川滇区域高频地震动地形效应初探

历次强震表明:局域起伏地形对由高频地震动起决定作用的震害存在显著影响。忽略场地浅表土层的影响,凸起地形场地震害高于凹陷地形。然而,由于地形效应影响因素的复杂多样以及公认地形效应表征模型的缺失,已有的宽频带地震动模拟与预测方法并未考虑高频地震动地形效应,这可能导致对地震动时程及参数的错误估计。为此,本文利用当前较具代表性的地形效应量化表征模型,初步分析了川滇区域高频地震动的地形效应。首先,给出了基于量化表征模型的区域高频地震动地形效应计算分析方案;其次,完整地阐述了该方案在川滇地区的应用,并结合漾濞地震震害考察结果初步验证了川滇高频地震动地形效应分析结果的可靠性;最后,讨论了分析结果的局限并给出其应用于宽频带地震动模拟与预测方法中的初步建议。     

Introducing a Novel Approach for Oil-Oil Correlation based on Asphaltene Structure:X-ray Diffraction

Asphaltenes have always been an attractive subject for researchers. However, the application of this fraction of the geochemical field has only been studied in a limited way. In other words, despite many studies on asphaltene structure, the application of asphaltene structures in organic geochemistry has not so far been assessed. Oil-oil correlation is a well-known concept in geochemical studies and plays a vital role in basin modeling and the reconstruction of the burial history of basin sediments, as well as accurate characterization of the relevant petroleum system. This study aims to propose the X-ray diffraction (XRD) technique as a novel method for oil-oil correlation and investigate its reliability and accuracy for different crude oils. To this end, 13 crude oil samples from the Iranian sector of the Persian Gulf region, which had previously been correlated by traditional geochemical tools such as biomarker ratios and isotope values, in four distinct genetic groups, were selected and their asphaltene fractions analyzed by two prevalent methods of XRD and Fourier-transform infrared spectroscopy (FTIR). For oil-oil correlation assessment, various cross-plots, as well as principal component analysis (PCA), were conducted, based on the structural parameters of the studied asphaltenes. The results indicate that asphaltene structural parameters can also be used for oil-oil correlation purposes, their results being completely in accord with the previous classifications. The average values of distance between saturated portions (dr) and the distance between two aromatic layers (dm) of asphaltene molecules belonging to the studied oil samples are 4.69? and 3.54?, respectively. Furthermore, the average diameter of the aromatic sheets (La), the height of the clusters (Lc), the number of carbons per aromatic unit (Cau), the number of aromatic rings per layer (Ra), the number of sheets in the cluster (Me) and aromaticity (fa) values of these asphaltene samples are 10.09?, 34.04?, 17.42?, 3.78?, 10.61? and 0.26?, respectively. The results of XRD parameters indicate that plots of dr vs. dm, dr vs. Me, dr vs. fa, dm vs. Lc, Lc vs. La, and fa vs. La perform appropriately for distinguishing genetic groups. A comparison between XRD and FTIR results indicated that the XRD method is more accurate for this purpose. In addition, decision tree classification, one of the most efficacious approaches of machine learning, was employed for the geochemical groups of this study for the first time. This tree, which was constructed using XRD data, can distinguish genetic groups accurately and can also determine the characteristics of each geochemical group. In conclusion, the obtaining of structural parameters for asphaltene by the XRD technique is a novel, precise and inexpensive method, which can be deployed as a new approach for oil-oil correlation goals. The findings of this study can help in the prompt determination of genetic groups as a screening method and can also be useful for assessing oil samples affected by secondary processes.     

