南秦岭铧厂沟碧口群玄武岩LA-ICP-MS锆石U-Pb年龄及岩石成因研究

铧厂沟地区碧口群玄武岩呈带状和透镜状分布于凝灰岩和凝灰质千枚岩中。在详细野外观察基础上,利用显微镜观察、主微量元素及放射性同位素分析等综合分析技术对玄武岩的岩石学、地球化学以及年代学特征进行了研究。结果表明:碧口群玄武岩普遍经历了绿片岩相的变质作用,主要矿物为斜长石、绿泥石和绿帘石;SiO_2(44.67%~49.76%)、TiO_2(1.14%~1.34%)含量较低,TFe_2O_3(12.03%~15.47%)、MgO(7.57%~9.3%)、CaO(7.29%~10.54%)含量较高。稀土总量较低,轻稀土亏损,重稀土富集。岩石微量元素和(?)石Hf同位素特征显示玄武岩形成环境可能类似N-MORB,起源于软流圈,并在上升过程中混入了古老的地壳物质。LA-ICP-MS锆石测年结果显示玄武岩的形成年龄为(316.3:±6.0)Ma(MSWD=0.78;n=7),表明碧口群火山岩系至少是两期(新元古代时期和晚古生代时期)火山作用的产物。其大规模形成时期为新元古代,后经晚古生代火山作用的叠加改造而成。     

拉萨地块西段中新世赛利普超钾质火山岩富集地幔源区和岩石成因:Li同位素制约

作为一种“非传统稳定同位素”,锂同位素地球化学研究已经成为近年来国际上研究的热点之一.文章成功应用锂同位素对青藏高原西南部赛利普超钾质火山岩进行了示范研究.研究表明,赛利普超钾质火出岩的w(Li)为11.2×10-6～22.9× 10-6,同位素组成δ7Li为1.2‰～+3.5‰,平均值为0 2‰,与平均上地壳的相当.超钾质火山岩的锂同位素组成与岩浆结晶分异程度参数之间不存在任何相关性,这表明在超钾质火山岩结晶分异过程中没有发生明显的锂同位素分馏,锂同位素组成特征反映了其形成时的源区特征.超钾质火山岩的锂同位素组成变化范围达4.7‰,并且与pb-Sr-Nd同位素和岩浆结晶分异参数之间亦无任何相关性,表明锂同位素异常可能反映了不均匀源区岩石特征.通过计算模拟以及与前人的类似研究成果进行对比,笔者认为俯冲印度地壳而不是特提斯洋壳(包括沉积物)的流体/熔体参与了超钾质火山岩的源区富集,并在此基础上提出了超钾质火山岩成因模式.     

拉萨地块西段中新世查加寺钾质火山岩岩石成因*——岩石地球化学、年代学和Sr-Nd同位素约束

通常认为,青藏高原碰撞后钾质超钾质岩是交代富集上地幔低度部分熔融的产物,而最近的研究则表明,钾质火山岩也可以起源于下地壳源区.文章对青藏高原拉萨地块西段新识别出的查加寺火山岩进行了岩石地球化学、锆石SIMS U-Pb定年和Sr-Nd同位素研究,结果表明其岩石类型为碱性系列钾质粗面岩,锆石SIMS U Pb 年龄为(23.97±0.28) Ma,说明火山活动为中新世.钾质粗面岩显示出富集LREE及LILE(K、Rb、Ba、Th、U、Pb)、亏损HFSE(Ti、Nb、Ta、P),具有类似于埃达克质岩的稀土元素分布模式和微量元素蛛网图分布模式的特征;具有高的La/Yb比值(81～105)、较高的ω(Sr)(409×10-6～472×10-6)、较高的Sr/Y比值(28-37)、较低的ω(Y)(11.5×10-6～15.7×10-6)、明显亏损重稀土元素Yb(0.78×10-6～1.08×1)-6)、较高的w(Al2O3)(15.47％～16.7％)、较低的w(MgO)(0.63％～2.12％),无明显的Eu、Sr负异常,类似于典型的埃达克岩成分特征;具有高的w(K2O)(6.28％～6.97％)、高的Rb/Sr比值(0.94～1.03)和低的Ba/Rb比值(2.21～2.51),以及Na2O、K2O与SiO2无明显的相关关系,表明源区的富钾矿物是以金云母为主;具有较低的ω(Cr) 、ω(Ni)(分别为53.4×10-6～69.4×10-6,11.4×10-6～23.5×10-6),以及较低的εNd值(-12.6～-11.8)和较高的87Sr/86Sr比值(0.73207～0.73249).所有这些特征都表明,查加寺钾质粗面岩起源于拉萨地块增厚下地壳富钾物质的部分熔融.查加寺钾质粗面岩具有约145Ma、75 Ma和30 Ma等3组继承锆石年龄群.     

