。     

a′Trous小波变换与PCA变换相结合的遥感影像融合分析

随着高分辨率遥感卫星的产生,传统的融合技术难以达到较好的融合效果,如主成分分析(PrincipalComponents Analysis)变换融合受到融合区域的限制,而传统的小波融合(Wavelet Transformation)算法由于高频直接替换,导致了一定程度的光谱失真,由此本文在分析主成分分析变换和a′Trous小波变换(WT)的基础上,以QuickBird全色和多光谱数据为实验数据,提出了一种将两者相结合的遥感影像融合方法,通过与其他融合方法的定量和视觉比较,结果表明该方法能得到更好的融合效果。     

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几种常见影像融合方法的比较

简述了多源遥感影像融合过程,并利用IKONOS-2的全色影像和多光谱影像,对常用的几种影像融合方法进行了试验与比较,同时对实验结果进行分析和讨论,结果表明小波变换融合算法总体优于其他几种融合方法。     

地面三维激光雷达点云误差分析及校正方法

分析了地面三维激光雷达点云误差来源,提出了相应的误差校正模型。通过实测数据验证,该模型能够消除系统误差,提高了点云精度。     

高速公路接线处中线偏差的一个特殊处理案例

笔者结合高速公路勘测设计中的实践,介绍高速公路接线处中线偏差的处理及调整方法,介绍了其在AutoCAD中处理的一个例子.     

厦门市二调数据成果1980西安坐标转换

根据第二次全国土地调查有关技术文件的要求,各地汇总和提交的成果资料的数学基础必须是1980西安坐标系,而当前许多城市的土地调查工作是基于地方坐标系进行的.本文以厦门市为例,从技术路线、实现方法、精度检查等方面就地方坐标系下的调查成果如何转换为西安坐标系进行了较为详细的探讨,为其他地区的类似工作提供了有益的借鉴.