塔河油田碳酸盐岩缝洞型油藏远井储集体定量化表征及动用技术

塔河油田奥陶系碳酸盐岩储层主要储集空间为溶洞和裂缝,直接钻遇溶洞比例达50%。针对目前远井储集体特征认识模糊、动用难度大等问题,基于物质平衡原理及注水指示曲线、液面恢复曲线等资料,对远井储集体的规模、裂缝导流系数、地层能量进行定量化研究,形成了一套远井储集体参数定量化表征技术。基于远井储集体特征,运用酸化、高压注水、复合措施等方法提高对远井储集体的动用,并在塔河油田推广应用,高效井占75%以上,有较好的应用前景。     

鄂尔多斯盆地上三叠统延长组超低渗储层油气成藏启动压力研究

近10年来,非常规油气资源在全球能源格局中的地位愈发重要,低渗透—致密油已成为目前勘探的热点,在我国具有可观的前景。而对于低渗透油气成藏启动压力的研究一直是一个难点,目前仍处于起步阶段,它的完善直接关系到低渗透乃至致密油气成藏的理论研究及勘探。本文首先以鄂尔多斯盆地延长组岩心为基础进行覆压孔隙度、渗透率实验研究,分析储层物性随覆压的变化关系;其次,结合喉道半径与孔、渗的关系,研究喉道半径随有效应力的变化关系,并探讨不同成藏机制的致密油藏的启动压力;最后详细分析鄂尔多斯盆地华池—合水地区上三叠统延长组长7致密油藏的成藏启动压力及成藏下限。结果表明:超低渗储层的孔、渗与有效应力间存在较好的乘幂关系,拟合函数的系数与地表的物性值相关性较好;喉道半径与孔、渗的相关性较好,与孔隙度呈指数关系,与渗透率呈乘幂关系;对于先致密后成藏类型油气藏来说,以渗透率建立的启动压力计算方法可靠,而先成藏后致密或边成藏边致密类型油气藏,启动压力计算方法还有待深入研究。华池—合水地区延长组长7致密油藏成藏时储层渗透率为0.00473×10-3μm2~0.52832×10-3μm2,平均0.01380×10-3μm2;孔隙度为1.458%~10.851%,平均7.224%;储层的平均喉道半径为0.0033~0.3769μm。该区属先致密后成藏,成藏的实际启动压力为0.0788~13.0022 MPa,平均2.1025 MPa。长7源岩的最大埋深为3000 m,原油的充注压力为6.06 MPa,油藏条件下充注的喉道半径下限为8.576×10-3μm,渗透率下限为0.00486×10-3μm2。     

Groundwater potential of the Egbe-Mopa basement area,central Nigeria

Abstract

An investigation on the groundwater potentials of the Egbe-Mopa area in central Nigeria, underlain by the Basement Complex, is presented. The investigation involved mapping of the subsurface by use of vertical electrical soundings; measurement of depth to groundwater; and evaluation of hydraulic conductivity, transmissivity and yield by means of pumping test interpretation. The results indicate subsurface units that range from three to five resistivity layers; depth to groundwater of 0–10 m; overburden thickness of 3–16 m; hydraulic conductivity of 6.2?×?10^?6 to 3.4?×?10^?4 m/s; transmissivity of 4.3?×?10^?7 to 2?×?10^?3 m²/s; and groundwater yield of 0.2–2.5 L/s. The hydraulic head assessments revealed a general northward groundwater flow direction. The study identified three aquifer potential types, of high, medium and low productivity, respectively. Based on the longitudinal conductance of the overburden units, four distinct Aquifer Protective Capacity zones were delineated, namely, poor, weak, moderate and good.

Citation Okogbue, C.O. and Omonona, O.V., 2013. Groundwater potential of Egbe-Mopa basement area, central Nigeria. Hydrological Sciences Journal, 58 (4), 826–840.     

地震多属性综合解释的支持向量机方法研究

能够同时对多种属性进行训练,具有优秀推广能力的支持向量机(Support Vector Machine,简称SVM)方法是进行高精度地震参数预测的有力保障。然而,支持向量机中用于构建回归估计函数的参数最优解很难确定。针对该问题,通过建立数学模型进行参数选择研究,总结出了参数ε、C、σ2对样本预测的影响规律。在此基础上提出了求取惩罚因子C和核参数σ2的权系数公式。结合提出的参数求取公式,利用支持向量机方法,以地震属性为输入向量对渤海SZ36-1油田的砂泥岩百分比和孔隙度进行了预测。结果表明,利用该方法对储层参数进行预测具有较高的预测精度;权系数公式的提出极大地缩短了构建回归估计函数所耗用的时间,简化了参数选取的难度。     