青藏高原西北缘红其拉莆岩体的岩石成因、时代及其构造意义

青藏高原西北缘的南羌塘地块(班公湖-怒江结合带西段北侧)中发育着规模巨大的白垩纪花岗岩带,红其拉甫岩体是该花岗岩带中典型岩体之一,主要由花岗闪长岩和少量闪长岩组成。结合锆石阴极发光(CL)图像和Th、U、REE元素特征,利用LA-ICP-MS锆石U-Pb定年,测得岩体年龄为107.2±0.9Ma,属于早白垩世晚期。地球化学特征显示,岩体偏中性,富Al、Ca和K,稀土元素含量低,轻重稀土分馏明显,中等或弱的负铕异常,富集大离子亲石元素(Rb、Th、K和LREE),亏损高场强元素(Nb、Ta、P、Ti和HREE),属于高钾钙碱性准铝质—弱过铝质I型花岗岩。在岩浆演化过程中,部分熔融与结晶分异作用均起重要作用,并发生了以斜长石、磷灰石和钛铁矿为主的分离结晶作用。岩体的CaO、CaO/Na2O值较高,Nb、Ta亏损、Mg#值较小、相对富钾以及Sr同位素等特征说明岩体源岩应来自下地壳角闪岩相的变玄武岩。根据岩体较低的Y、HREE含量和较高的Al2O3、Sr、Sr/Y比值,发育石英与碱性长石的交生结构,以及SiO2对Mg#和Al2O3图解,推测岩浆源区压力>1.5GPa(地壳厚度至少50km),通过对锆石饱和温度的计算和锆石结构、U-Pb同位素分析,得出岩体初始岩浆温度>788℃,这与高Sr低Yb型花岗岩(埃达克岩)的形成温压条件一致,残留相应为石榴子石+角闪石+金红石(无斜长石)。综合区域地质资料分析,该岩体应是与班公湖-怒江洋闭合有关的冈底斯地块与羌塘地块之间的碰撞造山,导致地壳加厚的产物,表明班公湖-怒江洋西部与中东部的闭合时限可能具有一致性。     

Age and origin of a Palaeozoic nepheline syenite from northern Shanxi Province,China: U–Pb zircon age and whole-rock geochemical and Sr–Nd isotopic constraints

Geochronological, geochemical, and whole-rock Sr–Nd isotopic analyses were performed on a suite of Palaeozoic nepheline syenites from Zijinshan to characterize their ages and petrogenesis. Laser ablation inductively coupled plasma-mass spectrometry U–Pb zircon analyses yield consistent ages of 525.7 ± 2.8 million years for a sample (HYK01). These intrusive rocks belong to the foid syenite magma series in terms of K₂O?+?Na₂O contents (14.3–15.2 wt.%) and to the shoshonitic series based on their high K₂O contents (5.42–5.61 wt.%). The nepheline syenites are further characterized by high light rare earth element contents [(La/Yb) _N ?=?29.1–36.1]; show modest negative Eu anomalies (δEu?=?0.5–0.6) and positive anomalies in Rb, Th, U, Pb, Zr, and Hf; are depleted in Ba and high field strength elements (P and Ti). In addition, all the nepheline syenites in this study display relatively low radiogenic Sr (⁸⁷Sr/⁸⁶Sr) _i (0.7042–0.7043) and positive ?_Nd (t) (0.7–0.8). These results suggest that the nepheline syenites were derived from depleted continental crust. The parent magmas likely experienced fractional crystallization of plagioclase, Ti-bearing oxides (e.g. rutile, ilmenite, and titanite), apatite, and zircon during ascent, with negligible crustal contamination before final emplacement at a high crustal level.     

Palaeozoic porphyry Cu–Au and ultramafic Cu–Ni deposits in the eastern Tianshan orogenic belt: temporal constraints from U–Pb geochronology

During late Palaeozoic time, extensive magmatism and associated ore deposits were developed in the eastern Tianshan orogenic belt (ETOB), Northwest China, which is part of the Central Asian Orogenic Belt. To understand the petrogenesis of the intrusions in this area, we performed in situ zircon U–Pb and Hf isotopic analyses on the Tuwu–Yandong (TW–YD) stocks and the Xianshan, Hulu, Luodong, and Poshi batholiths. Two major suites of intrusive rocks have been recognized in the ETOB: (1) 338–339 Ma plagiogranite porphyries and 265–300 Ma ultramafic and mafic rocks, of which the former are associated with 323 Ma porphyry Cu–Mo deposits and have enriched radiogenic Hf isotopic compositions (?_Hf(t) = +11.5 to +15.6), which were derived from a depleted mantle source, whereas the latter are associated with 265–300 Ma magmatic Ni–Cu deposits and have variable Hf isotopic compositions (?_Hf(t) = ?10.3 to +14.3), indicating an origin via the hybridization of depleted mantle magma and variable amounts of ancient lower-crustal components. The proposed magma sources, combined with the geochemical differences between these two suites of intrusive rocks, indicate that in the lower to middle Carboniferous, a N-dipping subduction zone beneath the Dananhu arc triggered the emplacement of granitic porphyries in the Tousuquan and Dananhu island arc belt in the east Tianshan, leading to the formation of the TW and YD porphyry Cu–Mo deposits. In the Upper Carboniferous to Lower Permian, large mafic–ultramafic complexes were emplaced during the closure of the ancient Tianshan Ocean, resulting in the formation of several magmatic Cu–Ni sulphide deposits.     

Zircon U–Pb geochronology and Hf isotopic constraints on the petrogenesis of Early Triassic granites in the Wulonggou area of the Eastern Kunlun Orogen,Northwest China

Widespread granitic intrusions in the northeast part of the Wulonggou area were previously thought to be emplaced into the Palaeoproterozoic Jinshuikou Group during the Neoproterozoic. This contribution presents detailed LA-ICP-MS zircon U–Pb geochronology, major and trace element geochemistry, and zircon Hf isotope systematic on the Wulonggou Granodiorite and Xiaoyakou Granite from the Wulonggou area. Three granodiorite samples yielded U–Pb zircon ages of 247 ± 2, 248 ± 1, and 249 ± 1 Ma, and one granite sample yielded U–Pb zircon age of 246 ± 3 Ma. The granodiorite samples are metaluminous with an alumina saturation index of 0.90–0.96, as well as intermediate- to high-alkali contents of 5.49–6.14 wt.%, and low Zr+Nb+Ce+Y contents, and low Fe₂O_3T/MgO ratios, which suggest an I-type classical island arc magmatic source. The granite samples are peraluminous with an alumina saturation index of 1.02–1.03, Sr content of 305.00–374.00 ppm, Sr/Y ratios of between 17.68 and 28.77, (La/Yb)_N values of 16.98–25.07, low HREEs (Yb = 1.10–2.00 ppm), and low Y (13.00–21.10 ppm), which suggest adakite-like rocks. All granodiorite samples have zircons ε_Hf(t) values ranging from ?2.9 to +3.9, and granite samples have zircon ε_Hf(t) values ranging from ?7.8 to +3.2. These Hf isotopic data suggest that the Early Triassic granites were derived from the partial melting of a mafic Mesoproterozoic lower crust, although the degree of ancient crustal assimilation may be higher for the Xiaoyakou Granite. It is suggested here that the ca. 246–248 Ma magma was generated during the northward subduction of the Palaeo-Tethys oceanic plate.     