弹性参数直接反演技术在储层流体识别中的应用

叠前地震反演是目前应用于流体识别的主要技术,但在具体研究区储层地质地震特点的应用过程中,存在岩石物理基础研究薄弱、多解性等问题。为提高流体地震识别精度,以KD地区为例,开展了陆相碎屑岩典型储层的岩石物理基础、叠前地震反演技术研究及应用。利用河道砂岩实验室岩石物理测试数据,分析了岩性、物性及孔隙流体对岩石物理参数的影响;基于弹性阻抗方程,通过弹性参数直接反演获取对储层流体敏感的参数,对KD地区河道砂岩储层进行了流体识别,提高了流体地震识别精度,取得了较好的地质效果。     

Comparative Evaluation for Characterization of Produced Water Generated from Oil,Gas, and Oil–Gas Production Fields

A reliable wastewater characterization is a prerequisite for the selection of an acceptable treatment strategy for produced water which exhibits significant differences due to the varied kinds of wells, seasonal changes, and formation types. A complete characterization of produced water generated from oil, gas, and oil–gas fields in Turkey was performed based on seasonal and locational variations. The results showed that the produced water generated from oil field wells was highly polluted and wastewater volume was higher in comparison to gas and oil–gas field wells. Besides, the characterization of produced water was varying in a wide range based on seasonal and locational variations. Useful relationships were observed between chloride, sodium, bromide, and total dissolved solids concentrations. The results can be used in the design, operation, and optimization of wastewater treatment systems of petroleum and oil industries for future studies.     

滇西崇山剪切带南段左行走滑作用的构造特征及时代约束

作为保山地块与兰坪-思茅盆地的重要边界,崇山剪切带新生代以来经历了多阶段的构造变形;其中以大规模走滑韧性剪切作用最为明显,表现为北段以右行走滑剪切为主、南段以左行走滑剪切为主.本文通过对崇山剪切带南段永保桥-瓦窑桥剖面出露的崇山群石英片岩、片麻岩及糜棱岩等进行详细露头解析、室内显微构造观察以及变形石英的EBSD组构分析,认为崇山剪切带南段的岩石新生代以来至少经历了两期不同环境下的韧性变形:第一期(D1)为纯剪条件下的收缩变形,发生的温度条件大约在550 ～ 650℃(角闪岩相),表现为一些褶皱构造、石香肠或透镜体构造的发育及石英的C轴组构图呈斜方对称式;第二期(D2)为单剪递进条件下的左行走滑剪切变形,表现形式为走滑剪切面理的发育及各类岩石遭受韧性剪切变形从而改造成糜棱岩.此外,在崇山剪切带内发育一套含电气石花岗质脉体,根据详细的露头解析及显微构造分析,本文认为该套含电气石花岗质脉体是左行剪切作用初期阶段伴随的深熔作用的产物,为同剪切花岗岩脉.本文选取了两个含电气石花岗质脉体的样品进行了LA-ICP-MS锆石U-Pb测年,分别得到21.7±0.3Ma和22.7±0.3Ma的锆石U-Pb年龄,进一步表明了崇山剪切带南段的左行剪切作用起始时代在22Ma左右或略早于22Ma.     

Purification and characterization of a new thermostable κ-carrageenase from the marine bacterium Pseudoalteromonas sp. QY203

A new extracellular κ-carrageenase, namely CgkP, 34.0 kDa in molecular weight, was purified from Pseudoalteromonas sp. QY203. CgkP showed relatively high activity at acidities ranging from pH6.0 to pH9.0 and temperatures ranging from 30℃ to 50℃ with the highest activity at 45℃ and pH7.2. Sodium chloride increased its activity markedly, and KCl increased its activity slightly. The divalent and trivalent metal ions including Cu2+ , Ni2+ , Zn2+ , Mn2+ , Al3+ and Fe3+ significantly inhibited its activity, while Mg2+ did not. CgkP remained 70% of original activity after being incubated at 40℃ for 48 h, and remained 80% of the activity after being incubated at 45℃ for 1 h. It exhibited endo-κ-carrageenase activity, mainly depolymerizing the κ-carrageenan into disaccharide and tetrasaccharide. CgkP was more thermostable than most of previously reported κ-carrageenases with a potential of being used in industry.