Zircon U–Pb geochronology and Hf isotopic constraints on the petrogenesis of the Late Silurian Shidonggou granite from the Wulonggou area in the Eastern Kunlun Orogen,Northwest China

ABSTRACT

The Wulonggou area in the Eastern Kunlun Orogen (EKO) in Northwest China is characterized by extensive granitic magmatism, ductile faulting, and orogenic gold mineralizations. The Shidonggou granite is located in the central part of the Wulonggou area. This study investigated the major as well as trace-element compositions, zircon U–Pb dates, and zircon Hf isotopic compositions of the Shidonggou granite. Three Shidonggou granite samples yielded an average U–Pb zircon age of 416 Ma (Late Silurian). The Late Silurian Shidonggou granite is peraluminous, with high alkali contents, high Ga/Al ratios, high (K₂O + Na₂O)/CaO ratios, and high Fe₂O₃^T/MgO ratios, suggesting an A-type granite. The Shidonggou granite samples have zircon ε_Hf(t) values ranging from ?7.1 to +4.4. The Hf isotopic data suggest that the Late Silurian granite was derived from the partial melting of Palaeo- to Mesoproterozoic juvenile mantle-derived mafic lower crust. Detailed geochronological and geochemical data suggest that the Late Silurian granite was emplaced in a post-collisional environment following the closure of the Proto-Tethys Ocean. Combining data of other A-type granitic rocks with ages of Late Early Silurian to Middle Devonian, such post-collisional setting related to the Proto-Tethys Ocean commenced at least as early as ~430 Ma (Late Early Silurian), and sustained up to ~389 Ma (Middle Devonian) in the EKO.     

西藏当惹雍错富钾和富钠碱性火山岩的矿物学研究及其成因指示

对青藏高原西南部当惹雍错地区的中新世超钾质粗面岩及共存的富钠质方沸石(霞石)响岩进行了详细的岩石学、矿物学研究,揭示出两套岩石具有不同的矿物学特征.钠质方沸石(霞石)响岩中橄榄石斑晶的熔体包裹体与钾质火山岩的成分相当,应属于早期残余的钾质岩浆,表明了钠质方沸石(霞石)响岩的形成晚于超钾质粗面岩.两类岩石的全岩化学成分、...     

新疆西准噶尔接特布调A型花岗岩年代学、地球化学及岩石成因

西准噶尔乃至整个北疆地区广泛发育晚古生代后碰撞花岗岩类。接特布调岩体作为一个典型的代表, 岩石类型主要有中粗粒二长花岗岩和正长花岗岩, 是认识西准噶尔花岗岩岩石成因及构造-岩浆演化的关键。本文对接特布调岩体进行高精度锆石LA-ICP-MS U-Pb测年, 获得二长花岗岩和正长花岗岩的加权平均206Pb/238U年龄分别为(287±9) Ma(n=10, MSWD=0.92)和(278±3) Ma(n=14, MSWD=0.43), 确定其形成于早二叠世, 属于300 Ma前后准噶尔周边地区后碰撞岩浆活动的产物。岩石地球化学研究表明, 前人认为的接特布调I型花岗岩应归属于A型花岗岩。正长花岗岩具有高硅(SiO2: 76.11%~76.82%), 富碱(Na2O+K2O: 8.47%~8.49%), 低钛(TiO2: 0.04%~0.05%), 贫钙(CaO: 0.36%~0.42%)的特征。二长花岗岩与其类似, 高硅(SiO2: 68.35%~71.80%), 富碱(Na2O+K2O: 6.80%~7.86%), 低钛和钙(TiO2: 0.29%~0.82%, CaO: 1.76%~2.87%), 均属于准铝质或弱过铝质(ACNK: 0.98~1.09)高钾钙碱性系列。正长花岗岩相对于二长花岗岩具有相对较低的稀土元素总量(ΣREE)(分别为23.8×10-6~49.3×10-6, 95.23×10-6~222.2×10-6), 并具有明显的负Eu异常(Eu/Eu*分别为0.01~0.02, 0.57~0.72), 另外, 正长花岗岩相对二长花岗岩明显地富集大离子亲石元素(Rb、Th、K)及高场强元素(Zr、Hf、Nb), 而强烈亏损Ba、Sr、Eu、Ti等, 具有较高的10000Ga/Al比值(>2.44)。依据微量元素比值及相关判别图, 可将接特布调花岗岩体进一步细分为A1型和A2型。接特布调岩体就位于后碰撞环境, 来源于由年轻的地幔来源物质组成的下地壳。在后碰撞岩浆活动的初期, 年轻的下地壳部分熔融形成具有岛弧印迹的A2型二长花岗岩岩浆, 随着岩石圈进一步伸展, 可能在局部出现类似裂谷的环境, 即形成显示裂谷特征的A1型正长花岗岩岩浆。